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TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE

CAS No.
983-81-3
Chemical Name:
TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE
Synonyms
NSC 132587;trans-vinylenebis[diphenylphosphine];[(E)-Vinylene]bis(diphenylphosphine);(E)-1,2-Bis(diphenylphosphino)ethene;(E)-1,2-Bis(diphenylphosphanyl)ethene;TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE;[(E)-1,2-Ethenediyl]bis(diphenylphosphine);trans-1,2-Ethenediylbis(diphenylphosphine);[(E)-Ethene-1,2-diyl]bis(diphenylphosphine);trans-1,2-Bis(diphenylphosphino)ethylene,97%
CBNumber:
CB4177436
Molecular Formula:
C26H22P2
Molecular Weight:
396.4
MDL Number:
MFCD00063219
MOL File:
983-81-3.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 04:54:34
Product description Number Pack Size Price
trans-1,2-Bis(diphenylphosphino)ethylene 97% 287970 1g $79.6
trans-1,2-Bis(diphenylphosphino)ethylene >96.0%(T) B2003 1g $68
trans-1,2-Bis(diphenylphosphino)ethylene Asreported 267119 1g $336
trans-1,2-Bis(diphenylphosphino)ethylene Asreported 267119 2g $468
trans-1,2-Bis(diphenylphosphino)ethylene Asreported 267119 5g $686

TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE Properties

Melting point 126-130 °C(lit.)
Boiling point 546.8±33.0 °C(Predicted)
storage temp. 2-8°C, protect from light, stored under nitrogen
form Crystalline
color White to Almost white
Sensitive Air Sensitive
BRN 757793
InChI 1S/C26H22P2/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26/h1-22H/b22-21+
InChIKey NCKJIJSEWKIXAT-QURGRASLSA-N
SMILES c1ccc(cc1)P(\C=C\P(c2ccccc2)c3ccccc3)c4ccccc4
CAS DataBase Reference 983-81-3(CAS DataBase Reference)
UNSPSC Code 12352002
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338-P280a-P304+P340-P405-P501a-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
RIDADR  UN 3464 6.1/PG 2
WGK Germany  3
HS Code  29310099
Storage Class 11 - Combustible Solids
NFPA 704
1
2 0

TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE price More Price(43)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 287970 trans-1,2-Bis(diphenylphosphino)ethylene 97% 983-81-3 1g $79.6 2026-04-30 Buy
TCI Chemical B2003 trans-1,2-Bis(diphenylphosphino)ethylene >96.0%(T) 983-81-3 1g $68 2026-04-30 Buy
Usbiological 267119 trans-1,2-Bis(diphenylphosphino)ethylene Asreported 983-81-3 1g $336 2026-06-03 Buy
Usbiological 267119 trans-1,2-Bis(diphenylphosphino)ethylene Asreported 983-81-3 2g $468 2026-06-03 Buy
Usbiological 267119 trans-1,2-Bis(diphenylphosphino)ethylene Asreported 983-81-3 5g $686 2026-06-03 Buy
Product number Packaging Price Buy
287970 1g $79.6 Buy
B2003 1g $68 Buy
267119 1g $336 Buy
267119 2g $468 Buy
267119 5g $686 Buy

TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powde

Uses

Catalyst for:

  • Coupling of primary and secondary alkyl halides with aryl grignard reagents
  • Homogeneous hydrogenation of Carbon Dioxide mediated by Ruthenium

Reactant for:
  • Preparation of cyclopalladated derivatives of benzylidene
  • Preparation of cyclopalladated complexes containing tridentate thiosemicarbazone ligands as antimalarial agents
  • Catalytic asymetric intramolecular hydroamination of alkynylamines

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE Preparation Products And Raw materials

Raw materials

Preparation Products

TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE Suppliers

Global( 113)Suppliers
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Neostar United (Changzhou) Industrial Co., Ltd.
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Alfa Chemistry
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Henan Research New Materials Co., Ltd.
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Henan Allgreen Chemical Co.,LTD
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Hebei Chuanghai Biotechnology Co., Ltd
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Amadis Chemical Company Limited
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Mainchem Co., Ltd. +86-0592-6210733 sale@mainchem.com China 32343 55
Henan Research New Material Co., Ltd. 86-18903931531 18903931628 sales036@researchvip.com China 178 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE (E)-1,2-Bis(diphenylphosphino)ethene [(E)-1,2-Ethenediyl]bis(diphenylphosphine) [(E)-Ethene-1,2-diyl]bis(diphenylphosphine) [(E)-Vinylene]bis(diphenylphosphine) trans-vinylenebis[diphenylphosphine] trans-1,2-Bis(diphenylphosphino)ethylene,97% NSC 132587 trans-1,2-Ethenediylbis(diphenylphosphine) (E)-1,2-Bis(diphenylphosphanyl)ethene [(E)-2-diphenylphosphinoethenyl]-diphenylphosphine trans-1,2-Bis(diphenylphosphino)ethylene > Phosphine, 1,1'-(1E)-1,2-ethenediylbis[1,1-diphenyl- [(E)-2-diphenylphosphanylethenyl]-diphenylphosphane trans-1,2-Bis(diphenylphosphino)ethylene (E)-1,2-Bis(diphenylphosphanyl)ethene - [B90366] 983-81-3 C26H22P2 Phosphine Ligands Catalysis and Inorganic Chemistry Phosphorus Compounds Polydentate Phosphine Ligands Ligand Phosphine Ligands Synthetic Organic Chemistry Catalysis and Inorganic Chemistry Phosphorus Compounds Polydentate Phosphine Ligands