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4-Chloro-1,3-benzenediamine

4-Chloro-1,3-benzenediamine Structure
4-Chloro-1,3-benzenediamine structure
CAS No.
5131-60-2
Chemical Name:
4-Chloro-1,3-benzenediamine
Synonyms
ci76027;4-Cl-m-Pd;c.i.76027;C.I. 76027;NCI-C03305;p-Chlor-m-fenylendiamin;3-Amino-4-chloroaniline;2,4-DIAMINOCHLOROBENZENE;4-chloro-3-benzenediamine;4-Chlorophene-1,3-diamine
CBNumber:
CB4370455
Molecular Formula:
C6H7ClN2
Molecular Weight:
142.59
MDL Number:
MFCD00025284
MOL File:
5131-60-2.mol
MSDS File:
SDS
Last updated:2026-01-13 11:21:52
Product description Number Pack Size Price
4-Chloro-1,3-phenylenediamine >98.0%(GC)(T) C0710 5g $67
4-Chloro-1,3-phenylenediamine >98.0%(GC)(T) C0710 25g $195
4-Chlorobenzene-1,3-diamine >95% 126772 10g $180
4-Chlorobenzene-1,3-diamine >95% 126772 1g $36
4-Chloro-m-phenylenediamine F770 5g $89
More product size
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4-Chloro-1,3-benzenediamine Properties

Melting point 87-90 °C (lit.)
Boiling point 232.49°C (rough estimate)
Density 1.2124 (rough estimate)
refractive index 1.5210 (estimate)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
pka 3.95±0.10(Predicted)
form powder to crystal
color White to Gray to Brown
Water Solubility <0.1 g/100 mL at 19 ºC
InChI 1S/C6H7ClN2/c7-5-2-1-4(8)3-6(5)9/h1-3H,8-9H2
InChIKey ZWUBBMDHSZDNTA-UHFFFAOYSA-N
SMILES Nc1ccc(Cl)c(N)c1
Toxicology and Carcinogenesis Bioassay of 4-Chloro-m-phenylenediamine for Possible Carcinogenicity (CASRN 5131-60-2)
CAS DataBase Reference 5131-60-2(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 46M6FQ5PJK
IARC 3 (Vol. 27, Sup 7) 1987
NIST Chemistry Reference 1,3-Benzenediamine, 4-chloro-(5131-60-2)
EPA Substance Registry System 4-Chloro-m-p.henylenediamine (5131-60-2)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs Respiratory system
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
RIDADR  UN 1673 6.1/PG 3
WGK Germany  3
RTECS  SS8800000
TSCA  TSCA listed
HazardClass  6.1
PackingGroup  III
HS Code  29215900
Storage Class 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazardous Substances Data 5131-60-2(Hazardous Substances Data)
NFPA 704
0
2 0

4-Chloro-1,3-benzenediamine price More Price(16)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical C0710 4-Chloro-1,3-phenylenediamine >98.0%(GC)(T) 5131-60-2 5g $67 2026-03-19 Buy
TCI Chemical C0710 4-Chloro-1,3-phenylenediamine >98.0%(GC)(T) 5131-60-2 25g $195 2026-03-19 Buy
Matrix Scientific 126772 4-Chlorobenzene-1,3-diamine >95% 5131-60-2 10g $180 2021-12-16 Buy
Matrix Scientific 126772 4-Chlorobenzene-1,3-diamine >95% 5131-60-2 1g $36 2021-12-16 Buy
AK Scientific F770 4-Chloro-m-phenylenediamine 5131-60-2 5g $89 2021-12-16 Buy
Product number Packaging Price Buy
C0710 5g $67 Buy
C0710 25g $195 Buy
126772 10g $180 Buy
126772 1g $36 Buy
F770 5g $89 Buy

4-Chloro-1,3-benzenediamine Chemical Properties,Uses,Production

Chemical Properties

Crystals. Soluble in ethanol; slightly soluble in water; insoluble in petroleum ether.

Uses

This compound has uses in dye production and in rubber processing.

Uses

4-Chloro-1,3-diaminobenzene has been used to study the mutagenic effect of phenylenediamines hair chemicals on Salmonella typhimurium TA 102.

Definition

ChEBI: 4-Chloro-meta-phenylenediamine is a member of monochlorobenzenes.

General Description

Gray powder or dark purple solid.

Air & Water Reactions

4-Chloro-1,3-benzenediamine is sensitive to prolonged exposure to light and air. Insoluble in water.

Reactivity Profile

Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.

Health Hazard

ACUTE/CHRONIC HAZARDS: 4-Chloro-1,3-benzenediamine is a positive animal carcinogen and suspected human carcinogen.

Fire Hazard

Flash point data for 4-Chloro-1,3-benzenediamine are not available; however, 4-Chloro-1,3-benzenediamine is probably combustible.

Safety Profile

Suspected carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl and NOx. See also AROMATIC AMINES.

Synthesis

2-Chloro-5-nitro-benzamine

6283-25-6

4-Chloro-1,3-benzenediamine

5131-60-2

General method: 2-chloro-5-nitroaniline (1 mmol), Pd/C (5% w/w) and methanol (5 mL) were mixed in a reaction vial and hydrazine hydrate (10 mmol) was added to the mixture. The reaction system was heated at reflux at 80 °C for 5 min. Upon completion of the reaction, the mixture was filtered while hot to remove the catalyst and the filtrate was concentrated under reduced pressure to remove the solvent. The crude product was purified by fast column chromatography to give 4-chloro-1,3-benzenediamine.

References

[1] RSC Advances, 2016, vol. 6, # 23, p. 19331 - 19340
[2] Synlett, 2014, vol. 25, # 10, p. 1403 - 1408
[3] Patent: WO2006/40568, 2006, A1. Location in patent: Page/Page column 70
[4] Catalysis Communications, 2016, vol. 84, p. 25 - 29

4-Chloro-1,3-benzenediamine Preparation Products And Raw materials

Raw materials

2,4-Dinitrochlorobenzene 2-Chloro-5-nitro-benzamine 4-Chloroaniline Methanol Palladium
Activated carbon Hydrazine hydrate

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Preparation Products

Chromate(3-), bis[3-[[2-(amino-κN)-4-amino-5-chlorophenyl]azo-κN1]-2-(hydroxy-κO)-5-nitrobenzenesulfonato(3-)]-, disodium hydrogen Direct Black 11 MORDANT BROWN 48 N-(3-Amino-4-chlorophenyl)-2,2-dimethylpropanamide

4-Chloro-1,3-benzenediamine Suppliers

Global( 168)Suppliers
Supplier Tel Email Country ProdList Advantage
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD 		+86-13017695106 +86-13676922317 jiuyitime@fdachem.com China 16513 58
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 33024 60
Changzhou Ansciep Chemical Co., Ltd. 		+86 519 86305871 sales@ansciepchem.com CHINA 4241 58
CONIER CHEM AND PHARMA LIMITED 		+8618523575427 sales@conier.com China 49977 58
career henan chemical co 		+86-0371-86658258 +8613203830695 factory@coreychem.com China 29794 58
Fuxin Pharmaceutical 		+86-021-021-50872116 +8613122107989 contact@fuxinpharm.com China 10000 58
Hefei TNJ Chemical Industry Co.,Ltd. 		+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34563 58
Win-Win chemical CO., Limited 		+86-0086-577-64498589 +86-15355981851 sales@win-winchemical.com China 14306 58
ANHUI WITOP BIOTECH CO., LTD 		+8615255079626 eric@witopchemical.com China 23541 58
Wuhan Fortuna Chemical Co., Ltd 		+86-27-59207850 info@fortunachem.com China 5972 58
Supplier Advantage
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD 		58
ATK CHEMICAL COMPANY LIMITED 		60
Changzhou Ansciep Chemical Co., Ltd. 		58
CONIER CHEM AND PHARMA LIMITED 		58
career henan chemical co 		58
Fuxin Pharmaceutical 		58
Hefei TNJ Chemical Industry Co.,Ltd. 		58
Win-Win chemical CO., Limited 		58
ANHUI WITOP BIOTECH CO., LTD 		58
Wuhan Fortuna Chemical Co., Ltd 		58

View Lastest Price from 4-Chloro-1,3-benzenediamine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4clmpd pictures 2026-04-13 4clmpd
US $600.00 / KG 1G 99.8% 500kg .GZ HONESTCHEM CO.,LTD
4CLMPD pictures 2026-04-13 4CLMPD
US $1.00 / KG 1G 99.9% 500KG .GZ HONESTCHEM CO.,LTD
4-Chloro-1,3-benzenediamine pictures 2026-04-10 4-Chloro-1,3-benzenediamine
5131-60-2
 US $0.00 / KG 1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
  • 4clmpd pictures
  • 4clmpd
  • US $600.00 / KG
  • 99.8%
  • .GZ HONESTCHEM CO.,LTD
  • 4CLMPD pictures
  • 4CLMPD
  • US $1.00 / KG
  • 99.9%
  • .GZ HONESTCHEM CO.,LTD

4-Chloro-1,3-benzenediamine Spectrum

4-Chloro-1,3-benzenediamine(5131-60-2)MS4-Chloro-1,3-benzenediamine(5131-60-2)1HNMR4-Chloro-1,3-benzenediamine(5131-60-2)IR14-Chloro-1,3-benzenediamine(5131-60-2)IR2

5131-60-2(4-Chloro-1,3-benzenediamine)Related Search:

p-Phenylenediamine o-Phenylenediamine Benzene-1,3-diamine dihydrochloride 1,3-Phenylenediamine sulfate Diphenyl chlorophosphate
m-Phenylenediamine Tetrachloroterephthalonitrile Benzhydrylamine 2,4-Dinitrochlorobenzene 2-Chloro-3,5-dinitrobenzotrifluoride
1,3,5-trichloro-2,4-dinitrobenzene 4-CHLORO-6-METHYL-M-PHENYLENE DIISOCYANATE 1,3-DICHLORO-2,4,6-TRINITROBENZENE 2-Chloro-5-nitro-benzamine MORDANT BROWN 48
2,4-DICHLORO-3,5-DINITROBENZOIC ACID Difluorochloromethane 2-Chloro-3,5-dinitrobenzoic acid

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1,3-benzenediamine,-chloro- 1-Chloro-2,4-Diaminobenzene 4-Chloro-1,3-benzenediamine 4-chloro-3-benzenediamine 4-Chloro-meta-phenylenediamine 4-chloro-m-phenylenediamin 4-Chlorophene-1,3-diamine 4-Chlorophenylene-1,3-diamine 4-Cl-m-Pd C.I. 76027 c.i.76027 ci76027 m-Phenylenediamine, 4-chloro- NCI-C03305 p-Chlor-m-fenylendiamin p-Chloro-m-phenylenediamine 3-amino-8-chloro-5H-phenanthridin-6-one 2,4-DIAMINOCHLOROBENZENE 4-CHLORO-3-PHENYLENEDIAMINE 4-CHLORO-1,3-PHENYLENEDIAMINE 4-CHLORO-M-PHENYLENEDIAMINE 4-chlorobenzene-1,3-diamine 4-Chloro-3-Phenylenediamine,>95% 1,3-DIAMINO-4-CHLOROBENZENE 4-Chloro-1,3-diaminobenzene 3-Amino-4-chloroaniline 1-Chlorobenzene-2,4-diamine 4-Chloro-m-phenylenediamine,97% 2,4-Diaminochlorobenzene 1,3-Diamino-4-chlorobenzene sulfuric acid compound with 3-amino-4-chlorophenylamine (1:1) 4-Chloro-1,3-phenylenediamine > 1,3-Benzenediamine, 4-chloro- 4-Chloro-1,3-phenylenediamine, ≥ 98.0% 4-Chloro-m-phenylenediamine, 98% 5131-60-2 Building Blocks Polyamines Organic Building Blocks Nitrogen Compounds