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Chloro[tri(o-tolyl)phosphine]gold(I)

CAS No.
83076-07-7
Chemical Name:
Chloro[tri(o-tolyl)phosphine]gold(I)
Synonyms
Chloro(tri-o-tolylphosphine)gold;Chloro(tris(2-tolyl)phosphine)gold;Chloro[tris(o-tolyl)phosphine]gold;(Tri-o-tolylphosphine)gold chloride;Chloro[tri(o-tolyl)phosphine]gold(I);chloro-tris(2-methylphenyl)phosphanium;Chloro(tri(2-methylphenyl)phosphine)gold;Chloro[tri(o-tolyl)phosphine]gold(I),95%;Chloro[tris(o-methylphenyl)phosphine]gold;Chloro[tris(2-methylphenyl)phosphine]gold
CBNumber:
CB42512499
Molecular Formula:
C21H20AuClP+
Molecular Weight:
535.776811
MDL Number:
MFCD14155882
MOL File:
83076-07-7.mol
MSDS File:
SDS
Last updated:2026-05-28 02:14:27

Chloro[tri(o-tolyl)phosphine]gold(I) Properties

storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form solid
Appearance White to off-white Solid
InChI 1S/C21H21P.Au.ClH/c1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3;;/h4-15H,1-3H3;;1H/q;+1;/p-1
InChIKey VECXLHSTZNCQLD-UHFFFAOYSA-M
SMILES Cl[Au].Cc1ccccc1P(c2ccccc2C)c3ccccc3C
UNSPSC Code 12352300

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338
target organs Respiratory system
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
WGK Germany  3
Storage Class 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

Chloro[tri(o-tolyl)phosphine]gold(I) price More Price(18)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 717460 Chloro[tri(o-tolyl)phosphine]gold(I) 95% 83076-07-7 500mg $138 2022-05-15 Buy
aablocks AA003OQ6 Chloro[tri(o-tolyl)phosphine]gold(I) 95% 83076-07-7 100mg $42 2026-05-28 Buy
aablocks AA003OQ6 Chloro[tri(o-tolyl)phosphine]gold(I) 95% 83076-07-7 250mg $67 2026-05-28 Buy
aablocks AA003OQ6 Chloro[tri(o-tolyl)phosphine]gold(I) 95% 83076-07-7 1g $152 2026-05-28 Buy
ACHEMBLOCK W168034 Chloro[tri(o-tolyl)phosphine]gold(I) 97% 83076-07-7 1G $245 2026-05-27 Buy
Product number Packaging Price Buy
717460 500mg $138 Buy
AA003OQ6 100mg $42 Buy
AA003OQ6 250mg $67 Buy
AA003OQ6 1g $152 Buy
W168034 1G $245 Buy

Chloro[tri(o-tolyl)phosphine]gold(I) Chemical Properties, Uses, Production

Uses

Gold Catalysts — 21st Century ′Gold Rush′
Catalyst for:

  • Alkylation of silyl enol ethers with orthoalkynylbenzoic acid esters
  • Cycloisomerization
  • Cyclization of 1,6-enynes
  • Tandem [3,3]-sigmatropic rearrangement-cycloisomerization cascade
  • Cycloaddition of enyne derivatives with aryl alkynes or alkenes

reaction suitability

core: gold
reagent type: catalyst

Chloro[tri(o-tolyl)phosphine]gold(I) Preparation Products And Raw materials

Raw materials

Preparation Products

Chloro[tri(o-tolyl)phosphine]gold(I) Suppliers

Global Suppliers ( 54)
Supplier Tel Email Country ProdList Advantage
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Nanjin Cynthia chemicals Technology Co.,Ltd 0550-5618439 15951861180 cynthiachem@163.com China 291 62
Chengdu Ai Keda Chemical Technology Co., Ltd. 4008-755-333 18080918076 800078821@qq.com China 9706 55
Shanghai Jian Chao Chemical Technology Co., Ltd. 150-2103-5486 18017383231 983544897@qq.com China 9336 55
Shanghai Aladdin Bio-Chem Technology Co.,LTD 400-6206333 13167063860 anhua.mao@aladdin-e.com China 29985 65
Amatek Scientific Co. Ltd. 0512-56316828 4008675858 sales@amateksci.com China 9849 55
Bide Pharmatech Ltd. 400-164-7117 18317119277 product02@bidepharm.com China 40000 60
Alfa Chemistry 1-516-6625404 support@alfa-chemistry.com United States 9170 60
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 0371-65511006 18625597674 info@kingorgchem.com;sales@kingorgchem.com China 806 55
Chloro[tri(o-tolyl)phosphine]gold(I),95% Chloro[tri(o-tolyl)phosphine]gold(I) (Tri-o-tolylphosphine)gold chloride Chloro(tri(2-methylphenyl)phosphine)gold Chloro(tri-o-tolylphosphine)gold Chloro(tris(2-tolyl)phosphine)gold Chloro[tris(2-methylphenyl)phosphine]gold Chloro[tris(o-methylphenyl)phosphine]gold Chloro[tris(o-tolyl)phosphine]gold Tris(2-methylphenyl)phosphinegold chloride chloro-tris(2-methylphenyl)phosphanium Chloro[tri(o-tolyl)phosphine]gold(I) 83076-07-7 C21H21AuClP Au