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5-BROMOBENZO[B]THIOPHENE

CAS No.
4923-87-9
Chemical Name:
5-BROMOBENZO[B]THIOPHENE
Synonyms
5-BROMO-1-BENZOTHIOPHENE;BUTTPARK 98\04-80;Bromobenzothiophene;5-Bromothianaphthene;5-BROMOBENZO[B]THIOP;5-Bromobenzopyrazole;5-Bromobenzobüthiophene;5-BROMOBENZO[B]THIOPHENE;Benzo[b]thiophene, 5-broMo-;5-Bromobenzo[b]thiophene >
CBNumber:
CB4183466
Molecular Formula:
C8H5BrS
Molecular Weight:
213.09
MDL Number:
MFCD03069318
MOL File:
4923-87-9.mol
MSDS File:
SDS
Last updated:2026-01-12 17:28:22
Product description Number Pack Size Price
5-Bromobenzo[b]thiophene >98.0%(GC) B3762 1g $21
5-Bromobenzo[b]thiophene >98.0%(GC) B3762 5g $63
5-Bromobenzo[b]thiophene B680425 2.5g $85
5-Bromobenzothiophene 95+% 073024 5g $90
5-Bromobenzo[b]thiophene FB62210 1g $120
More product size

5-BROMOBENZO[B]THIOPHENE Properties

Melting point 47-48°C
Boiling point 105-107°C 10mm
Density 1.649±0.06 g/cm3(Predicted)
Flash point 105-107°C/10mm
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility soluble in Toluene
form powder to crystal
color White to Light yellow to Light orange
Sensitive Light Sensitive
BRN 112878
InChI InChI=1S/C8H5BrS/c9-7-1-2-8-6(5-7)3-4-10-8/h1-5H
InChIKey RDSIMGKJEYNNLF-UHFFFAOYSA-N
SMILES C12=CC=C(Br)C=C1C=CS2
CAS DataBase Reference 4923-87-9(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
Hazard Note  Irritant
HS Code  29349990
NFPA 704
1
2 0

5-BROMOBENZO[B]THIOPHENE price More Price(39)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical B3762 5-Bromobenzo[b]thiophene >98.0%(GC) 4923-87-9 1g $21 2025-07-31 Buy
TCI Chemical B3762 5-Bromobenzo[b]thiophene >98.0%(GC) 4923-87-9 5g $63 2025-07-31 Buy
TRC B680425 5-Bromobenzo[b]thiophene 4923-87-9 2.5g $85 2021-12-16 Buy
Matrix Scientific 073024 5-Bromobenzothiophene 95+% 4923-87-9 5g $90 2021-12-16 Buy
Biosynth Carbosynth FB62210 5-Bromobenzo[b]thiophene 4923-87-9 1g $120 2021-12-16 Buy
Product number Packaging Price Buy
B3762 1g $21 Buy
B3762 5g $63 Buy
B680425 2.5g $85 Buy
073024 5g $90 Buy
FB62210 1g $120 Buy

5-BROMOBENZO[B]THIOPHENE Chemical Properties,Uses,Production

Chemical Properties

white solid

Uses

5-Bromobenzo[b]thiophene is used as a reactant in the preparation of 4-aminoquinolines and tetraoxanes displaying antimalarial activity.

Synthesis Reference(s)

Journal of Heterocyclic Chemistry, 25, p. 1271, 1988 DOI: 10.1002/jhet.5570250445

Synthesis

A mixture of phosphoric acid (218 g) and chlorobenzene (2 L) was heated at 130C and then treated with the product from Example 165A (107.0 g) for 2 hours using a syringe pump. The mixture was heated at 130C for 15 hours. Water was removed from the mixture using a Dean-Stark trap at the start of reflux. The mixture was cooled to room temperature and quenched with 400 mL of water. The bottom aqueous layer was extracted with 200 mL of dichloromethane. The combined organic layers were washed with 200 mL of 10% Na2CO3 and concentrated to a brown oil (129.4 g). The crude oil was dissolved in 1 L of 10:90 EtOAC:hexane, filtered through a short pad of silica gel and concentrated. Further purification by column chromatography (silica gel, 5:95EtOAc:hexane) afforded 5-bromobenzo[b]thiophene yellow oil in yield (85.54 g, 95.8%).

105126-89-4
4923-87-9
Synthesis of 5-BROMOBENZO[B]THIOPHENE from Acetaldehyde, 2-[(4-bromophenyl)thio]-

5-BROMOBENZO[B]THIOPHENE Preparation Products And Raw materials

Global( 272)Suppliers
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Xi'an Yutbon Pharmaceutical Technology Co., Ltd
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8485655694 sales@alchempharmtech.com United States 63687 58
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View Lastest Price from 5-BROMOBENZO[B]THIOPHENE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
5-BROMOBENZO[B]THIOPHENE  pictures 2025-11-18 5-BROMOBENZO[B]THIOPHENE
4923-87-9
US $1.10 / g 1g 99.00% 100 Tons Dideu Industries Group Limited
 5-BROMOBENZO[B]THIOPHENE pictures 2019-07-06 5-BROMOBENZO[B]THIOPHENE
4923-87-9
US $1.00 / KG 1KG 98% 1ton Career Henan Chemical Co

5-BROMOBENZO[B]THIOPHENE Spectrum

5-BROMO-1-BENZOTHIOPHENE 5-BROMOBENZO[B]THIOPHENE BUTTPARK 98\04-80 5-Bromothianaphthene 5-BromobenzoÄbÜthiophene,98+% 5-BROMOBENZO[B]THIOPHENE, 98+% 5-Bromobenzobüthiophene, 98+% Benzo[b]thiophene, 5-broMo- 5-Bromo-1-benzothiophene, 5-Bromothianaphthene Bromobenzothiophene 5-Bromobenzobüthiophene 5-BROMOBENZO[B]THIOP Brexpiprazole Impurity 5-bromobenzo[b]thiophene 5-Bromobenzo[b]thiophene > 5-BROMOBENZO[B]THIOPHENE ISO 9001:2015 REACH 5-Bromobenzothiophene in isooctane 5-Bromobenzopyrazole 4923-87-9 4923-78-9 Heterocycle-oher series Thiophenes & Benzothiophenes Thiophenes & Benzothiophenes Benzothiophene Halogenated Organohalides Heterocycles series Halides