Iridium(III) acetylacetonate
- CAS No.
- 15635-87-7
- Chemical Name:
- Iridium(III) acetylacetonate
- Synonyms
- IRIDIUM(III) 2,4-PENTANEDIONATE;IRIDIUM III 2;Iridium(III) acetyL;Iridiumpentanedionate;Iridium acetylacetonate;Iridium(III) acetylacetote;IRIDIUM(III) ACETYLACETONATE;lridium(lll) acetylacetonate;Iridium tris(acetylacetonate);aIridium(III) acetylacetonate
- CBNumber:
- CB3294099
- Molecular Formula:
- C15H21IrO6
- Molecular Weight:
- 489.54
- MDL Number:
- MFCD00015353
- MOL File:
- 15635-87-7.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 269-271 °C(lit.) |
|---|---|
| Boiling point | 260°C/1mmHg |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| solubility | slightly soluble in H2O; soluble in toluene, chloroform,acetone, methanol |
| form | Crystalline |
| color | Orange-yellow |
| Water Solubility | Insoluble in water; soluble in chloroform and benzene; slightly soluble in ethanol and methanol. |
| Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
| InChI | InChI=1S/3C5H8O2.Ir/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-; |
| InChIKey | HLYTZTFNIRBLNA-LNTINUHCSA-K |
| SMILES | [Ir](O/C(/C)=C\C(=O)C)(O/C(/C)=C\C(=O)C)O/C(/C)=C\C(=O)C |
| NIST Chemistry Reference | Iridium, tris(2,4-pentanedionato-o,o')-, (oc-6-11)-(15635-87-7) |
| UNSPSC Code | 12352103 |
| NACRES | NA.23 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() ![]() GHS07,GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302+H312+H332-H315-H319-H335-H351 | |||||||||
| Precautionary statements | P280-P301+P312-P302+P352+P312-P304+P340+P312-P305+P351+P338-P308+P313 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 20/21/22-36/37/38-40 | |||||||||
| Safety Statements | 45-37/39-36/37/39-26 | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | No | |||||||||
| HS Code | 28439000 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Acute Tox. 4 Dermal Acute Tox. 4 Inhalation Acute Tox. 4 Oral Carc. 2 Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
|||||||||
| NFPA 704 |
|
Iridium(III) acetylacetonate price More Price(41)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 333352 | Iridium(III) acetylacetonate 97% | 15635-87-7 | 500mg | $253 | 2026-04-30 | Buy |
| Sigma-Aldrich | 333352 | Iridium(III) acetylacetonate 97% | 15635-87-7 | 2.5g | $975 | 2026-04-30 | Buy |
| TCI Chemical | T2557 | Tris(2,4-pentanedionato)iridium(III) | 15635-87-7 | 1g | $491 | 2026-04-30 | Buy |
| Strem Chemicals | 77-1500 | Iridium(III) acetylacetonate, 98% 98% | 15635-87-7 | 250mg | $156 | 2026-04-30 | Buy |
| Strem Chemicals | 77-1500 | Iridium(III) acetylacetonate, 98% 98% | 15635-87-7 | 1g | $469 | 2026-04-30 | Buy |
Iridium(III) acetylacetonate Chemical Properties,Uses,Production
Chemical Properties
orange-yellow crystalline powder, easily soluble in benzene and chloroform, slightly soluble in methanol and ethanol, insoluble in water. The melting point is 269°C, and the decomposition temperature is 290°C.
Uses
Iridium(III) acetylacetonate is used as a photoreducing agent, a precursor for preparing Ir-C thin film and a catalyst for hydrogenation of sulfur containing compounds. Used in various catalysis reactions in organic synthesis, including carbon nanostructures.
Application
(1) Using Ir(acac)3 as the precursor, the tomahawk coating is prepared by MOCVD technology, which has been widely used as the base material of the engine of missiles, rockets, cruisers, automobiles, etc.
(2) Using Ir(acac)3 as the deposition source, Ir-C cluster films were prepared on ZrO2 substrates, which have excellent electrochemical properties.
(3) Catalysts for hydrogenation of sulfur-containing aromatics.
(4) Strong photoreducing agent for phenylpyridine aqueous solution.
Reactions
Precursor for preparation heterogeneous catalyst on different supports for various catalytic applications: organic reactions ; water oxidation ; CO preferential oxidation ; oxygen evolution reactions;
CVD/ALD precursor for preparation of Ir and Ir2O3 films on different substrates.
Starting material for synthesis of phosphorescent iridium complexes bearing arylpyridine ligands.
reaction suitability
core: iridium
reagent type: catalyst
References
[1] N. B. MOROZOVA. Saturated Vapor Pressure of Iridium(III) Acetylacetonate[J]. Journal of Thermal Analysis and Calorimetry, 2000, 60 2: 489-495. DOI:10.1023/A:1010122301535.
[2] V. G. ISAKOVA. Synthesis and crystal structure determination of iridium(III) acetylacetonate and its Br-and I-substituted analogs[J]. Journal of Structural Chemistry, 1999, 40 2: 276-283. DOI:10.1007/BF02903657.
[3] SHIRUI YANG . Growth kinetics and microstructure of MOCVD iridium coating from iridium(III) acetylacetonate with hydrogen[J]. Applied Surface Science, 2015, 329: Pages 248-255. DOI:10.1016/j.apsusc.2014.12.146.
Iridium(III) acetylacetonate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Chenzhou Gaoxin Platinum Industry Co., Ltd. | 0735-2390599 13574551630;15073547586 | 1156989506@qq.com | China | 78 | 58 |
| Shanghai platinum raw metal material co., ltd. | 021-33360721 18601346310 | mingbomail@163.com | China | 254 | 58 |
| Jiangsu Boquan Biotechnology Co., Ltd. | 19709916022 | 5954981@qq.com | China | 2458 | 58 |
| Yunnan Precious Metals Laboratory Co., Ltd | 13529192135 | changqiaowen@126.com | China | 225 | 58 |
| Guiyan Chemical Materials (Yunnan) Co., LTD | 18317061306 | wanghongyou@ipm.com.cn | China | 114 | 58 |
| Yunnan Boquan Metal Materials Co., Ltd | 18251603297 15096626657 | 1464906612@qq.com | China | 644 | 58 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
View Lastest Price from Iridium(III) acetylacetonate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2019-07-06 | Iridium(III) acetylacetonate
15635-87-7
|
$1.00 | 1G | 98% | 100KG | Career Henan Chemical Co |
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- Iridium(III) acetylacetonate
15635-87-7
- $1.00
- 98%
- Career Henan Chemical Co






