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Bis(triphenylphosphine)nickel(II)chloride

Bis(triphenylphosphine)nickel(II)chloride structure

CAS No.: 14264-16-5

Chemical Name:: Bis(triphenylphosphine)nickel(II)chloride

Synonyms: NiCl2(PPh3)2;Bis(triphenylphosphine)nickel dichloride;BIS(TRIPHENYLPHOSPHINE)NICKEL(II) CHLORIDE;DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL(II);BIS(TRIPHENYLPHOSPHINE)NICKEL(II) DICHLORIDE;NSC 137147;(II) dichL;(PPh3)2NiCl2;Ni(PPh3)2Cl2;phosphine)nickeL

CBNumber:: CB8433158

Molecular Formula:: C36H30Cl2NiP2

Molecular Weight:: 654.17

MDL Number:: MFCD00009592

MOL File:: 14264-16-5.mol

MSDS File:: SDS

Last updated:2026-01-13 11:27:08

Product description	Number	Pack Size	Price
Bis(triphenylphosphine)nickel(II) dichloride synthesis grade	237116	10g	$58.6
Bis(triphenylphosphine)nickel(II) dichloride synthesis grade	237116	50g	$173.85
Bis(triphenylphosphine)nickel(II) Dichloride >96.0%(T)	B1571	10g	$43
Bis(triphenylphosphine)nickel(II) Dichloride >96.0%(T)	B1571	100g	$200
Bis(triphenylphosphine)nickel(II) chloride, 99%	28-0095	5g	$27
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Bis(triphenylphosphine)nickel(II)chloride Properties

Melting point	250 °C (dec.)(lit.)
storage temp.	Inert atmosphere,Room Temperature
solubility	DMSO (Slightly), Methanol (Slightly)
form	Crystals or Powder
color	Dark green to dark gray
Water Solubility	insoluble
Sensitive	Hygroscopic
Exposure limits	NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
InChI	InChI=1S/2C18H15P.2ClH.Ni/c21-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h21-15H;2*1H;/q;;;;+2/p-2
InChIKey	ZBRJXVVKPBZPAN-UHFFFAOYSA-L
SMILES	P(C1C=CC=CC=1)(C1=CC=CC=C1)C1C=CC=CC=1.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.[Ni](Cl)Cl
CAS DataBase Reference	14264-16-5(CAS DataBase Reference)
EWG's Food Scores	1
NIST Chemistry Reference	dichlorobis(triphenylphosphine)nickel(14264-16-5)
EPA Substance Registry System	Nickel, dichlorobis(triphenylphosphine)- (14264-16-5)
UNSPSC Code	12352300
NACRES	NA.23

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07,GHS08

Signal word

Danger

Hazard statements

H317-H350-H412

Precautionary statements

P201-P273-P280-P302+P352-P308+P313

PPE

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Hazard Codes

Risk Statements

45-43-52/53-34-20/21/22

Safety Statements

53-36/37-45-60-36/37/39-26

RIDADR

3260

WGK Germany

RTECS

QR6170000

TSCA

TSCA listed

HazardClass

6.1(b)

PackingGroup

III

HS Code

29310095

Storage Class

6.1D - Non-combustible acute toxic Cat.3
toxic hazardous materials or hazardous materials causing chronic effects

Hazard Classifications

Aquatic Chronic 3
Carc. 1B
Skin Sens. 1

Limited Quantities

5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)

Excepted Quantities

Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)

NFPA 704

	0
3		0

Bis(triphenylphosphine)nickel(II)chloride price More Price(45)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	237116	Bis(triphenylphosphine)nickel(II) dichloride synthesis grade	14264-16-5	10g	$58.6	2025-07-31	Buy
Sigma-Aldrich	237116	Bis(triphenylphosphine)nickel(II) dichloride synthesis grade	14264-16-5	50g	$173.85	2025-07-31	Buy
TCI Chemical	B1571	Bis(triphenylphosphine)nickel(II) Dichloride >96.0%(T)	14264-16-5	10g	$43	2025-07-31	Buy
TCI Chemical	B1571	Bis(triphenylphosphine)nickel(II) Dichloride >96.0%(T)	14264-16-5	100g	$200	2025-07-31	Buy
Strem Chemicals	28-0095	Bis(triphenylphosphine)nickel(II) chloride, 99%	14264-16-5	5g	$27	2024-03-01	Buy

Product number	Packaging	Price	Buy
237116	10g	$58.6	Buy
237116	50g	$173.85	Buy
B1571	10g	$43	Buy
B1571	100g	$200	Buy
28-0095	5g	$27	Buy

Bis(triphenylphosphine)nickel(II)chloride Chemical Properties,Uses,Production

Reaction

Catalyst for hydrosilylation of styrene with diphenysilane
Catalyst for carboxylation of various aryl chlorides and other derivatives
Catalyst for C–P cross-coupling reactions of diphenylphosphine oxide with aryl chloride
Catalyst for N?Heterocyclic carbene-assisted cross-coupling reactions of diarylborinic acids with aryl chlorides,tosylates, and sulfamates.
Catalyst for Negishi biaryl ketone synthesis by cross-coupling of amides with aryl zinc halides via carbon-nitrogen bond cleavage.

Chemical Properties

dark green to dark grey crystals or powder

Uses

Coordination compund.

Uses

suzuki reaction

Uses

Dichlorobis(triphenylphosphine)nickel(II) is used as a catalyst for cross-coupling of Grignard reagents, hydrosilylations, hydrogenation and polymerization.

reaction suitability

core: nickel
reagent type: catalyst

Purification Methods

Wash it with glacial AcOH and dry it in a vacuum over H2SO4 and KOH until AcOH is removed. [Venanzi J Chem Soc 719 1958, Kocienski et al. J Org Chem 54 1215 1989, Beilstein 16 IV 953.]

Bis(triphenylphosphine)nickel(II)chloride Preparation Products And Raw materials

Raw materials

Nickel(II) chloride hexahydrate Ethanol Dichloromethane Triphenylphosphine

Preparation Products

6,6'-Dimethyl-2,2'-dipyridyl 3-PHENYLPIPERIDINE

Bis(triphenylphosphine)nickel(II)chloride Suppliers

Global( 384)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Chuanghai Biotechnology Co., Ltd	+8615350571055	Sibel@chuanghaibio.com	China	8754	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718; +8613336195806	sales@capot.com	China	29735	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-2158073036	info@dakenam.com	China	13619	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21600	55
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	33024	60
AB PharmaTech,LLC	323-480-4688	sales@acrospharmatech.com	United States	989	55
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29837	58
Wuhan Pengo Technology.,Ltd.	+86-27-81330736 +86-13628634921	sunny.w@boronicgroup.com	CHINA	171	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49977	58

Supplier	Advantage
Hebei Chuanghai Biotechnology Co., Ltd	58
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
ATK CHEMICAL COMPANY LIMITED	60
AB PharmaTech,LLC	55
career henan chemical co	58
Wuhan Pengo Technology.,Ltd.	58
Alchem Pharmtech,Inc.	58
CONIER CHEM AND PHARMA LIMITED	58

View Lastest Price from Bis(triphenylphosphine)nickel(II)chloride manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2026-01-05	Bis(triphenylphosphine)nickel(II)chloride 14264-16-5	US $10.00 / KG	1KG	99%	5tons	Hebei Chuanghai Biotechnology Co., Ltd
2023-04-17	Bis(triphenylphosphine)nickel(II)chloride 14264-16-5	US $200.00 / KG	1KG	99%	500t	Shanghai Yunao International Trade Co., Ltd
2022-09-24	Bis(triphenylphosphine)nickel(II)chloride 14264-16-5	US $0.00 / kg	1kg	99%	1000kg	henan kanbei chemical co.,ltd

Bis(triphenylphosphine)nickel(II)chloride
14264-16-5
US $10.00 / KG
99%
Hebei Chuanghai Biotechnology Co., Ltd

Bis(triphenylphosphine)nickel(II)chloride
14264-16-5
US $200.00 / KG
99%
Shanghai Yunao International Trade Co., Ltd

Bis(triphenylphosphine)nickel(II)chloride
14264-16-5
US $0.00 / kg
99%
henan kanbei chemical co.,ltd

Bis(triphenylphosphine)nickel(II)chloride Spectrum

Bis(triphenylphosphine)nickel(II)chloride(14264-16-5)MS Bis(triphenylphosphine)nickel(II)chloride(14264-16-5)IR1 Bis(triphenylphosphine)nickel(II)chloride(14264-16-5)IR2

14264-16-5(Bis(triphenylphosphine)nickel(II)chloride)Related Search:

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BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Bis-(triphenylphosphino)-cuprous borohydride BIS(TRIPHENYLPHOSPHINE)COBALT (II) CHLORIDE Nickel(II) chloride hexahydrate Nickle chloride

Potassium chloride Tris(triphenylphosphine)chlororhodium Bis(tricyclohexylphosphine)nickel(II) chloride, 99%

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Dichlorobis(triphenyIphosphine)-nickel tributyl-phosphin compd. with nickelchloride Nickel(II) chloride bis(triphenylphosphine) Bis(triphenylphosphine)nick Dichlorobis(triphenylphosphine)nickel(II), Nickel(II)bis(triphenylphosphine) dichloride Phosphine, tributyl-, compound with nickel chloride (2:1) Dichlorobis(triphenylphosphine)nickel(Ⅱ) Dichlorobis(triphenylphosphine)nickel(II), 98+% Dichlorobis(triphehylphosphine)nickel(II) ,98% Bis(triphenylphosphine)nickel(II)chloride, 98% 10GR Bis(triphenylphosphine)nickel(II) chloride,98% (PPh3)2NiCl2 NSC 137147 BIS(TRIPHENYLPHOSPHINE)NICKEL(II) CHLORI Bis (triphenylphosphine) nickel chloride NiCl2(PPh3)2 Bis(triphenylphosphine)nickel(II) dichloride 99.99% trace metals basis Bis(triphenylphosphine)nickel(II) dichloride synthesis grade Bis(triphenylphosphine)nickel(II)chloride,(PPh3)2NiCl2 NICKEL(II)-BIS(TRIPHENYLPHOSPHINE) DICHLORIDE NICKEL BIS(TRIPHENYLPHOSPHINE)DICHLORIDE DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL(II) BIS(TRIPHENYLPHOSPHINO)NICKEL(II) CHLORIDE BIS(TRIPHENYLPHOSPHINE)NICKEL(2) DICHLORIDE BIS(TRIPHENYLPHOSPHINE)NICKEL(II) CHLORIDE BIS(TRIPHENYLPHOSPHINE)NICKEL(II) DICHLORIDE Bis(tri-N-butylphosphine)dichloronickel bis(triphenylphosphine)dichloro-nicke Bis(triphenylphosphine)dichloronickel Bis(triphenylphosphine)nickel dichloride Dichlorobis(triphenyIphosphine)-nickel(II) dichlorobis(triphenylphosphine)-nicke Nickel, bis(triphenylphosphine)dichloro- Nickel, dichlorobis(triphenylphosphine)- Phosphine, tributyl-, compd. with nickelchloride (2:1) bis(triphenylphosphine)nickle(II) Bis-(triphenylphosphino)-nickel chloride tributyl-phosphincompd.withnickelchloride(2:1) Bis(triphenylphosphine)nickel(II) chloride for synthesis TRIPHENYLPHOSPHINE NICKEL (II) CHLORIDE Bis(triphenylphosphine)nickel(II) chloride, 98+% Bis(triphenylphosphine)dichloronickel(II)~Dichlorobis(triphenylphosphine)nickel(II) Bis(triphenylphosphine)nickel(II)chloride,99% Dichloro bis (Triphenyl phosphine) Nickel catalyst Bis(triphenylphosphine)nickel(II)chloride,NiCl2(PPh3)2 Dichlorobis(triphenylphosphine)nickel(II), 98%, for synthesis Bis(triphenylphosphine)nickel(II) Dichloride > (II) dichL phosphine)nickeL Bis(triphenylphosphine)nickel(II)chloride ISO 9001：2015 REACH Bis(triphenylphosphin)nickel(II)chlorid dichloronickel triphenylphosphane is(triphenylphosphine)nickel(II)chloride (PPh3)2NiCl2 NICKEL(2+) ION BIS(TRIPHENYLPHOSPHINE) DICHLORIDE Bis(Triphenylphosphoranyl)nickel(iv) chloride Ni(PPh3)2Cl2 14264-16-5