Chinese Japanese Germany Korea
ChemicalBook >> CAS DataBase List >>1,12-BENZOPERYLENE

1,12-BENZOPERYLENE

1,12-BENZOPERYLENE Structure
1,12-BENZOPERYLENE structure
CAS No.
191-24-2
Chemical Name:
1,12-BENZOPERYLENE
Synonyms
BENZO[GHI]PERYLENE;1,12-Benzperylene;Benzo[g;RMA-308;hi]peryL;NSC 89275;Benzo(g.h.i)p;Benzo[ghi]peryL;Benzo[ghi]Pyrene;6,7-Ethenoperylene
CBNumber:
CB4708830
Molecular Formula:
C22H12
Molecular Weight:
276.33
MDL Number:
MFCD00004135
MOL File:
191-24-2.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-06-04 16:00:12
Product description Number Pack Size Price
Benzo[ghi]perylene 98% B9009 25mg $183
Benzo[ghi]perylene 98% B9009 100mg $530
Benzo[ghi]perylene certified reference material, TraceCERT 55488 10mg $391
Benzo[ghi]perylene analytical standard 48491 25mg $108
Benzo[ghi]perylene solution certified reference material, 200?μg/mL in dichloromethane 48667 1mL $28.3
More product size
Request For Quotation

1,12-BENZOPERYLENE Properties

Melting point 277-279 °C(lit.)
Boiling point >500 °C(lit.)
Density 1.1847 (estimate)
vapor pressure 1.10 (extrapolated from vapor pressures determined at higher temperatures, Pupp et al., 1974)1.04 (Murray et al., 1974)
refractive index 1.9800 (estimate)
Flash point -18 °C
storage temp. room temp
solubility Soluble in most solvents (U.S. EPA, 1985) including benzene, methylene chloride, and acetone.
pka >15 (Christensen et al., 1975)
form Needle-Like Crystals or Crystalline Powder
color Yellow
Water Solubility 0.137ug/L(25 ºC)
BRN 1913029
Henry's Law Constant 1.88, 2.66, 5.13, 5.33, 6.51, and 8.59 at 10.0, 20.0, 35.0, 40.1, 45.0, and 55.0 °C, respectively (wetted-wall column, ten Hulscher et al., 1992)
Stability Stable. Combustible. Incompatible with strong oxidizing agents.
InChI 1S/C22H12/c1-3-13-7-9-15-11-12-16-10-8-14-4-2-6-18-17(5-1)19(13)21(15)22(16)20(14)18/h1-12H
InChIKey GYFAGKUZYNFMBN-UHFFFAOYSA-N
SMILES c1cc2ccc3ccc4ccc5cccc6c(c1)c2c3c4c56
Substances of Very High Concern (SVHC) Candidate List Benzo[ghi]perylene (191-24-2)
REACH Annex XVII Substances List Benzo[ghi]perylene (191-24-2)
FDA UNII 5ZME2E2Q9L
IARC 3 (Vol. 92, Sup 7) 2010
EPA Substance Registry System Benzo[g,h,i]perylene (191-24-2)
UNSPSC Code 41116107
NACRES NA.24

SAFETY

Risk and Safety Statements

Symbol(GHS)  Environment (GHS09)
GHS09
Signal word  Warning
Hazard statements  H410
Precautionary statements  P273-P391-P501
Hazard Codes  N,Xn,F
Risk Statements  50/53-40-67-65-38-11-36/37/38-20
Safety Statements  60-61-36/37-24/25-23-62-33-25-16-9
RIDADR  UN 3077 9/PG 3
WGK Germany  3
RTECS  DI6200500
F  8-10
HazardClass  9
PackingGroup  III
HS Code  29029090
Storage Class 11 - Combustible Solids
Hazard Classifications Aquatic Acute 1
Aquatic Chronic 1
Hazardous Substances Data 191-24-2(Hazardous Substances Data)
Toxicity mma-sat 2 mg/plate/48H FCTXAV 17,141,79
Limited Quantities 5.0 kg (11 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)

1,12-BENZOPERYLENE price More Price(59)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich B9009 Benzo[ghi]perylene 98% 191-24-2 25mg $183 2026-04-30 Buy
Sigma-Aldrich B9009 Benzo[ghi]perylene 98% 191-24-2 100mg $530 2026-04-30 Buy
Sigma-Aldrich 55488 Benzo[ghi]perylene certified reference material, TraceCERT 191-24-2 10mg $391 2026-04-30 Buy
Sigma-Aldrich 48491 Benzo[ghi]perylene analytical standard 191-24-2 25mg $108 2026-04-30 Buy
Sigma-Aldrich 48667 Benzo[ghi]perylene solution certified reference material, 200?μg/mL in dichloromethane 191-24-2 1mL $28.3 2022-05-15 Buy
Product number Packaging Price Buy
B9009 25mg $183 Buy
B9009 100mg $530 Buy
55488 10mg $391 Buy
48491 25mg $108 Buy
48667 1mL $28.3 Buy

1,12-BENZOPERYLENE Chemical Properties,Uses,Production

Chemical Properties

solid

Uses

Research chemical. Derived from industrial and experimental coal gasification operations where the maximum concentration detected in coal tar streams was 2.7 mg/m3 (Cleland, 1981).

Uses

An n-channel organic semiconductor.

Definition

ChEBI: Benzo[ghi]perylene is an ortho- and peri-fused polycyclic arene.

General Description

Colorless to white crystalline solid. Water insoluble.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Vigorous reactions, sometimes amounting to explosions, can result from the contact between aromatic hydrocarbons, such as 1,12-BENZOPERYLENE, and strong oxidizing agents. They can react exothermically with bases and with diazo compounds. Substitution at the benzene nucleus occurs by halogenation (acid catalyst), nitration, sulfonation, and the Friedel-Crafts reaction.

Health Hazard

Inhalation of material may be harmful. Contact may cause burns to skin and eyes. Inhalation of Asbestos dust may have a damaging effect on the lungs. Fire may produce irritating, corrosive and/or toxic gases. Some liquids produce vapors that may cause dizziness or suffocation. Runoff from fire control may cause pollution.

Health Hazard

There is very little information available inthe literature on the toxicity of this compound. Benzo[g,h,i]perylene has low oraltoxicity. On the basis of its structural similarities with other carcinogenic polynucleararomatics, this compound is expected to show carcinogenic properties. Such evidence, however, is inadequate at the moment. A histidinereversion–Ames test for mutagenicity gaveinconclusive results.

Fire Hazard

Some may burn but none ignite readily. Containers may explode when heated. Some may be transported hot.

Safety Profile

Questionable carcinogen.Mutation data reported. When heated to decomposition itemits acrid smoke and irritating fumes.

Synthesis

Benzo(G,H,I)perylene can be produced by the reaction of perylene and nitroethylene in 1,2-dichlorobenzene at 175 C.

Carcinogenicity

Subcutaneous or dermal administration (repeated administration and initiation–promotion protocols) of benzo[ghi]perylene to mice gave negative results. Intrapulmonary injection into rats gave results considered to be inadequate for evaluation.

Source

Drinking water standard: No MCLGs or MCLs have been proposed (U.S. EPA, 2000).
Detected in 7 of 8 diesel fuels at concentrations ranging from 0.008 to 0.35 mg/L with a mean value of 0.113 mg/L (Westerholm and Li, 1994). Identified in Kuwait and South Louisiana crude oils at concentrations of <1 and 1.6 ppm, respectively (Pancirov and Brown, 1975) and in fresh motor oil (120 μg/kg) and used motor oil (108.8–289.4 mg/kg) (quoted, Verschueren, 1983). Detected in asphalt fumes at an average concentration of 22.76 ng/m3 (Wang et al., 2001).
The concentration of benzo[ghi]perylene in coal tar and the maximum concentration reported in groundwater at a mid-Atlantic coal tar site were 1,200 and 0.002 mg/L, respectively (Mackay and Gschwend, 2001). Based on laboratory analysis of 7 coal tar samples, benzo[ghi]perylene concentrations ranged from ND to 1,900 ppm (EPRI, 1990). Benzo[ghi]perylene was reported in a high-temperature coal tar pitch used in roofing at concentrations ranging from 754 to 3,980 mg/kg (Malaiyandi et al., 1982).
Nine commercially available creosote samples contained benzo[ghi]perylene at concentrations ranging from 1 to 45 mg/kg (Kohler et al., 2000).
Schauer et al. (2001) measured organic compound emission rates for volatile organic compounds, gas-phase semi-volatile organic compounds, and particle-phase organic compounds from the residential (fireplace) combustion of pine, oak, and eucalyptus. The particle-phase emission rates of benzo[ghi]perylene were 0.437 mg/kg of pine burned and 0.173 mg/kg of eucalyptus burned.
Gas-phase tailpipe emission rates from gasoline-powered automobiles with and without catalytic converters were 0.26 and 10.7 μg/km, respectively (Schauer et al., 2002).

Environmental Fate

Biological. Based on aerobic soil die away test data at 10 to 30 °C, the estimated half-lives ranged from 590 to 650 d (Coover and Sims, 1987).
Groundwater. Based on aerobic soil die away test data at 10 to 30 °C, the estimated half-lives ranged from 3.23 to 3.56 yr (Coover and Sims, 1987).
Photolytic. The atmospheric half-life was estimated to range from 0.321 to 3.21 h (Atkinson, 1987). Behymer and Hites (1985) determined the effect of different substrates on the rate of photooxidation of benzo[ghi]perylene using a rotary photoreactor. The photolytic half-lives of benzo[ghi]perylene using silica gel, alumina, and fly ash were 7.0, 22, and 29 h, respectively.
Chemical/Physical. At influent concentrations of 1.0, 0.1, 0.01, and 0.001 mg/L, the GAC adsorption capacities were 10.7, 4.6, 2.0, and 0.85 mg/g, respectively (Dobbs and Cohen, 1980).

Purification Methods

It forms light green crystals on recrystallisation from *C6H6 or xylene and sublimes at 320-340o/0.05mm [UV: Hopff & Schweizer Helv Chim Acta 42 2315 1959, Clar Chem Ber 65 846 1932, Fluoresc. Spectrum: Bowen & Brocklehurst J Chem Soc 3875 1954]. It also recrystallises from propan-1-ol [Altman & Ginsburg J Chem Soc 466 1959]. The 1,3,5-Trinitrobenzene complex has m 310-313o (deep red crystals from *C6H6), the picrate has m 267-270o (dark red crystals from *C6H6), and the styphnate (2,4,6-trinitroresorcinol complex) has m 234o (wine red crystals from *C6H6). [Beilstein 5 IV 2766.]

Toxics Screening Level

The Initial Threshold Screening Level (ITSL) for benzo(g,h,i)perylene is 13 μg/m3, with annual averaging time.

1,12-BENZOPERYLENE synthesis

625-48-9
198-55-0
191-24-2
Synthesis of 1,12-BENZOPERYLENE from 2-Nitroethanol and Perylene

1,12-BENZOPERYLENE Preparation Products And Raw materials

Raw materials

Preparation Products

2,3,6,7-TETRACHLORONAPHTHALENE

1,12-BENZOPERYLENE Suppliers

Global( 277)Suppliers
Supplier Tel Email Country ProdList Advantage
Hu Bei Jiutian Bio-medical Technology CO.,Ltd
027-88013699 17354350817 Ryan@jiutian-bio.com China 5927 58
Kindchem(Nanjing)Co.,Ltd 		+86-025-025-85281586 18651653755 sales@kindchem.cn China 1225 58
Capot Chemical Co.,Ltd. 		+86-（0）57185586718 +86-13336195806 sales@capot.com China 29626 60
Shanghai Daken Advanced Materials Co.,Ltd 		+86-2158073036 info@dakenam.com China 14032 58
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21531 55
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 32998 60
career henan chemical co 		+86-0371-86658258 sales@coreychem.com China 29766 58
Shanghai Arbor Chemical Co., Ltd. 		021-60451682 act@arborchemical.com CHINA 903 58
TianYuan Pharmaceutical CO.,LTD 		+86-755-23284190 13684996853 sales@tianpharm.com CHINA 304 58
BOC Sciences 		+1-631-485-4226 inquiry@bocsci.com United States 19935 58
Supplier Advantage
Hu Bei Jiutian Bio-medical Technology CO.,Ltd
58
Kindchem(Nanjing)Co.,Ltd 		58
Capot Chemical Co.,Ltd. 		60
Shanghai Daken Advanced Materials Co.,Ltd 		58
Henan Tianfu Chemical Co.,Ltd. 		55
ATK CHEMICAL COMPANY LIMITED 		60
career henan chemical co 		58
Shanghai Arbor Chemical Co., Ltd. 		58
TianYuan Pharmaceutical CO.,LTD 		58
BOC Sciences 		58

View Lastest Price from 1,12-BENZOPERYLENE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Benzo[ghi]perylene pictures 2026-08-13 Benzo[ghi]perylene
191-24-2
 1g 98%min 10kg WUHAN FORTUNA CHEMICAL CO., LTD
1,12-BENZOPERYLENE pictures 2025-04-04 1,12-BENZOPERYLENE
191-24-2
 1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
1,12-BENZOPERYLENE pictures 2024-06-11 1,12-BENZOPERYLENE
191-24-2
 1kg 98% 100 Kindchem(Nanjing)Co.,Ltd

1,12-BENZOPERYLENE Spectrum

1,12-BENZOPERYLENE(191-24-2)MS1,12-BENZOPERYLENE(191-24-2)1HNMR1,12-BENZOPERYLENE(191-24-2)13CNMR1,12-BENZOPERYLENE(191-24-2)IR11,12-BENZOPERYLENE(191-24-2)IR21,12-BENZOPERYLENE(191-24-2)Raman

191-24-2(1,12-BENZOPERYLENE)Related Search:

CORONENE 1,12-BENZOPERYLENE 1.12,2.3,4.5,6.7,8.9,10.11-HEXABENZOCORONENE Perylene Pyrene
BISANTHENE (PHENANTHRENO[1,10,9,8-OPQRA])PERYLENE CIRCOBIPHENYL OVALENE CORONENE (D12) DICORONYLENE
DIBENZO[LMQRS]NAPHTHA[3,2,1,8,7-DEFGH]PHENANTHRO[3,4,5-YZAB]PYRANTHRENE 1-METHYLCORONENE BENZO(G,H,I)PERYLENE D12 TETRABENZO[DEF,LM,GRS,YZ]PYRANTHRENE BENZO[PQR]DINAPHTHO[8,1,2-BCD:2',1',8'-LMN]PERYLENE
ANTHRACENO[2.3-A]CORONENE 1,12-BENZOPERYLENE (13C12) CORONYLOVALENE

1of4

6,7-Ethenoperylene Benzo[ghi]perylene,1,12-Benzoperylene 1.12-Benzoperylene 10mg [191-24-2] Benzo[ghi]Pyrene in methanol Benzo[ghi]perylene, 98+% 100MG benzo[ghl]perylene 30542, Benzo[ghi]perylene (purity) BENZO(G,H,I)PERYLENE, 1X1ML, CH2CL2, 200 UG/ML BENZO(G,H,I)PERYLENE, 25MG, NEAT Benzo[ghi]Pyrene Benzo[ghi]perylene, 98+% benzo[ghi]perylene solution Benzo[ghi]perylene (purity) Benzo[ghi]perylene 98% Benzo(g.h.i)p Benzo[ghi]perylene standard solution BENZO 1,12 PERYLENE NSC 89275 1,12-Benzperylene 1,12-BENZOPERYLENE 2-(4-methyl-1-piperazinyl)-3-phenylpropanoic acid (2,6-dimethylphenyl) ester hydrochloride Benzo[ghi]peryleneSolution,100mg/L,1ml Benzo[ghi]peryleneSolution,10mg/L,2x5ml Benzo(g,h,i)perylene @100 μg/mL in Dichloromethane Benzo(g,h,i)perylene@0.2 mg/mL in CH2Cl2 Benzo(g,h,i)perylene@0.5 mg/mL in Acetonitrile Benzo(g,h,i)perylene @1000 μg/mL in Dichloromethane Benzo[ghi]peryleneSolution,2000mg/L,1ml Benzo(g,h,i)perylene@50 μg/mL in Toluene Benzo[ghi]perylene > Benzo[ghi]peryleneSolution,10mg/L,1ml Benzo[ghi]perylene Standard Benzo[ghi]peryleneSolution,200mg/L,1ml Benzo[ghi]peryleneSolution,50mg/L,1ml Benzo(g,h,i)perylenesolution,500mg/L,1mL Benzo(g,h,i)perylene@1000 μg/mL in p-Dioxane Benzo[ghi]perylene ,97% Benzo[g hi]peryL Benzo[ghi]perylene solution in Acetonitrile/Dichloromethane,100μg/mL Benzo[ghi]peryL Benzo[ghi]perylene,0.97 Benzo[ghi]perylene, 98&plus Benzo[ghi]perylene purum Beno[G,H,I]Perylene Benzo[ghi]perylene-13C6 in n-nonane L20630000ALBenzo[g,h,i]perylenE10μg/mLin Ac L20630000CY Benzo[g,h,i]perylenE10μg/mLin Cy XA20630000ALBenzo[g,h,i]perylenE100μg/mLin A Benzo[g,h,i]perylene 100 μg/ml Cyclohexane C20630000 Benzo[g,h,i]perylene Benzo[ghi]perylene solution Benzo[ghi]perylene RMA-308 Benzo[g,h,i]perylene 10 μg/mL in Acetonitrile Benzo[g,h,i]perylene 10 μg/mL in Cyclohexane BENZO[GHI]PERYLENE 191-24-2