ChemicalBook >> CAS DataBase List >>4-Methylpiperidine

4-Methylpiperidine

CAS No.
626-58-4
Chemical Name:
4-Methylpiperidine
Synonyms
4PPC;4-PIPECOLINE;Piperidine, 4-methyl-;4-Methylpiperidine solution;4Me-Pip;g-Pipecoline;GAMMA-PIPECOLINE;AKOS BBS-00003666;4-METHYLPIPERIDINE;4-methyl-piperidin
CBNumber:
CB4124405
Molecular Formula:
C6H13N
Molecular Weight:
99.17
MDL Number:
MFCD00006005
MOL File:
626-58-4.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 01:58:06

4-Methylpiperidine Properties

Melting point 4-5 °C
Boiling point 124 °C(lit.)
Density 0.838 g/mL at 25 °C(lit.)
vapor pressure 16 hPa (20 °C)
refractive index n20/D 1.446(lit.)
Flash point 45 °F
storage temp. Flammables area
solubility Chloroform
form Liquid
pka pK1:11.23(+1) (25°C,μ=0.5)
Specific Gravity 0.838
color Clear slightly yellow
PH 13 (100g/l, H2O, 20℃)
Water Solubility miscible
BRN 1083
InChI 1S/C6H13N/c1-6-2-4-7-5-3-6/h6-7H,2-5H2,1H3
InChIKey UZOFELREXGAFOI-UHFFFAOYSA-N
SMILES CC1CCNCC1
CAS DataBase Reference 626-58-4(CAS DataBase Reference)
FDA UNII EV6HN6HDP8
NIST Chemistry Reference Piperidine, 4-methyl-(626-58-4)
EPA Substance Registry System Piperidine, 4-methyl- (626-58-4)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Corrosion (GHS05)
GHS02,GHS05
Signal word  Danger
Hazard statements  H314-H225
Precautionary statements  P501-P240-P210-P233-P243-P241-P242-P264-P280-P370+P378-P303+P361+P353-P301+P330+P331-P363-P304+P340+P310-P305+P351+P338+P310-P403+P235-P405
PPE Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  F,Xi,T
Risk Statements  11-36/37/38-36-20/21-10-61
Safety Statements  16-26-36-45-36/37-53
RIDADR  UN 1993 3/PG 2
WGK Germany  3
TSCA  TSCA listed
HazardClass  3
PackingGroup  II
HS Code  29333999
Storage Class 3 - Flammable liquids
Hazard Classifications Acute Tox. 4 Oral
Eye Dam. 1
Flam. Liq. 2
Skin Corr. 1B
REACH Registrations Active
Limited Quantities 1.0 L (0.3 gallon) (liquid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
NFPA 704
3
3 0

4-Methylpiperidine price More Price(55)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.06187 4-Methylpiperidine for synthesis 626-58-4 100mL $79.2 2026-04-30 Buy
Sigma-Aldrich 792152 4-Methylpiperidine solution for peptide synthesis, 20 % (w/w) in DMF 626-58-4 500ml $221 2026-04-30 Buy
Sigma-Aldrich 8.06187 4-Methylpiperidine for synthesis 626-58-4 500mL $247 2026-04-30 Buy
Sigma-Aldrich 792152 4-Methylpiperidine solution for peptide synthesis, 20 % (w/w) in DMF 626-58-4 2l $807 2026-04-30 Buy
TCI Chemical P0445 4-Methylpiperidine >98.0%(GC)(T) 626-58-4 25mL $30 2026-04-30 Buy
Product number Packaging Price Buy
8.06187 100mL $79.2 Buy
792152 500ml $221 Buy
8.06187 500mL $247 Buy
792152 2l $807 Buy
P0445 25mL $30 Buy

4-Methylpiperidine Chemical Properties,Uses,Production

Chemical Properties

clear slightly yellow liquid

Uses

4-Methylpiperidine is used as a catalyst in the synthesis of stilbene derivatives as anti-malarial agents. It also serves as an anti-corrosive compound for iron.

Uses

4-Methylpiperidine acts as a catalyst in the preparation of stilbene derivatives. It is used as an anti-corrosive compound for iron. It is also used in the synthesis of peptides to remove or deprotection of 9-fluorenylmethyloxycarbonyl (Fmoc) groups.

Purification Methods

Purify it via the hydrochloride (m 189o). It is freed from 3-methylpyridine by zone melting. The hydrobromide has m 173o(from butanone/*C6H6). [Beilstein 20 III/IV 1511, 20/4 V 116.]

108-89-4
626-58-4
Synthesis of 4-Methylpiperidine from 4-Methylpyridine
Global( 257)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Harvest Chemical Industrial Co., Ltd. 15721252604 17321035817 sales@harvest-chem.com China 2829 64
Qingdao Dexin Chemical Co., Ltd 18353358123 839877395@qq.com China 287 58
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
ShangHai DEMO Chemical Co.,Ltd 400-021-7337 2355568890 sales@demochem.com China 2569 57
Beijing dtftchem Technology Co., Ltd. 010-60275820 13031183356 elainezt@sina.com China 1386 62
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Wuhan Chemwish Technology Co., Ltd 86-027-67849912 sales@chemwish.com China 35884 56
Capot Chemical Co., Ltd +86 (0) 571 85 58 67 18 China 18187 66

View Lastest Price from 4-Methylpiperidine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-Methylpiperidine pictures 2019-07-06 4-Methylpiperidine
626-58-4
$1.00 1kg 99% 200kg Career Henan Chemical Co
LABOTEST-BB LTBB000596 HEXAHYDRO-G-PICOLINE GAMMA-PIPECOLINE 4-METHYLPIPERIDINE 4PPC 4-methyl-piperidin 4-pipecoline(gamma-) 4-Methylpiperidine99% PIPECOLINE = 4-METHYLPIPERIDINE Piperidine, 4-methyl- 4-PIPECOLINE 4-METHYL PIPERIDINE 4Me-Pip 4-Methylpiperidine, 98+% γ-Pipecoline, 4-Pipecoline g-Pipecoline 4-Methylpiperidine, 99% 100GR AKOS BBS-00003666 4-Methylpiperidine solution 4-Methylpiperidine> 4'-Methylbiphenyl-2-carboxylic acid Minoxidil Impurity 89 4-PIPECOLINE 626-58-4 625-58-4 Heterocyclic Building Blocks AMINE Building Blocks Piperidines Chemical Synthesis Heterocyclic Building Blocks Piperidines Building Blocks C5 to C7 Piperidine K00001 YP00036