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Bis(triphenylphosphine)nickel(II)chloride

Bis(triphenylphosphine)nickel(II)chloride Structure
Bis(triphenylphosphine)nickel(II)chloride structure
CAS No.
14264-16-5
Chemical Name:
Bis(triphenylphosphine)nickel(II)chloride
Synonyms
NiCl2(PPh3)2;Ni(PPh3)2Cl2;BIS(TRIPHENYLPHOSPHINE)NICKEL(II) CHLORIDE;Bis(triphenylphosphine)nickel dichloride;(PPh3)2NiCl2;DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL(II);Bis (triphenylphosphine) nickel chloride;BIS(TRIPHENYLPHOSPHINE)NICKEL(II) DICHLORIDE;NSC 137147;(II) dichL
CBNumber:
CB8433158
Molecular Formula:
C36H30Cl2NiP2
Molecular Weight:
654.17
MDL Number:
MFCD00009592
MOL File:
14264-16-5.mol
MSDS File:
SDS
Last updated:2026-06-04 16:00:12
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Bis(triphenylphosphine)nickel(II)chloride Properties

Melting point 250 °C (dec.)(lit.)
storage temp. Inert atmosphere,Room Temperature
solubility DMSO (Slightly), Methanol (Slightly)
form Crystals or Powder
color Dark green to dark gray
Water Solubility insoluble
Sensitive Hygroscopic
Exposure limits NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
InChI InChI=1S/2C18H15P.2ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
InChIKey ZBRJXVVKPBZPAN-UHFFFAOYSA-L
SMILES P(C1C=CC=CC=1)(C1=CC=CC=C1)C1C=CC=CC=1.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.[Ni](Cl)Cl
CAS DataBase Reference 14264-16-5(CAS DataBase Reference)
REACH Annex XVII Substances List Bis(triphenylphosphine)nickel(II) chloride (14264-16-5)
EWG's Food Scores 1
NIST Chemistry Reference dichlorobis(triphenylphosphine)nickel(14264-16-5)
EPA Substance Registry System Nickel, dichlorobis(triphenylphosphine)- (14264-16-5)
UNSPSC Code 12352300
NACRES NA.23

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS07,GHS08
Signal word  Danger
Hazard statements  H317-H350-H412
Precautionary statements  P201-P273-P280-P302+P352-P308+P313
PPE dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Codes  T
Risk Statements  45-43-52/53-34-20/21/22
Safety Statements  53-36/37-45-60-36/37/39-26
RIDADR  3260
WGK Germany  3
RTECS  QR6170000
F  21
TSCA  TSCA listed
HazardClass  6.1(b)
PackingGroup  III
HS Code  29310095
Storage Class 6.1D - Non-combustible acute toxic Cat.3
toxic hazardous materials or hazardous materials causing chronic effects
Hazard Classifications Aquatic Chronic 3
Carc. 1B
Skin Sens. 1
REACH Registrations Active
Limited Quantities 5.0 kg (11 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
NFPA 704
0
3 0

Bis(triphenylphosphine)nickel(II)chloride price More Price(78)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 237116 Bis(triphenylphosphine)nickel(II) dichloride synthesis grade 14264-16-5 10g $62.4 2026-04-30 Buy
Sigma-Aldrich 237116 Bis(triphenylphosphine)nickel(II) dichloride synthesis grade 14264-16-5 50g $195 2026-04-30 Buy
TCI Chemical B1571 Bis(triphenylphosphine)nickel(II) Dichloride >96.0%(T) 14264-16-5 10g $40 2026-04-30 Buy
TCI Chemical B1571 Bis(triphenylphosphine)nickel(II) Dichloride >96.0%(T) 14264-16-5 100g $176 2026-04-30 Buy
Strem Chemicals 28-0095 Bis(triphenylphosphine)nickel(II) chloride, 99% 99% 14264-16-5 5g $28 2026-04-30 Buy
Product number Packaging Price Buy
237116 10g $62.4 Buy
237116 50g $195 Buy
B1571 10g $40 Buy
B1571 100g $176 Buy
28-0095 5g $28 Buy

Bis(triphenylphosphine)nickel(II)chloride Chemical Properties, Uses, Production

Reaction

  1. Catalyst for hydrosilylation of styrene with diphenysilane
  2. Catalyst for carboxylation of various aryl chlorides and other derivatives
  3. Catalyst for C–P cross-coupling reactions of diphenylphosphine oxide with aryl chloride
  4. Catalyst for N?Heterocyclic carbene-assisted cross-coupling reactions of diarylborinic acids with aryl chlorides,tosylates, and sulfamates.
  5. Catalyst for Negishi biaryl ketone synthesis by cross-coupling of amides with aryl zinc halides via carbon-nitrogen bond cleavage.
Reactions of 14264-16-5

Chemical Properties

dark green to dark grey crystals or powder

Uses

Coordination compund.

Uses

suzuki reaction

Uses

Dichlorobis(triphenylphosphine)nickel(II) is used as a catalyst for cross-coupling of Grignard reagents, hydrosilylations, hydrogenation and polymerization.

reaction suitability

core: nickel
reagent type: catalyst

Purification Methods

Wash it with glacial AcOH and dry it in a vacuum over H2SO4 and KOH until AcOH is removed. [Venanzi J Chem Soc 719 1958, Kocienski et al. J Org Chem 54 1215 1989, Beilstein 16 IV 953.]

Bis(triphenylphosphine)nickel(II)chloride Preparation Products And Raw materials

Raw materials

Nickel(II) chloride hexahydrate Ethanol Dichloromethane Triphenylphosphine

Preparation Products

6,6'-Dimethyl-2,2'-dipyridyl 3-Phenylpiperidine

Bis(triphenylphosphine)nickel(II)chloride Suppliers

Global Suppliers ( 386)
Supplier Tel Email Country ProdList Advantage
Zhengzhou Changkuan Technology Co., Ltd 0371-63769919 18530983798 sales5@changkuantech.com China 158 55
Panjin Greenchem Technology Co., Ltd. 13121959385 chemrocking@bjgreenchem.com China 223 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
INTATRADE GmbH +49 3493/605464 sales@intatrade.de Germany 3563 66
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TAIYUAN RHF CO.,LTD. +86 351 7031519 sales@RHFChem.com China 2334 56
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
ShangHai DEMO Chemical Co.,Ltd 400-021-7337 2355568890 sales@demochem.com China 2569 57
Beijing HwrkChemical Technology Co., Ltd 89508211 18501085097 sales.bj@hwrkchemical.com China 9407 55
Supplier Advantage
Zhengzhou Changkuan Technology Co., Ltd 55
Panjin Greenchem Technology Co., Ltd. 58
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
INTATRADE GmbH 66
Alfa Aesar 84
TAIYUAN RHF CO.,LTD. 56
TCI (Shanghai) Development Co., Ltd. 81
ShangHai DEMO Chemical Co.,Ltd 57
Beijing HwrkChemical Technology Co., Ltd 55

View Latest Price from Bis(triphenylphosphine)nickel(II)chloride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Bis(triphenylphosphine)nickel(II)chloride pictures 2026-03-20 Bis(triphenylphosphine)nickel(II)chloride
14264-16-5
 $10.00 1KG 99% 5tons Hebei Chuanghai Biotechnology Co., Ltd
Bis(triphenylphosphine)nickel(II)chloride pictures 2023-04-17 Bis(triphenylphosphine)nickel(II)chloride
14264-16-5
 $200.00 1KG 99% 500t Shanghai Yunao International Trade Co., Ltd
Bis(triphenylphosphine)nickel(II)chloride pictures 2022-09-24 Bis(triphenylphosphine)nickel(II)chloride
14264-16-5
 1kg 99% 1000kg henan kanbei chemical co.,ltd

Bis(triphenylphosphine)nickel(II)chloride Spectrum

Bis(triphenylphosphine)nickel(II)chloride(14264-16-5)MSBis(triphenylphosphine)nickel(II)chloride(14264-16-5)IR1Bis(triphenylphosphine)nickel(II)chloride(14264-16-5)IR2

14264-16-5 (Bis(triphenylphosphine)nickel(II)chloride) Related Search:

Sodium chloride Choline chloride Nickel oxide Ammonium chloride Calcium chloride
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(Oxydi-2,1-phenylene)bis(diphenylphosphine) Bis(triphenylphosphine)dicarbonylnickel Bis(tricyclohexylphosphine)nickel(II) chloride, 99%

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Dichlorobis(triphenyIphosphine)-nickel tributyl-phosphin compd. with nickelchloride Nickel(II) chloride bis(triphenylphosphine) Bis(triphenylphosphine)nick Dichlorobis(triphenylphosphine)nickel(II), Nickel(II)bis(triphenylphosphine) dichloride Phosphine, tributyl-, compound with nickel chloride (2:1) Dichlorobis(triphenylphosphine)nickel(Ⅱ) Dichlorobis(triphenylphosphine)nickel(II), 98+% Dichlorobis(triphehylphosphine)nickel(II) ,98% Bis(triphenylphosphine)nickel(II)chloride, 98% 10GR Bis(triphenylphosphine)nickel(II) chloride,98% (PPh3)2NiCl2 NSC 137147 BIS(TRIPHENYLPHOSPHINE)NICKEL(II) CHLORI Bis(triphenylphosphine)nickel(II) dichloride 99.99% trace metals basis Bis(triphenylphosphine)nickel(II) dichloride synthesis grade Bis(triphenylphosphine)nickel(II)chloride,(PPh3)2NiCl2 NICKEL(II)-BIS(TRIPHENYLPHOSPHINE) DICHLORIDE NICKEL BIS(TRIPHENYLPHOSPHINE)DICHLORIDE DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL BIS(TRIPHENYLPHOSPHINO)NICKEL(II) CHLORIDE BIS(TRIPHENYLPHOSPHINE)NICKEL(2) DICHLORIDE BIS(TRIPHENYLPHOSPHINE)NICKEL(II) DICHLORIDE Bis(tri-N-butylphosphine)dichloronickel bis(triphenylphosphine)dichloro-nicke Bis(triphenylphosphine)dichloronickel Dichlorobis(triphenyIphosphine)-nickel(II) dichlorobis(triphenylphosphine)-nicke Nickel, bis(triphenylphosphine)dichloro- Nickel, dichlorobis(triphenylphosphine)- Phosphine, tributyl-, compd. with nickelchloride (2:1) bis(triphenylphosphine)nickle(II) Bis-(triphenylphosphino)-nickel chloride tributyl-phosphincompd.withnickelchloride(2:1) Bis(triphenylphosphine)nickel(II) chloride for synthesis TRIPHENYLPHOSPHINE NICKEL (II) CHLORIDE Bis(triphenylphosphine)nickel(II) chloride, 98+% Bis(triphenylphosphine)dichloronickel(II)~Dichlorobis(triphenylphosphine)nickel(II) Bis(triphenylphosphine)nickel(II)chloride,99% Dichloro bis (Triphenyl phosphine) Nickel catalyst Bis(triphenylphosphine)nickel(II)chloride,NiCl2(PPh3)2 Dichlorobis(triphenylphosphine)nickel(II), 98%, for synthesis Bis(triphenylphosphine)nickel(II) Dichloride > (II) dichL phosphine)nickeL Bis(triphenylphosphine)nickel(II)chloride ISO 9001：2015 REACH Bis(triphenylphosphin)nickel(II)chlorid dichloronickel triphenylphosphane is(triphenylphosphine)nickel(II)chloride NICKEL(2+) ION BIS(TRIPHENYLPHOSPHINE) DICHLORIDE Bis(Triphenylphosphoranyl)nickel(iv) chloride Dichlorobis(triphenylphosphine)nickel(Ⅱ) (PPh3)2NiCl2 Bis (triphenylphosphine) nickel chloride BIS(TRIPHENYLPHOSPHINE)NICKEL(II) CHLORIDE Bis(triphenylphosphine)nickel dichloride DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL(II) NiCl2(PPh3)2 Ni(PPh3)2Cl2