3-Bromo-1-benzothiophene
- CAS No.
- 7342-82-7
- Chemical Name:
- 3-Bromo-1-benzothiophene
- Synonyms
- 3-BROMOBENZO[B]THIOPHENE;3-BROMOBENZOTHIOPHENE;3-BROMOTHIANAPHTHENE;BUTTPARK 147\16-62;Bromothianaphthene;TIMTEC-BB SBB003415;3-BROMO-1-BENZOTHIOPHENE;3-BroMothianaphthene 95%;3-Bromo-1-benzothiophenec;Benzo[b]thiophene, 3-broMo-
- CBNumber:
- CB7246607
- Molecular Formula:
- C8H5BrS
- Molecular Weight:
- 213.1
- MDL Number:
- MFCD00023009
- MOL File:
- 7342-82-7.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 146-156 °C |
|---|---|
| Boiling point | 269 °C/752.5 mmHg (lit.) |
| Density | 1.629 g/mL at 25 °C (lit.) |
| refractive index |
n |
| Flash point | >230 °F |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | Sparingly Soluble (0.14 g/L) (25°C). |
| form | clear liquid |
| color | Light yellow to Brown |
| InChI | InChI=1S/C8H5BrS/c9-7-5-10-8-4-2-1-3-6(7)8/h1-5H |
| InChIKey | SRWDQSRTOOMPMO-UHFFFAOYSA-N |
| SMILES | C12=CC=CC=C1C(Br)=CS2 |
| CAS DataBase Reference | 7342-82-7(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzo[b]thiophene, 3-bromo-,(7342-82-7) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319 | |||||||||
| Precautionary statements | P264-P280a-P305+P351+P338-P321-P332+P313-P337+P313 | |||||||||
| PPE | Eyeshields, Gloves, type N95 (US) | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-37/39 | |||||||||
| WGK Germany | 3 | |||||||||
| HazardClass | IRRITANT | |||||||||
| HS Code | 29349990 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| NFPA 704 |
|
3-Bromo-1-benzothiophene price More Price(82)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 494976 | 3-Bromothianaphthene 95% | 7342-82-7 | 5ml | $91.4 | 2026-04-30 | Buy |
| Sigma-Aldrich | 494976 | 3-Bromothianaphthene 95% | 7342-82-7 | 25ml | $317 | 2026-04-30 | Buy |
| TCI Chemical | B5589 | 3-Bromobenzo[b]thiophene >96.0%(GC) | 7342-82-7 | 5g | $55 | 2026-04-30 | Buy |
| TCI Chemical | B5589 | 3-Bromobenzo[b]thiophene >96.0%(GC) | 7342-82-7 | 25g | $219 | 2026-04-30 | Buy |
| Apolloscientific | OR23177 | 3-Bromobenzo[b]thiophene 97% | 7342-82-7 | 5g | $21 | 2026-06-04 | Buy |
3-Bromo-1-benzothiophene Chemical Properties, Uses, Production
Chemical Properties
Colorless to yellow to red liquid
Uses
Antifungal activity of synthetic di (hetero) arylamines based on the benzo [b] thiophene moiety.
Uses
3-Bromothianaphthene may be used in the synthesis of (benzo[b]thiophen-3-yl)trimethylstannane.
General Description
3-Bromothianaphthene is a heteroaryl halide. It undergoes Suzuki-Miyaura reaction with phenylboronic acid (PBA) or 3-thienylboronic acid in the presence of a novel heterogeneous Pd catalyst [Pd@PDEB, PDEB=poly(1,3-diethynylbenzene)]. The substitution reaction of 3-bromothianaphthene with piperidine to form 3-piperidinothianaphthene as the major product has been reported.
Synthesis
![2,3-Dibromobenzo[b]thiophene](/CAS/GIF/6287-82-7.gif)
6287-82-7
7342-82-7
The general procedure for the synthesis of 3-bromobenzothiophene from 2,3-dibromothiophene was as follows: first, the halogenated heterocycle (0.66 mmol) was dissolved in anhydrous THF (13.2 mL) and degassed by drumming in argon for a few minutes. Subsequently, PdCl2 (dppf) (27.0 mg, 0.033 mmol, 5.0 mol%), TMEDA (0.130 g, 1.12 mmol, 1.7 equiv) and NaBH4 (42.4 mg, 1.12 mmol, 1.7 equiv) were added sequentially. The reaction mixture was stirred at room temperature for appropriate time under argon protection and finally post-treated according to standard methods.
References
[1] Journal of Organic Chemistry, 2012, vol. 77, # 21, p. 9921 - 9925,5
[2] Journal of Molecular Catalysis A: Chemical, 2014, vol. 393, p. 191 - 209
[3] Patent: WO2015/188790, 2015, A1. Location in patent: Page/Page column 22
3-Bromo-1-benzothiophene Preparation Products And Raw materials
Raw materials
1of3
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Wuping Biological Technology Co., Ltd. | 18501609135 | 182517690@qq.com | China | 237 | 55 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Capot Chemical Co., Ltd | +86 (0) 571 85 58 67 18 | China | 18187 | 66 | |
| Beijing Ouhe Technology Co., Ltd | 13552068683 13522913783 | 2355560935@qq.com | China | 11777 | 60 |
| Nanjing Habo Medical Technology Co., Ltd. | 13376080562 13376090521 | sales@habotech.com | China | 724 | 60 |
| Adamas Reagent, Ltd. | 400-6009262 15618770481 | yhx@titansci.com | China | 14098 | 59 |
| Accela ChemBio Co.,Ltd. | 021-50795510 4000665055 | marketing@accelachem.com | China | 10972 | 64 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
View Latest Price from 3-Bromo-1-benzothiophene manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-08-20 | 3-Bromo-1-benzothiophene
7342-82-7
|
$1.10 | 1g | 99.00% | 100 Tons | Dideu Industries Group Limited | |
 |
2026-06-24 | 3-Bromo-1-benzothiophene
7342-82-7
|
$1.00 | 1kg | 99.5-99.9 | 20tons | Zhejiang Free Trade Zone Violet Trade Co., Ltd. | |
 |
2026-02-02 | 3-Bromo-1-benzothiophenec
7342-82-7
|
$1.00 | 1g | 99% | 50tons | Shaanxi Dideu Medichem Co. Ltd |
-
- 3-Bromo-1-benzothiophene
7342-82-7
- $1.10
- 99.00%
- Dideu Industries Group Limited
-
- 3-Bromo-1-benzothiophene
7342-82-7
- $1.00
- 99.5-99.9
- Zhejiang Free Trade Zone Violet Trade Co., Ltd.
-
- 3-Bromo-1-benzothiophenec
7342-82-7
- $1.00
- 99%
- Shaanxi Dideu Medichem Co. Ltd
