N,N-DiMethylMethyleneaMMoniuM Iodide
- CAS No.
- 33797-51-2
- Chemical Name:
- N,N-DiMethylMethyleneaMMoniuM Iodide
- Synonyms
- ESCHENMOSER'S SALT;N,N-DIMETHYLMETHYLENEIMINIUM IODIDE;N-Methyl-N-MethyleneMethanaMiniuM iodide;eneammonium Iodide;Eschenmoser's salt ,97%;eschenmoser's iodide salt;dimethyl(methylidene)azanium;dimethylmethylammonium iodide;Methylenedimethyliminium·iodide;N, n-dimethyl methylamine iodide
- CBNumber:
- CB4779333
- Molecular Formula:
- C3H8IN
- Molecular Weight:
- 185.01
- MDL Number:
- MFCD00011810
- MOL File:
- 33797-51-2.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Product description | Number | Pack Size | Price |
| N,N-Dimethylmethyleneiminium iodide 98% | 214914 | 10g | $115 |
| N,N-Dimethylmethyleneiminium iodide 98% | 214914 | 50g | $373 |
| N,N-Dimethylmethyleneammonium Iodide >97.0%(T) | D1646 | 5g | $60 |
| N,N-Dimethylmethyleneammonium Iodide >97.0%(T) | D1646 | 25g | $177 |
| N,N-Dimethylmethyleneiminium iodide | D496025 | 500mg | $60 |
| More product size | |||
| Melting point | 219 °C (dec.)(lit.) |
|---|---|
| Density | 1.7217 (estimate) |
| storage temp. | Keep in dark place,Inert atmosphere,2-8°C |
| solubility | Soluble in dimethylformamide. Partially soluble in acetonitrile, tetrahydrofuran and dichloromethane. |
| form | Crystalline Powder |
| color | Cream to yellow |
| Water Solubility | water: soluble 50mg/mL, clear to slightly hazy, colorless to yellow |
| Sensitive | Moisture & Light Sensitive |
| Merck | 14,3251 |
| BRN | 3594966 |
| InChI | InChI=1S/C3H8N.HI/c1-4(2)3;/h1H2,2-3H3;1H/q+1;/p-1 |
| InChIKey | VVDUZZGYBOWDSQ-UHFFFAOYSA-M |
| SMILES | [N+](=C)(C)C.[I-] |
| CAS DataBase Reference | 33797-51-2(CAS DataBase Reference) |
| FDA UNII | 5C42I004S1 |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 8-10-21 | |||||||||
| HS Code | 29239000 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
|||||||||
| NFPA 704 |
|
N,N-DiMethylMethyleneaMMoniuM Iodide price More Price(25)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 214914 | N,N-Dimethylmethyleneiminium iodide 98% | 33797-51-2 | 10g | $115 | 2026-03-19 | Buy |
| Sigma-Aldrich | 214914 | N,N-Dimethylmethyleneiminium iodide 98% | 33797-51-2 | 50g | $373 | 2026-03-19 | Buy |
| TCI Chemical | D1646 | N,N-Dimethylmethyleneammonium Iodide >97.0%(T) | 33797-51-2 | 5g | $60 | 2026-03-19 | Buy |
| TCI Chemical | D1646 | N,N-Dimethylmethyleneammonium Iodide >97.0%(T) | 33797-51-2 | 25g | $177 | 2026-03-19 | Buy |
| TRC | D496025 | N,N-Dimethylmethyleneiminium iodide | 33797-51-2 | 500mg | $60 | 2021-12-16 | Buy |
N,N-DiMethylMethyleneaMMoniuM Iodide Chemical Properties,Uses,Production
Description
N, N-Dimethylmethyleneammonium iodide (DMMIA) is a versatile quaternary ammonium compound characterized by its unique chemical structure and widely utilized in scientific research. This colorless salt readily dissolves in water and has a melting point of 197°C. DMMIA is a crucial reagent in various laboratory experiments, contributing significantly to synthesis processes. Moreover, it finds application in biochemical studies, showcasing diverse biochemical and physiological effects. Its importance in scientific research is evident, as it serves as a reagent for organic synthesis, a catalyst for alcohol oxidation, and a key component in producing heterocyclic compounds. Additionally, it is utilized in synthesizing surfactants and other amphiphilic molecules. Furthermore, DMMIA aids in studying enzyme kinetics by effectively inhibiting certain enzyme activities.
Chemical Properties
CREAM TO YELLOW CRYSTALLINE POWDER
Uses
In organic synthesis.
Uses
(N,N-Dimethyl)methyleneammonium iodide is a useful reagent for many synthetic applications like aminomethylation. It is also essential for the conversion of ketones to α, β-unsaturated enones. It is utilized to prepare derivatives of the type RCH2N(CH3)2. It is extensively used in medicines like painkillers and sedatives- Tramadol hydrochloride intermediate viz. 2-dimethylamine methylcyclohexanone. It is also employed in reactive dyes, synthesized spices. It plays an essential role in Mannich reactions.
General Description
N,N-Dimethylmethyleneiminium iodide is useful reagent for many synthetic applications, especially aminomethylation and conversion of ketones to α,βunsaturated enones.
Synthesis
The mixture of trimethylamine, diiodomethane, dioxane and absolute ethanol was placed in the dark to react at room temperature for 100 h, the resulting crystals were collected by filtration, washed with ethanol and ether in turn, and dried under vacuum at 70 °C to obtain iodomethyl trimethylMethylammonium iodide. It was heated with sulfolane and kept at 160 °C for 12 min. The precipitated crystals were collected by filtration, washed with carbon tetrachloride, and vacuum dried at 50 °C to obtain N,N-DiMethylMethyleneaMMoniuM Iodide.
N,N-DiMethylMethyleneaMMoniuM Iodide Preparation Products And Raw materials
Raw materials
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Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanxi Tihondan Pharmaceutical Technology Co., Ltd | +8618235132063 | sales@tihondan.com | China | 3767 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-029-81138252 +86-173 9270 1263 | 1057@dideu.com | China | 4000 | 58 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| Jinan Carbotang Biotech Co.,Ltd. | +8615866703830 | figo.gao@foxmail.com | China | 8497 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49977 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29795 | 58 |
| Zhengzhou Alfa Chemical Co.,Ltd | +8618530059196 | sale04@alfachem.cn | China | 9546 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52705 | 58 |
| PT CHEM GROUP LIMITED | +86-85511178; | peter68@ptchemgroup.com | China | 35425 | 58 |
View Lastest Price from N,N-DiMethylMethyleneaMMoniuM Iodide manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-08-15 | N,N-DiMethylMethyleneaMMoniuM Iodide
33797-51-2
|
US $1.00 / KG | 1KG | 99% | 20T | Shaanxi Dideu Medichem Co. Ltd | |
 |
2020-01-09 | ESCHENMOSER'S SALT
33797-51-2
|
US $1.00 / KG | 1KG | 99% | 200kg | Career Henan Chemical Co |
-
- N,N-DiMethylMethyleneaMMoniuM Iodide
33797-51-2
- US $1.00 / KG
- 99%
- Shaanxi Dideu Medichem Co. Ltd
-
- ESCHENMOSER'S SALT
33797-51-2
- US $1.00 / KG
- 99%
- Career Henan Chemical Co
N,N-DiMethylMethyleneaMMoniuM Iodide Spectrum
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