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ChemicalBook >> CAS DataBase List >>[2,6-Dimethyl-4-(phenylmethoxy)phenyl]boronic acid

[2,6-Dimethyl-4-(phenylmethoxy)phenyl]boronic acid

[2,6-Dimethyl-4-(phenylmethoxy)phenyl]boronic acid Structure
[2,6-Dimethyl-4-(phenylmethoxy)phenyl]boronic acid structure
CAS No.
865139-18-0
Chemical Name:
[2,6-Dimethyl-4-(phenylmethoxy)phenyl]boronic acid
Synonyms
865139-18-0;4-(benzyloxy)-2,6-dimethylphenylboronic acid;[2,6-Dimethyl-4-(phenylmethoxy)phenyl]boronic acid;Boronic acid, B-[2,6-dimethyl-4-(phenylmethoxy)phenyl]-
CBNumber:
CB42470979
Molecular Formula:
C15H17BO3
Molecular Weight:
256.1
MDL Number:
MOL File:
865139-18-0.mol
MSDS File:
SDS
Last updated:2026-05-28 01:28:46
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[2,6-Dimethyl-4-(phenylmethoxy)phenyl]boronic acid Properties

Boiling point 452.6±55.0 °C(Predicted)
Density 1.15
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
pka 8.85±0.58(Predicted)
Appearance White to off-white Solid

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338

[2,6-Dimethyl-4-(phenylmethoxy)phenyl]boronic acid price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
aablocks AA00H287 [2,6-Dimethyl-4-(phenylmethoxy)phenyl]boronic acid 97% 865139-18-0 1g $22 2026-05-28 Buy
aablocks AA00H287 [2,6-Dimethyl-4-(phenylmethoxy)phenyl]boronic acid 97% 865139-18-0 5g $79 2026-05-28 Buy
ACHEMBLOCK W159000 (4-(Benzyloxy)-2,6-dimethylphenyl)boronic acid 97% 865139-18-0 5G $100 2026-05-27 Buy
ACHEMBLOCK W159000 (4-(Benzyloxy)-2,6-dimethylphenyl)boronic acid 97% 865139-18-0 25G $335 2026-05-27 Buy
Crysdot CD12022482 (4-(Benzyloxy)-2,6-dimethylphenyl)boronic acid 95+% 865139-18-0 1g $248 2026-05-27 Buy
Product number Packaging Price Buy
AA00H287 1g $22 Buy
AA00H287 5g $79 Buy
W159000 5G $100 Buy
W159000 25G $335 Buy
CD12022482 1g $248 Buy

[2,6-Dimethyl-4-(phenylmethoxy)phenyl]boronic acid Chemical Properties, Uses, Production

Synthesis

(4-BROMO-3,5-DIMETHYL)PHENYL BENZYL ETHER

95741-44-9

[2,6-Dimethyl-4-(phenylmethoxy)phenyl]boronic acid

865139-18-0

The general procedure for the synthesis of 2,6-dimethyl-4-benzyloxyphenylboronic acid from (4-bromo-3,5-dimethyl)phenylbenzyl ether was as follows: 5-(benzyloxy)-2-bromo-1,3-dimethylbenzene (12a, 2.91 g, 10 mmol, prepared by the method disclosed in the patent application) was dissolved in a dry ice bath in 35 mL of anhydrous tetrahydrofuran, followed by a slow addition of n butyl lithium (4.8 mL, 12 mmol). The reaction mixture was stirred in a dry ice bath for 1.5 h. Tripropyl borate (5.64 g, 30 mmol) was added, and then the reaction system was gradually warmed to 30 °C and stirred continuously for 12 h. The reaction mixture was then stirred in a dry ice bath for 1.5 h. Upon completion of the reaction, 10 mL of 2M hydrochloric acid was slowly added dropwise to the reaction solution, followed by cooling the mixture to room temperature and continued stirring for 2 hours. The resulting mixture was concentrated under reduced pressure and the solid was collected by filtration. The solid was washed sequentially with 10 mL of water and 10 mL of hexane to afford 2,6-dimethyl-4-benzyloxyphenylboronic acid (4-(benzyloxy)-2,6-dimethylphenylboronic acid, 12b, 1.54 g, 60.2% yield) as a white solid. Mass spectrum (ESI) m/z: 257.2 [M + 1].

References

[1] Patent: EP2803664, 2014, A1. Location in patent: Paragraph 0158; 0159
[2] Patent: EP1726580, 2006, A1. Location in patent: Page/Page column 117
[3] Patent: WO2013/144098, 2013, A1. Location in patent: Page/Page column 140

[2,6-Dimethyl-4-(phenylmethoxy)phenyl]boronic acid Preparation Products And Raw materials

Raw materials

(4-Bromo-3,5-dimethyl)phenyl benzyl ether n-Butyllithium Tetrahydrofuran Tripropyl borate

Preparation Products

[2,6-Dimethyl-4-(phenylmethoxy)phenyl]boronic acid Suppliers

Global Suppliers ( 37)
Supplier Tel Email Country ProdList Advantage
DKD Shijiazhuang Chemical Co., Ltd. 0311-67790228 15531158659 2361184479@qq.com China 300 62
Shanghai HuanChuan Industry Co.,Ltd. 021-61478794 sales@hcshhai.com China 9781 50
Shanghai Changyan Chem & Tech Co., Ltd. 021-20242659 18930833303 sales@changyanchem.cn China 4998 55
parabiochem 025-83453382-8005 sale@parabiochem.com China 9577 55
Amadis Chemical Company Limited 571-89925085 sales@amadischem.com China 131885 58
Wuxi AppTec 022-59987777 13552403979 jia_guoqiang@wuxiapptec.com China 22344 58
Aikon International Limited 025-58859352 15955137747 sales01@aikonchem.com China 16021 58
Nanjing ChemLin Chemical Industry Co., Ltd. 025-83453327 product@chemlin.com.cn China 276 58
Shanghai Jizhi Biochemical Technology Co. Ltd. 021-4009004166/18616739031 18616739031 3007523370@qq.com China 40000 58
CD Chemical Group Limited +86-13651442114 info@codchem.com China 17253 58
Supplier Advantage
DKD Shijiazhuang Chemical Co., Ltd. 62
Shanghai HuanChuan Industry Co.,Ltd. 50
Shanghai Changyan Chem & Tech Co., Ltd. 55
parabiochem 55
Amadis Chemical Company Limited 58
Wuxi AppTec 58
Aikon International Limited 58
Nanjing ChemLin Chemical Industry Co., Ltd. 58
Shanghai Jizhi Biochemical Technology Co. Ltd. 58
CD Chemical Group Limited 58

[2,6-Dimethyl-4-(phenylmethoxy)phenyl]boronic acid Spectrum

[2,6-Dimethyl-4-(phenylmethoxy)phenyl]boronic acid(865139-18-0)1HNMR

865139-18-0 ([2,6-Dimethyl-4-(phenylmethoxy)phenyl]boronic acid) Related Search:

4-Benzyloxybenzeneboronic acid 4-Benzyloxy-2-methylphenylboronic acid 4-Benzyloxy-2-formylphenylboronic acid 1,3,2-Dioxaborolane, 2-[2,6-dimethyl-4-(phenylmethoxy)phenyl]-4,4,5,5-tetramethyl- (4-(Benzyloxy)-2,3-dimethylphenyl)boronic acid
4-(Benzyloxy)-2-ethylphenylboronic acid

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[2,6-Dimethyl-4-(phenylmethoxy)phenyl]boronic acid 4-(benzyloxy)-2,6-dimethylphenylboronic acid Boronic acid, B-[2,6-dimethyl-4-(phenylmethoxy)phenyl]- 865139-18-0 865139-18-0