Bis(cyclopentadienyl)zirconium dichloride
- CAS No.
- 1291-32-3
- Chemical Name:
- Bis(cyclopentadienyl)zirconium dichloride
- Synonyms
- ZIRCONOCENE DICHLORIDE;zirconocene;BIS(CYCLOPENTADIENYL)ZIRCONIUM(IV) DICHLORIDE;Bis(cyclopentadienyl)zirconium dichlorid;Dicyclopentadienyldichlorozirconium;Bis(cycL;bis(ηopentadienyL;)zirconium dichL;Dichlorozirconocene
- CBNumber:
- CB3756849
- Molecular Formula:
- C10H10Cl2Zr
- Molecular Weight:
- 292.32
- MDL Number:
- MFCD00003726
- MOL File:
- 1291-32-3.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 242-245 °C(lit.) |
|---|---|
| Boiling point | 124-125°C/15mm |
| Flash point | 124-125°C/15mm |
| storage temp. | Keep in dark place,Inert atmosphere,2-8°C |
| form | Powder |
| color | white to off-white |
| Water Solubility | hydrolysis |
| Sensitive | Air & Moisture Sensitive |
| Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
| Exposure limits |
ACGIH: TWA 5 mg/m3; STEL 10 mg/m3 NIOSH: IDLH 25 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3 |
| InChI | InChI=1S/2C5H5.2ClH.Zr/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2 |
| InChIKey | QRUYYSPCOGSZGQ-UHFFFAOYSA-L |
| SMILES | [CH]1[CH][CH][CH][CH]1.[CH]1[CH][CH][CH][CH]1.[Zr](Cl)Cl |^1:0,1,2,3,4,5,6,7,8,9| |
| CAS DataBase Reference | 1291-32-3(CAS DataBase Reference) |
| FDA UNII | SQE0U3LG60 |
| NIST Chemistry Reference | Bis(cyclopentadienyl)zirconium dichloride(1291-32-3) |
| EPA Substance Registry System | Zirconocene dichloride (1291-32-3) |
| UNSPSC Code | 12161600 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38-34 | |||||||||
| Safety Statements | 26-36-45-36/37/39 | |||||||||
| RIDADR | UN3261 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | ZH7525000 | |||||||||
| F | 8-10-21 | |||||||||
| TSCA | TSCA listed | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29319090 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
|||||||||
| NFPA 704 |
|
Bis(cyclopentadienyl)zirconium dichloride price More Price(44)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 196215 | Bis(cyclopentadienyl)zirconium(IV) dichloride ≥98% | 1291-32-3 | 5g | $45.5 | 2026-04-30 | Buy |
| Sigma-Aldrich | 196215 | Bis(cyclopentadienyl)zirconium(IV) dichloride ≥98% | 1291-32-3 | 25g | $146 | 2026-04-30 | Buy |
| TCI Chemical | Z0007 | Zirconocene Dichloride >97.0%(T) | 1291-32-3 | 5g | $60 | 2026-04-30 | Buy |
| TCI Chemical | Z0007 | Zirconocene Dichloride >97.0%(T) | 1291-32-3 | 25g | $174 | 2026-04-30 | Buy |
| Strem Chemicals | 93-4002 | Bis(cyclopentadienyl)zirconium dichloride, 99% (Zirconocene dichloride) 99% | 1291-32-3 | 5g | $36 | 2026-04-30 | Buy |
Bis(cyclopentadienyl)zirconium dichloride Chemical Properties, Uses, Production
Description
Bis(cyclopentadienyl)zirconium(IV) Dichloride or zirconocene dichloride is one of numerous organo-metallic compounds (also known as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the trade name AE Organo-MetallicsTM. As is the case for other transition metal metallocenes, bis(cyclopentadienyl)zirconium(IV) dichloride is most often used as a catalyst.
Chemical Properties
Bis(cyclopentadienyl)zirconium dichloride is a white crystals. Soluble in
polar organic solvents. Stable in dry air, very slowly
hydrolyzes in moist air.
Uses
Bis(cyclopentadienyl)zirconium dichloride is used for for Stereoselective Glycosidation. It is also used in the catalyzed transamidation of primary amides with amines. Zirconocene dichloride can also be used to prepare the Negishi reagent,in oxidative cyclisation reactions. Other applications include it is used to promote greener amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.
Uses
Zirconocene Dichloride is the main catalyst for Kaminsky-type catalytic systems, which have high activity and isotropy for catalytic olefin polymerization, and catalytic olefin zwitterionization has also been reported in the literature. Zirconocene Dichloride is also the main component of Negishi's reagent, which can be used for the ring formation of intramolecular dienes and the ring formation of intermolecular alkynes and olefins. Rubber accelerator, component of a catalyst system for polymerization of vinyl monomers, curing agent for water-repellent silicone materials, agent for plating with zirconium.
Application
Used to promote greener amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.
Direct amide formation from unactivated carboxylic acids and amines.
Useful in the synthesis of a wide range of early-transition-metal complexes and organometallic compounds.
Preparation
Synthesis of zirconium dichlorodichloride
A stirring magnet was placed in a 500 mL three-necked flask, fitted with a constant pressure dropping funnel and reflux condenser, evacuated, and replaced with pure nitrogen three times. The flask was added with 50mL of toluene and 22.3g (0.1mol) of ZrCl4, and the suspension was made by turning on the stirring. Add the THF solution of sodium cyclopentadienylide to a constant pressure dropping funnel, add dropwise at room temperature, keep the reaction solution slightly boiling, after the dropwise addition, continue the reaction for 2h. Under the heating of oil bath at 50℃, evaporate the solvent under reduced pressure to obtain a yellow solid. Put the solid into a soxhlet extractor and extract with CHCl3. Most of the solvent in the extract was evaporated under reduced pressure, and the solid was precipitated after cooling and filtered. The product was washed with a small amount of CHCl3 and dried under vacuum, yielding 20.2g of white crystals, 69% yield.
Reactions
Reagent for the conversion of enynes to bicyclic cyclopentenones.
Precursor for the cyclization of dienes to cyclopentane and cyclohexane derivatives.
Precatalyst for the alkylation of olefins.
Precursor to zirconocene complexes of unsaturated organic molecules.
Catalyst for the coupling of alkoxymethyl-substituted styrene derivatives.
Reagent for the carboalumination-Claisen rearrangement-carbonyl addition cascade reaction.
Useful for the preparation of vinyl allenes.
Reagent for the alkynylation of epoxides.
Catalyst for the formation of carbocycles from cyclic enol ether.
General Description
This product has been enhanced for catalytic efficiency.
Air & Water Reactions
Bis(cyclopentadienyl)zirconium dichloride is extremely unstable when exposed to air. Decomposes in water .
Reactivity Profile
Bis(cyclopentadienyl)zirconium dichloride is incompatible with water, acids, bases, alcohols and halogens.
Hazard
Toxic by inhalation and skin contact, irritant to eyes and mucous membranes.
Fire Hazard
Flash point data for Bis(cyclopentadienyl)zirconium dichloride are not available, but Bis(cyclopentadienyl)zirconium dichloride is probably combustible.
reaction suitability
core: zirconium
reaction type: Polymerization Reactions
reagent type: catalyst
reaction type: Olefin Metathesis
Safety Profile
Poison by intraperitoneal route. Mutation data reported. When heated to decomposition it emits toxic fumes of Zr and Cl-.
Purification Methods
Recrystallise the dichloride from CHCl3 or xylene and dry it in a vacuum. 1H NMR (CDCl3) : 6.52 from Me4Si. Store it dry in the dark under N2. [Reid et al. Aust J Chem 18 173 1965, Beilstein 16 IV 1770.]
Bis(cyclopentadienyl)zirconium dichloride Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Yueyang Kimoutain Sci-tech Co | 07308418519 17873001173 | info@kimoutain.com | China | 3 | 58 |
| WUXI HONORSHINE CHEMICAL CO.,LTD. | 0510-83593312 13665125081 | sales@honorshinechem.com | China | 54 | 60 |
| Zhengzhou HQ Material Co., Ltd. | 0371-0371-67759225 13526468238 | sales@hqmat.com | China | 342 | 55 |
| Beijing HwrkChemical Technology Co., Ltd | 89508211 18501085097 | sales.bj@hwrkchemical.com | China | 9407 | 55 |
| Wuhan Ying Yuan Bei Biological Limited | 13349903920 | 1540154086@qq.com | China | 2994 | 58 |
| Shaanxi Yanhua Technology Co., Ltd | 15029556408 | 554033698@qq.com | China | 94 | 58 |
| Jiangsu Jingping New Material Technology Co., Ltd. | 18852320356 | 3437818551@qq.com | China | 81 | 58 |
| Qingdao Haizhi Weiyuan Biotechnology Co., Ltd. | 18317699790 18317699790 | l202008112023@163.com | China | 7733 | 58 |
| Tianjin Zhongxin Chemtech Co., Ltd. | 022-66880623 | sales@tjzxchem.com | China | 612 | 60 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
Related articles
- Bis(cyclopentadienyl)zirconium dichloride: Properties and Applications as Catalyst
- Bis(cyclopentadienyl)zirconium dichloride is a highly reactive, selective, and stable catalyst used in polymerization reaction....
- Feb 28,2024
- Bis(cyclopentadienyl) zirconium dichloride catalyzed acetylation of phenols, alcohols and amines
- Bis(cyclopentadienyl)zirconium dichloride has been regarded as one of the stable non-hazardous organometallic compounds and id....
- Mar 16,2023
- Synthesis of Bis(cyclopentadienyl)zirconium dichloride
- Bis(cyclopentadienyl)zirconium dichloride is the main catalyst of the Kaminsky type catalytic system.
- Jun 21,2022
View Latest Price from Bis(cyclopentadienyl)zirconium dichloride manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-09-14 | Bis(cyclopentadienyl)zirconium dichloride
1291-32-3
|
$24.00-333.00 | 25g | 0.98 | 10kg | Shanghai UCHEM Inc. | |
 |
2026-09-14 | Zirconocene Dichlorid
1291-32-3
|
20KG/CTN | 98% | 45tons | WUXI HONOR SHINE CHEMICAL CO.,LTD | ||
 |
2026-06-30 | Bis(cyclopentadienyl)zirconium dichloride
1291-32-3
|
1kg | 99% | 10000KGS | Shaanxi Dideu New Materials Co. Ltd |
-
- Bis(cyclopentadienyl)zirconium dichloride
1291-32-3
- $24.00-333.00
- 0.98
- Shanghai UCHEM Inc.
-
- Zirconocene Dichlorid
1291-32-3
- 98%
- WUXI HONOR SHINE CHEMICAL CO.,LTD
-
- Bis(cyclopentadienyl)zirconium dichloride
1291-32-3
- $0.00
- 99%
- Shaanxi Dideu New Materials Co. Ltd
1291-32-3 (Bis(cyclopentadienyl)zirconium dichloride) Related Search:
1of4
