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Prussian Blue

CAS No.
14038-43-8
Chemical Name:
Prussian Blue
Synonyms
CI 77510;Pigment Blue 27;Iron Blue;FERRIC FERROCYANIDE;Iron ferrocyanide;PRUSSIAN BLUE INSOLUBLE;IRON(III) HEXACYANOFERRATE(II);ferric hexacyanoferrate;Blue 27;ferrocin
CBNumber:
CB4134130
Molecular Formula:
C6FeN6.4/3Fe
Molecular Weight:
859.23
MDL Number:
MFCD00135663
MOL File:
14038-43-8.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-09-12 10:01:08

Prussian Blue Properties

Density 1.8
storage temp. Room Temperature
solubility insoluble in H2O, dilute acid solutions, organic solvents
form Powder
color Dark blue
Water Solubility practically insoluble
Sensitive Hygroscopic
λmax 694 nm
Merck 14,7910
Solubility Product Constant (Ksp) pKsp: 40.52
Exposure limits ACGIH: TWA 1 mg/m3
NIOSH: IDLH 25 mg/m3; TWA 1 mg/m3
Stability Stable. Incompatible with strong acids, strong oxidizing agents, ammonia. Light sensitive.
Cosmetics Ingredients Functions COLORANT
InChI InChI=1S/18CN.7Fe/c18*1-2;;;;;;;/q;;;;;;;;;;;;;;;;;;3*-4;4*+3
InChIKey DNMNDNSFJMUUFM-UHFFFAOYSA-N
SMILES [Fe-4](C#N)(C#N)(C#N)(C#N)(C#N)C#N.[Fe-4](C#N)(C#N)(C#N)(C#N)(C#N)C#N.[Fe-4](C#N)(C#N)(C#N)(C#N)(C#N)C#N.[Fe+3].[Fe+3].[Fe+3].[Fe+3]
LogP -0.250 (est)
FDA 21 CFR 73.1299; 73.2299
EWG's Food Scores 1-4
FDA UNII TLE294X33A
ATC code V03AB31
EPA Substance Registry System Iron ferrocyanide (Fe4[Fe(CN)6]3) (14038-43-8)
UNSPSC Code 12352302
NACRES NA.55

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H332-H312
Precautionary statements  P261-P271-P304+P340-P312-P280-P302+P352-P312-P322-P363-P501
Safety Statements  22-24/25
WGK Germany  1
RTECS  LJ8200000
TSCA  TSCA listed
HS Code  32041990
Storage Class 11 - Combustible Solids
Hazardous Substances Data 14038-43-8(Hazardous Substances Data)
Toxicity mouse,LD,oral,> 8gm/kg (8000mg/kg),Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 35(1), Pg. 35, 1991.
REACH Registrations Active
NFPA 704
0
0 0

Prussian Blue price More Price(27)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 234125 Iron(III) ferrocyanide 14038-43-8 25g $79.1 2026-04-30 Buy
TCI Chemical I0849 Iron(III) Hexacyanoferrate(II) 14038-43-8 25g $41 2026-04-30 Buy
Usbiological 287559 Prussian blue insoluble, Technical grade Asreported 14038-43-8 50g $230 2026-06-03 Buy
Usbiological 287559 Prussian blue insoluble, Technical grade Asreported 14038-43-8 100g $340 2026-06-03 Buy
TRC TRC-I775228-500MG Iron(III) Ferrocyanide 14038-43-8 500mg $89 2026-06-03 Buy
Product number Packaging Price Buy
234125 25g $79.1 Buy
I0849 25g $41 Buy
287559 50g $230 Buy
287559 100g $340 Buy
TRC-I775228-500MG 500mg $89 Buy

Prussian Blue Chemical Properties, Uses, Production

Description

Iron blue is chemically referred to as ferric ammonium ferrocyanide Fe(Fe(CN)6)3. This material is generated through the reaction of sodium ferrocyanide and ferrous sulfate in the presence of ammonium sulfate. Pigments prepared with sodium or potassium salts are called ferric ferrocyanide.

Chemical Properties

dark blue crystalline powder

Uses

Prussian blue (KFe(Fe(CN)6)) is an intense reddish blue pigment with fairly good properties. It is used as a coloring pigment in many types of paint systems and is also used in the production of lead chrome greens.

Uses

Iron(III) hexacyanoferrate(II) is uses extensively as an Iron Oxide dye. Prussian blue is used as a paint and wallpaper printing, chemical coatings, carbon paper and in the plastics industry. as an antidote for poisoning with radioactive cesium or thallium. In the metalworking and mechanical engineering Prussian blue is thinly applied as a paste on metal surfaces in order to assess the quality scraped surfaces can.

Definition

The most common and best- known name for blue iron ferrocyanide (iron blue) pigments made by a variety of procedures.

Origin

Ferric hexacyanoferrate(II), known as Prussian blue, has the empirical formula Fe4[Fe(CN)6]3. It was probably synthesized for the first time by the paint maker Diesbach in Berlin in 1704, and it was one of the first synthetic pigments. A number of different, even if chemically related compounds, are named Prussian blue. Here this term refers only to insoluble ferric hexacyanoferrate(II)[1].

Flammability and Explosibility

Not classified

Structure and conformation

Prussian blue has a basic cubic structure consisting of alternating iron(II) and iron(III) located on a face centered cubic lattice, in such a way that the iron(III) ions are surrounded octahedrically by nitrogen atoms, and iron(II) ions are surrounded by carbon atoms[2].

References

[1] Crisponi, G. and V. Nurchi. “Chelating Agents as Therapeutic Compounds—Basic Principles.” Chelation Therapy in the Treatment of Metal Intoxication (2016) 35-61.
[2] Karyakin, A. “Chemical and biological sensors based on electroactive inorganic polycrystals.”Electrochemical Sensors, Biosensors and their Biomedical Applications (2008) 411-439.

Global Suppliers ( 334)
Supplier Tel Email Country ProdList Advantage
Tianjin Baima Technology Co., LTD 02288195255 15620955089 362698781@qq.com China 783 58
yimo organism 15915870272; 15915870272 yimo_bio@163.com China 284 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
future industrial shanghai co., ltd 400-0066400 13621662912 sales@jonln.com China 1989 65
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 45000 61
Sichuan Kulinan Technology Co., Ltd 400-1166-196 18981987031 cdhxsj@163.com China 11674 57
Tianjin heowns Biochemical Technology Co., Ltd. 400 638 7771 sales@heowns.com China 14412 57

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