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ChemicalBook >> CAS DataBase List >>(R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, min. 95% CTH-(R)-3,5-xylyl-phanephos

(R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, min. 95% CTH-(R)-3,5-xylyl-phanephos

(R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, min. 95% CTH-(R)-3,5-xylyl-phanephos Structure
(R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, min. 95% CTH-(R)-3,5-xylyl-phanephos structure
CAS No.
325168-89-6
Chemical Name:
(R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, min. 95% CTH-(R)-3,5-xylyl-phanephos
Synonyms
(R)-XylPhanePHOS;(R)-Xylyl-PHANEPhos;(R)-5,11-Bis(3,5-xylylphosphino)tricyclo[8.2.24,7]hexadeca-hexaene;(R)-(–)-4,12-Bis[di(3,5-xylyl)phosphino]-[2.2]-paracyclophane;(R)-4,12-Bis(1,1-bis(3,5-dimethylphenyl)phosphine)-[2.2]paracyclophane;(R)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE ,CTH-(S)-3,5-XYLYL-PHANEPHOS;(R)-Xylyl-PHANEPhos, (R)-5,11-Bis(3,5-xylylphosphino)tricyclo[8.2.2.24,7]hexadeca-hexaene;(R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, min. 95% CTH-(R)-3,5-xylyl-phanephos;(R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, Min. 97% CTH-(R)-3,5-xylyl-PHANEPHOS;Phosphine, 1,1'-tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene-5,11-diylbis[1,1-bis(3,5-dimethylphenyl)-, stereoisomer
CBNumber:
CB4634847
Molecular Formula:
C48H50P2
Molecular Weight:
688.86
MDL Number:
MFCD03840578
MOL File:
325168-89-6.mol
MSDS File:
SDS
Last updated:2026-09-12 18:52:55
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(R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, min. 95% CTH-(R)-3,5-xylyl-phanephos Properties

Melting point 234-238 °C
Boiling point 785.2±60.0 °C(Predicted)
form Powder
color white
optical activity [α]22/D -61.0, c = 0.1 in ethanol
InChIKey LYHOBZAADXPPNW-UHFFFAOYSA-N
SMILES Cc1cc(C)cc(c1)P(c2cc(C)cc(C)c2)c3cc4CCc5ccc(CCc3cc4)cc5P(c6cc(C)cc(C)c6)c7cc(C)cc(C)c7
UNSPSC Code 12352002
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xi
Risk Statements  36/38
Safety Statements  26
WGK Germany  3
Storage Class 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2

(R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, min. 95% CTH-(R)-3,5-xylyl-phanephos price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 682306 (R)-(–)-4,12-Bis[di(3,5-xylyl)phosphino]-[2.2]-paracyclophane 95% 325168-89-6 100mg $137 2023-06-20 Buy
Sigma-Aldrich 682306 (R)-(–)-4,12-Bis[di(3,5-xylyl)phosphino]-[2.2]-paracyclophane 95% 325168-89-6 500mg $543 2023-06-20 Buy
Strem Chemicals 15-0730 (R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, min. 97% CTH-(R)-3,5-xylyl-PHANEPHOS min.97% 325168-89-6 100mg $113 2026-04-30 Buy
Strem Chemicals 15-0730 (R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, min. 97% CTH-(R)-3,5-xylyl-PHANEPHOS min.97% 325168-89-6 500mg $443 2026-04-30 Buy
aablocks AA003C0E (R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane 98% 325168-89-6 100mg $272 2026-05-28 Buy
Product number Packaging Price Buy
682306 100mg $137 Buy
682306 500mg $543 Buy
15-0730 100mg $113 Buy
15-0730 500mg $443 Buy
AA003C0E 100mg $272 Buy

(R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, min. 95% CTH-(R)-3,5-xylyl-phanephos Chemical Properties,Uses,Production

Reaction

  1. Chiral ligand employed in the enantioselective hydrogenation of various ketones.
  2. Chiral ligand employed in the enantioselective hydroxycarbonylation and alkoxycarbonylation of alkenes.
  3. Chiral ligand employed in the enantioselective [2+2] cycloaddition of oxabicyclic alkenes with terminal alkynes.
  4. Chiral ligand employed in the gold-catalyzed enantioselective Cope rearrangement of achiral 1,5-dienes.
Reactions of 325168-89-6

Uses

Efficient ligand for asymmetric hydrogenation of dehydroamino acids, methyl esters and ketones.

(R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, min. 95% CTH-(R)-3,5-xylyl-phanephos Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, min. 95% CTH-(R)-3,5-xylyl-phanephos Suppliers

Global( 33)Suppliers
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Beijing Guofang Dingsheng Technology Co., Ltd. 18610472091 gfdskj@163.com China 496 58
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51389 80
Shanghai Chiral bio-compound co., Ltd. 021-5068 3667/17749785980/1029026415; 17749785980 1029026415@qq.com China 4501 58
Shanghai Xilong Biochemical Technology Co., Ltd. 021-52907766-8042 China 9928 58
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 0371-65511006 18625597674 info@kingorgchem.com;sales@kingorgchem.com China 806 55
Greenherbs Science and Technology Development Co., Ltd. 010-61136123 pub02@greenherbs.com.cn China 4045 58
Aikon International Limited 025-58859352 15955137747 sales01@aikonchem.com China 16021 58
Supplier Advantage
J & K SCIENTIFIC LTD. 76
Alfa Aesar 84
Energy Chemical 61
Beijing Guofang Dingsheng Technology Co., Ltd. 58
Sigma-Aldrich 80
Shanghai Chiral bio-compound co., Ltd. 58
Shanghai Xilong Biochemical Technology Co., Ltd. 58
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 55
Greenherbs Science and Technology Development Co., Ltd. 58
Aikon International Limited 58

325168-89-6((R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, min. 95% CTH-(R)-3,5-xylyl-phanephos)Related Search:

Parylene N (R)-(-)-4,12-Bis(diphenylphosphino)-(2.2)-paracyclophane (R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane (S)-(+)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane ,CTH-(S)-3,5-xylyl-phanephos (R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane
(R)-An-Phanephos

1of2

(R)-Xylyl-PHANEPhos, (R)-5,11-Bis(3,5-xylylphosphino)tricyclo[8.2.2.24,7]hexadeca-hexaene (R)-5,11-Bis(3,5-xylylphosphino)tricyclo[8.2.24,7]hexadeca-hexaene (R)-Xylyl-PHANEPhos (R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, Min. 97% CTH-(R)-3,5-xylyl-PHANEPHOS (R)-XylPhanePHOS (R)-4,12-Bis(1,1-bis(3,5-dimethylphenyl)phosphine)-[2.2]paracyclophane Phosphine, 1,1'-tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene-5,11-diylbis[1,1-bis(3,5-dimethylphenyl)-, stereoisomer (R)-(–)-4,12-Bis[di(3,5-xylyl)phosphino]-[2.2]-paracyclophane (R)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE ,CTH-(S)-3,5-XYLYL-PHANEPHOS (R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, min. 95% CTH-(R)-3,5-xylyl-phanephos 325168-89-6 PHANEPhos Series Chiral Phosphine organophosphine ligand