1-Bromohexane
- CAS No.
- 111-25-1
- Chemical Name:
- 1-Bromohexane
- Synonyms
- N-HEXYL BROMIDE;Bromohexane;N-BROMOHEXANE;HEXYL BROMIDE;Hexylbromid;1-Bromohexane 98% For Synthesis;1-Bromhexan;1-bromo-hexan;1-BROMOHEXANE;JACS-111-25-1
- CBNumber:
- CB4447030
- Molecular Formula:
- C6H13Br
- Molecular Weight:
- 165.07
- MDL Number:
- MFCD00000271
- MOL File:
- 111-25-1.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | −85 °C(lit.) |
|---|---|
| Boiling point | 154-158 °C(lit.) |
| Density | 1.176 g/mL at 25 °C(lit.) |
| vapor density | 5.7 (vs air) |
| vapor pressure | <10 mm Hg ( 20 °C) |
| refractive index |
n |
| Flash point | 135 °F |
| storage temp. | Store below +30°C. |
| solubility | <1g/l |
| form | Liquid |
| color | Clear |
| Water Solubility | Immiscible with water. |
| Thermal Conductivity | 0.108 W/(m·K) at 25 ℃ |
| Specific Heat Capacity | Cp(liquid): 1.24 J/(g·K), at 25℃ |
| BRN | 1731290 |
| Henry's Law Constant | 3.0×10-4 mol/(m3Pa) at 25℃, Duchowicz et al. (2020) |
| Dielectric constant | 5.8(24℃) |
| Stability | Stable. Incompatible with strong oxidizing agents, strong bases. Combustible. |
| InChI | 1S/C6H13Br/c1-2-3-4-5-6-7/h2-6H2,1H3 |
| InChIKey | MNDIARAMWBIKFW-UHFFFAOYSA-N |
| SMILES | CCCCCCBr |
| CAS DataBase Reference | 111-25-1(CAS DataBase Reference) |
| FDA UNII | WVA0FAX7GA |
| NIST Chemistry Reference | Hexane, 1-bromo-(111-25-1) |
| EPA Substance Registry System | Hexane, 1-bromo- (111-25-1) |
| UNSPSC Code | 12352101 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS02,GHS07,GHS09 |
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|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H303-H315-H319-H411-H226 | |||||||||
| Precautionary statements | P501-P273-P240-P210-P233-P243-P241-P242-P264-P280-P370+P378-P312-P391-P337+P313-P305+P351+P338-P362+P364-P303+P361+P353-P332+P313-P403+P235 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | Eyeshields, Gloves, type ABEK (EN14387) respirator filter | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38-10 | |||||||||
| Safety Statements | 26-36-16 | |||||||||
| RIDADR | UN 1993 3/PG 3 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | MO0925000 | |||||||||
| TSCA | TSCA listed | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29033036 | |||||||||
| Storage Class | 3 - Flammable liquids | |||||||||
| Hazard Classifications | Eye Irrit. 2 Flam. Liq. 3 Skin Irrit. 2 STOT SE 3 |
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| Toxicity | LD50 orally in Rabbit: > 2000 mg/kg | |||||||||
| REACH Registrations | Active | |||||||||
| Limited Quantities | 5.0 L (1.3 gallons) (liquid) | |||||||||
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L) | |||||||||
| NFPA 704 |
|
1-Bromohexane price More Price(34)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | B68240 | 1-Bromohexane 98% | 111-25-1 | 100g | $25.8 | 2026-04-30 | Buy |
| Sigma-Aldrich | B68240 | 1-Bromohexane 98% | 111-25-1 | 1kg | $188 | 2026-04-30 | Buy |
| Sigma-Aldrich | 8.01603 | 1-Bromohexane for synthesis | 111-25-1 | 100mL | $43.8 | 2026-04-30 | Buy |
| Sigma-Aldrich | 8.01603 | 1-Bromohexane for synthesis | 111-25-1 | 500mL | $73.6 | 2026-04-30 | Buy |
| TCI Chemical | B0600 | 1-Bromohexane >98.0%(GC) | 111-25-1 | 25g | $43 | 2026-04-30 | Buy |
1-Bromohexane Chemical Properties, Uses, Production
Chemical nature
1-Bromohexane is organobromine compound with formula Br(CH2)5CH3. It is a colorless liquid.
Synthesis and reactions
Most 1-bromoalkanes are prepared by free-radical addition of hydrogen bromide to the 1-alkene. These conditions lead to anti-Markovnikov addition, giving the 1-bromo derivative.
1-Bromohexane undergoes reactions expected of simple alkyl bromides. It can form Grignard reagents. It reacts with potassium fluoride to give the corresponding fluorocarbons.
Chemical Properties
1-Bromohexane is a colourless liquid organohalide. It is a solvent that is frequently used in grignard reactions. It is also used as Intermediate, for introduction of hexyl group.
Uses
1-Bromohexane is utilized in the preparation of pharmaceuticals and organic chemicals. It is involved in Grignard reactions as an alkylating agent and in the synthesis of bromo-cyclic compounds.
Application
1-Bromohexane is a very useful synthetic intermediate，it can be used to react with Mg to prepare Grignard reagents which play an important role in formation of carbon-carbon bond.
Synthesis Reference(s)
Chemistry Letters, 7, p. 833, 1978
Synthetic Communications, 6, p. 21, 1976 DOI: 10.1080/00397917608062128
Tetrahedron, 40, p. 641, 1984 DOI: 10.1016/S0040-4020(01)91092-0
Mechanism of action
1-Bromohexane is a nucleophilic reagent, which reacts with electrophiles (electron-rich molecules) to form a new bond.
Purification Methods
Shake the bromide with H2SO4, wash with water, dry (K2CO3) and fractionally distil. [Beilstein 1 IV 352.]
1-Bromohexane Preparation Products And Raw materials
Raw materials
Preparation Products
1of3
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Yancheng Longshen Chemical Co.,Ltd. | 0515-88718898 18352070236 | 2355801706@qq.com | China | 100 | 60 |
| Huaian yishu technology co.,ltd | 0517-85883738; 13852390259 | sales@yishuchem.com | China | 58 | 58 |
| CHANGZHOU XINYOU GOODS AND MAT | 0519-88861658 15351933796 | 601763459@qq.com | China | 37 | 58 |
| Shouguang Tongshun Chemical Co., Ltd | 13792625218 | 2103858215@qq.com | China | 64 | 58 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Beijing dtftchem Technology Co., Ltd. | 010-60275820 13031183356 | elainezt@sina.com | China | 1386 | 62 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Capot Chemical Co., Ltd | +86 (0) 571 85 58 67 18 | China | 18187 | 66 |
View Latest Price from 1-Bromohexane manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-09-14 | 1-Bromohexane
111-25-1
|
1KG | ≥99% | 50 Tons/Month | Yancheng Longshen Chemical Co.,Ltd. | ||
 |
2026-09-02 | 1-Bromohexane
111-25-1
|
$1.00-100.00 | 1KG | 99% | Henan Fengda Chemical Co., Ltd | ||
 |
2026-05-28 | bromohexane
111-25-1
|
$19.00 | 1KG | 99.% | 10 ton | Hebei Chuanghai Biotechnology Co,.LTD |
-
- 1-Bromohexane
111-25-1
- $0.00
- ≥99%
- Yancheng Longshen Chemical Co.,Ltd.
-
- 1-Bromohexane
111-25-1
- $1.00-100.00
- 99%
- Henan Fengda Chemical Co., Ltd
-
- bromohexane
111-25-1
- $19.00
- 99.%
- Hebei Chuanghai Biotechnology Co,.LTD
