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N-TERT-BUTYLTRIMETHYLSILYLAMINE

CAS No.
5577-67-3
Chemical Name:
N-TERT-BUTYLTRIMETHYLSILYLAMINE
Synonyms
tert-C4H9NHSi(CH3)3;t-Butylamino Trimethylsilane;TERT-BUTYLAMINOTRIMETHYLSILANE;TERT-BUTYL TRIMETHYLSILYLAMINE;N-TERT-BUTYLTRIMETHYLSILYLAMINE;(Trimethylsilyl)(tert-butyl)amine;N-(TRIMETHYLSILYL)-TERT-BUTYLAMINE;N-(tert-Butyl)(trimethyl)silanamine;N-tert-Butyltrimethylsilylamine 98%;N-tert-butyl-1,1,1-trimethylsilanamine
CBNumber:
CB4185743
Molecular Formula:
C7H19NSi
Molecular Weight:
145.32
MDL Number:
MFCD00054891
MOL File:
5577-67-3.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 01:48:06
Product description Number Pack Size Price
N-tert-Butyltrimethylsilylamine 98% 369330 25g $163
N-tert-Butyltrimethylsilylamine 95% OR939298 5g $21
N-tert-Butyltrimethylsilylamine 95% OR939298 25g $47
N-tert-Butyltrimethylsilylamine 95% OR939298 100g $138
N-tert-Butyltrimethylsilylamine 95% OR939298 500g $433

N-TERT-BUTYLTRIMETHYLSILYLAMINE Properties

Boiling point 118-119 °C(lit.)
Density 0.762 g/mL at 25 °C(lit.)
refractive index n20/D 1.406(lit.)
Flash point 80 °F
form liquid
pka 13.25±0.70(Predicted)
color Clear, colourless
BRN 1734528
InChI 1S/C7H19NSi/c1-7(2,3)8-9(4,5)6/h8H,1-6H3
InChIKey GVHIREZHTRULPT-UHFFFAOYSA-N
SMILES CC(C)(C)N[Si](C)(C)C
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Corrosion (GHS05)
GHS02,GHS05
Signal word  Danger
Hazard statements  H226-H314
Precautionary statements  P280-P305+P351+P338-P310
PPE Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Codes  C
Risk Statements  10-34
Safety Statements  16-26-36/37/39-45
RIDADR  UN 2733 3/PG 3
WGK Germany  3
10-21
HazardClass  3.2
PackingGroup  III
HS Code  2931900090
Storage Class 3 - Flammable liquids
Hazard Classifications Flam. Liq. 3
Skin Corr. 1B
REACH Registrations Active

N-TERT-BUTYLTRIMETHYLSILYLAMINE price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 369330 N-tert-Butyltrimethylsilylamine 98% 5577-67-3 25g $163 2026-04-30 Buy
Apolloscientific OR939298 N-tert-Butyltrimethylsilylamine 95% 5577-67-3 5g $21 2026-06-04 Buy
Apolloscientific OR939298 N-tert-Butyltrimethylsilylamine 95% 5577-67-3 25g $47 2026-06-04 Buy
Apolloscientific OR939298 N-tert-Butyltrimethylsilylamine 95% 5577-67-3 100g $138 2026-06-04 Buy
Apolloscientific OR939298 N-tert-Butyltrimethylsilylamine 95% 5577-67-3 500g $433 2026-06-04 Buy
Product number Packaging Price Buy
369330 25g $163 Buy
OR939298 5g $21 Buy
OR939298 25g $47 Buy
OR939298 100g $138 Buy
OR939298 500g $433 Buy

N-TERT-BUTYLTRIMETHYLSILYLAMINE Chemical Properties,Uses,Production

Uses

N-tert-Butyltrimethylsilylamine may be used in the preparation of selenium and tellurium chalcogenides and the facile synthesis of N-alkylaminomethylphosphonates.

Preparation

N-tert-Butyltrimethylsilylamine is prepared by the reaction of the parent amines with n-Butyllithium in THF/hexane. The parent amines are prepared by the reaction of lithium t-butylamide and the corresponding chlorosilanes (eq 1).
N-TERT-BUTYLTRIMETHYLSILYLAMINE synthesis route

General Description

N-tert-Butyltrimethylsilylamine (Me3SiNH-t-Bu) reacts with [Cp*Rh(H2O)3](OTf)2 in acetone to yield a hydroxyl-capped half-cubane [Cp*3Rh3(μ-OH)3(μ3-OH)](OTf)3(t-BuNH3).

storage

N-tert-Butyltrimethylsilylamine reacts readily with protic solvents, especially water, and must be maintained in a dry environment. It is thermally stable. Use in a fume hood.

Purification Methods

Best purified by distillation.

N-TERT-BUTYLTRIMETHYLSILYLAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

N-TERT-BUTYLTRIMETHYLSILYLAMINE Suppliers

Global( 57)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Daken Advanced Materials Co.,Ltd
+86-2158073036 info@dakenam.com China 14032 58
Shaanxi Dideu Medichem Co. Ltd
+86-29-87569266 +86-17392581500 1015@dideu.com China 3861 58
Nanjing Doge Biomedical Technology Co., Ltd
+86-25-58227606 +86-15305155328 sales@dogechemical.com China 4124 58
ShenZhen Trendseen Biological Technology Co.,Ltd.
13417589054 trendseenbio@gmail.com China 11674 58
HANGZHOU LEAP CHEM CO., LTD.
+86-571-87711850 +86-15355479329 market18@leapchem.com China 43303 58
Aladdin Scientific
tp@aladdinsci.com United States 57473 58
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.
+8618950047208 ellena@amitychem.com China 43392 58
DAYANG CHEM (HANGZHOU) CO.,LTD
+86-88938639 +86-17705817739 info@dycnchem.com China 53799 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
TERT-BUTYL TRIMETHYLSILYLAMINE N-TERT-BUTYLTRIMETHYLSILYLAMINE N-(TRIMETHYLSILYL)-TERT-BUTYLAMINE Silanamine,N-(1,1-dimethylethyl)-1,1,1-trimethyl- TERT-BUTYLAMINOTRIMETHYLSILANE N-tert-Butyltrimethylsilylamine 98% N-(tert-Butyl)(trimethyl)silanamine tert-C4H9NHSi(CH3)3 (Trimethylsilyl)(tert-butyl)amine N-(Trimethylsilyl)-2-methyl-2-propanamine 2-methyl-N-trimethylsilylpropan-2-amine N-(1,1-Dimethylethyl)-1,1,1-trimethylsilanamine t-Butylamino Trimethylsilane N-tert-butyl-1,1,1-trimethylsilanamine N-tert-Butyltrimethylsilylamine 5577-67-3 CH33SiNHCCH33 Protected Amines Organic Building Blocks Nitrogen Compounds Building Blocks Building Blocks Chemical Synthesis Nitrogen Compounds Organic Building Blocks Protected Amines