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Methyl cyclopropane carboxylate

Methyl cyclopropane carboxylate Structure
Methyl cyclopropane carboxylate structure
CAS No.
2868-37-3
Chemical Name:
Methyl cyclopropane carboxylate
Synonyms
METHYL CYCLOPROPANECARBOXYLATE;MCPC;Methyl cyclopropylcarboxylate;CYCLOPROPANECARBOXYLIC ACID METHYL ESTER;Cyclopropyl methyl ester;RARECHEM AL BF 0553;Methyl cyclopropanoate;Lenvatinib Impurity 67;Methylcyclopropancarboxylat;methylcyclopropylcarboxylate
CBNumber:
CB4435543
Molecular Formula:
C5H8O2
Molecular Weight:
100.12
MDL Number:
MFCD00001280
MOL File:
2868-37-3.mol
MSDS File:
SDS
Last updated:2026-05-28 03:08:30
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Methyl cyclopropane carboxylate Properties

Boiling point 119 °C/764 mmHg (lit.)
Density 0.985 g/mL at 25 °C (lit.)
refractive index n20/D 1.419(lit.)
Flash point 64 °F
storage temp. Store below +30°C.
solubility Chloroform (Sparingly), Methanol (Slightly)
form Liquid
Specific Gravity 0.980.985
color Clear colorless
Water Solubility Not miscible or difficult to mix in water.
BRN 2039388
Henry's Law Constant 4.1×10-1 mol/(m3Pa) at 25℃, Bagno et al. (1991)
InChI 1S/C5H8O2/c1-7-5(6)4-2-3-4/h4H,2-3H2,1H3
InChIKey PKAHQJNJPDVTDP-UHFFFAOYSA-N
SMILES COC(=O)C1CC1
CAS DataBase Reference 2868-37-3(CAS DataBase Reference)
FDA UNII 5UQ53F585U
NIST Chemistry Reference Cyclopropanecarboxylic acid, methyl ester(2868-37-3)
EPA Substance Registry System Cyclopropanecarboxylic acid, methyl ester (2868-37-3)
UNSPSC Code 12352108
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Skull and Crossbones (GHS06)
GHS02,GHS06
Signal word  Danger
Hazard statements  H225-H302-H311-H319
Precautionary statements  P210-P233-P280-P301+P312-P303+P361+P353-P305+P351+P338
PPE Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  F,Xn
Risk Statements  11-21/22-36
Safety Statements  16-26-36-9-33-29
RIDADR  UN 1992 3/PG 2
WGK Germany  3
RTECS  GZ2017500
Autoignition Temperature 435 °C
TSCA  TSCA listed
HazardClass  3
PackingGroup  II
HS Code  29162000
Storage Class 3 - Flammable liquids
Hazard Classifications Acute Tox. 3 Dermal
Acute Tox. 4 Oral
Eye Irrit. 2
Flam. Liq. 2
REACH Registrations Active
Limited Quantities 1.0 L (0.3 gallon) (liquid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
NFPA 704
3
2 0

Methyl cyclopropane carboxylate price More Price(39)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.41225 Methyl cyclopropanecarboxylate for synthesis 2868-37-3 25mL $95.2 2026-04-30 Buy
TCI Chemical C1607 Methyl Cyclopropanecarboxylate >97.0%(GC) 2868-37-3 25mL $26 2026-04-30 Buy
TCI Chemical C1607 Methyl Cyclopropanecarboxylate >97.0%(GC) 2868-37-3 250mL $140 2026-04-30 Buy
TRC TRC-M294710-50G Methyl Cyclopropane Carboxylate 2868-37-3 50g $281 2026-06-03 Buy
TRC TRC-M294710-10G Methyl Cyclopropane Carboxylate 2868-37-3 10g $186 2026-06-03 Buy
Product number Packaging Price Buy
8.41225 25mL $95.2 Buy
C1607 25mL $26 Buy
C1607 250mL $140 Buy
TRC-M294710-50G 50g $281 Buy
TRC-M294710-10G 10g $186 Buy

Methyl cyclopropane carboxylate Chemical Properties, Uses, Production

Chemical Properties

CLEAR COLOURLESS LIQUID

Uses

Methyl cyclopropane carboxylate is used as a reagent in the synthesis of N’thiazole and N-pyrazole based inhibitors of MAP kinase p38α.

Uses

It is primarily used an intermediate in the manufacture of pharmaceutical and agrochemical products. Methyl cyclopropane carboxylate is used as a reagent in the synthesis of N-thiazole and N-pyrazole based inhibitors of MAP kinase p38α.

Definition

ChEBI: Methyl cyclopropanecarboxylate is a methyl ester derived from cyclopropanecarboxylic acid. It is a methyl ester and a member of cyclopropanes. It is functionally related to a cyclopropanecarboxylic acid.

Synthesis Reference(s)

Tetrahedron Letters, 9, p. 4545, 1968 DOI: 10.1016/S0040-4039(01)99181-6

Methyl cyclopropane carboxylate synthesis

29006-01-7
2868-37-3
Synthesis of Methyl cyclopropane carboxylate from Methyl 4-methoxybutanoate

Methyl cyclopropane carboxylate Preparation Products And Raw materials

Raw materials

dimethyl 5,5-dimethylpyrazole-3,4-dicarboxylate Methyl 4-bromobutyrate Methyl 4-chlorobutyrate Methanol Cyclopropanecarboxylic acid
Dibromomethane Methyl acetate Propargyl alcohol 1,1-Cyclopropanedicarboxylic acid Sodium Methoxide

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Preparation Products

5-Cyclopropyl-2H-pyrazol-3-ylamine Cyclopropyl 2-fluorobenzyl ketone

Methyl cyclopropane carboxylate Suppliers

Global Suppliers ( 352)
Supplier Tel Email Country ProdList Advantage
Zhejiang zetian fine chemical co. LTD 0571-87322520 18957127338 June@zetchem.com China 382 58
Zhejiang Karry Pharmachem Co., Ltd. 19157666807 info@karrypharma.com China 37 58
Shandong Chengwu Zeda General Chemical Co., Ltd. 057186770761 zhedapanaco02@zhedachem.com China 171 58
Weifang QianJin Fine Chemical Co., Ltd. 18753684562 1577399715@qq.COM China 1772 55
Shanghai Boyle Chemical Co., Ltd. 021-50182298 021-50180596 sales@boylechem.com China 2202 55
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Supplier Advantage
Zhejiang zetian fine chemical co. LTD 58
Zhejiang Karry Pharmachem Co., Ltd. 58
Shandong Chengwu Zeda General Chemical Co., Ltd. 58
Weifang QianJin Fine Chemical Co., Ltd. 55
Shanghai Boyle Chemical Co., Ltd. 55
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
Alfa Aesar 84
TCI (Shanghai) Development Co., Ltd. 81
Energy Chemical 61

View Latest Price from Methyl cyclopropane carboxylate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Methyl Cyclopropane Carboxylate pictures 2026-05-28 Methyl Cyclopropane Carboxylate
2868-37-3
 $2.00-5.00 1KG 99% 10000kg Hebei Chuanghai Biotechnology Co,.LTD
Methyl cyclopropane carboxylate pictures 2025-06-20 Methyl cyclopropane carboxylate
2868-37-3
 1kg 99% 100tons Hebei Yanxi Chemical Co., Ltd.
Methyl cyclopropane carboxylate pictures 2025-05-26 Methyl cyclopropane carboxylate
2868-37-3
 $30.00 1kg 0.99 100 tons Hebei Fengjia New Material Co., Ltd

Methyl cyclopropane carboxylate Spectrum

Methyl cyclopropane carboxylate(2868-37-3)MSMethyl cyclopropane carboxylate(2868-37-3)1HNMRMethyl cyclopropane carboxylate(2868-37-3)13CNMRMethyl cyclopropane carboxylate(2868-37-3)IR1Methyl cyclopropane carboxylate(2868-37-3)Raman

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RARECHEM AL BF 0553 lMethyl cyclopropane carboxylate Methylcyclopropancarboxylat MEHTYLCYCLOPROPANECARBOXYLATE methylcyclopropylcarboxylate METHYL CYCLOPROPANECARBOXYLATE, 99+% Cyclopropane-1-carboxylic acid methyl ester cyclopropane carboxylate methyl ester Methyl cyclopropanecarboxylate,98% 1-Methylcyclopropane-1-carboxylate Methyl cyclopropanecarboxylate, 98% 100GR Methyl Cyclopropyl Corboxylate Methylecyclopropanecarboxylate METHYL CYCLOPROPANE-1-CARBOXYLATE METHYL CYCLOPROPANE CARBOXYLIC ACID Methyl cyclopropanoate Methyl Cyclopropanecarboxylate > METHYL CYCLOPROPANECARBOXYLATE FOR SYNTH Cyclopropyl methyl ester Lenvatinib Impurity 67 METHYL CYCLOPROPANE CARBOXYLATE 2868-37-3 methyl cyclopropanecarboxylate - [M86382] Methyl cyclopropylcarboxylate CYCLOPROPANECARBOXYLIC ACID METHYL ESTER MCPC METHYL CYCLOPROPANECARBOXYLATE 2868-37-3 2868-37-4 C3H5CO2CH3 Building Blocks Cyclopropanes Simple 3-Membered Ring Compounds Organic Building Blocks Esters C2 to C5 Carbonyl Compounds Cyclopropanes Simple 3-Membered Ring Compounds Pharmaceutical Intermediates Fine Chemical