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ISOPROPENYLMAGNESIUM BROMIDE

ISOPROPENYLMAGNESIUM BROMIDE structure

CAS No.: 13291-18-4

Chemical Name:: ISOPROPENYLMAGNESIUM BROMIDE

Synonyms: IsopropenyL;1-Methylvinylmagnesium bromide;Bromoisopropenylmagnesium;ISOPROPENYLMAGNESIUM BROMIDE;bromo(prop-1-en-2-yl)magnesium;Magnesium isopropenyl Bromoide;1-Methylethenylmagnesium bromide;bromo(1-methylethenyl)-Magnesium;(1-Methylethenyl)magnesium bromide;IsopropenylMagnesiuM broMide soluti

CBNumber:: CB4783309

Molecular Formula:: C3H5BrMg

Molecular Weight:: 145.28

MDL Number:: MFCD00192240

MOL File:: 13291-18-4.mol

MSDS File:: SDS

Last updated:2026-05-28 02:32:27

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ISOPROPENYLMAGNESIUM BROMIDE Properties

Melting point	102-104 °C
Boiling point	67 °C
Density	0.94 g/mL at 20 °C
Flash point	−36 °F
storage temp.	2-8°C
form	Crystalline Powder
color	White to yellow to orange
BRN	3587297
InChI	InChI=1S/C3H5.BrH.Mg/c1-3-2;;/h1H2,2H3;1H;/q;;+1/p-1
InChIKey	LFTYALBVGVNGLI-UHFFFAOYSA-M
SMILES	C(=C)(C)[Mg]Br
UNSPSC Code	12352103
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS02,GHS05,GHS07,GHS08
Signal word	Danger
Hazard statements	H225-H260-H302-H314-H335-H351
Precautionary statements	P210-P231+P232-P280-P370+P378-P402+P404-P403+P235
Hazard Codes	F,C
Risk Statements	11-14/15-34-40-37-19-14
Safety Statements	26-30-36/37/39-43-45-7/8-16
RIDADR	UN 3399 4.3/PG 1
WGK Germany	1
F	1-3-10-34
HS Code	29319090
Storage Class	4.3 - Hazardous materials which set free flammable gases upon contact with water
Hazard Classifications	Acute Tox. 4 Oral Eye Dam. 1 Flam. Liq. 2 Skin Corr. 1B Water-react 1
REACH Registrations	Active

ISOPROPENYLMAGNESIUM BROMIDE price More Price(15)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	419567	Isopropenylmagnesium bromide solution 0.5 M in THF	13291-18-4	100ml	$209	2026-04-30	Buy
Sigma-Aldrich	419567	Isopropenylmagnesium bromide solution 0.5 M in THF	13291-18-4	800ml	$386	2026-04-30	Buy
GFS CHEMICALS	25872	Isopropenylmagnesium Bromide, 1.5 M, In Methyl Tetrahydrofuran	13291-18-4	4L	$1237	2026-06-03	Buy
GFS CHEMICALS	17523	Isopropenylmagnesium Bromide, 0.5 M In Tetrahydrofuran	13291-18-4	1L	$180.6	2026-06-03	Buy
Synthonix	K73514	Isopropenylmagnesium bromide, 0.50 M in THF 0.50M	13291-18-4	50ml	$105	2026-05-06	Buy

Product number	Packaging	Price	Buy
419567	100ml	$209	Buy
419567	800ml	$386	Buy
25872	4L	$1237	Buy
17523	1L	$180.6	Buy
K73514	50ml	$105	Buy

ISOPROPENYLMAGNESIUM BROMIDE Chemical Properties,Uses,Production

Uses

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Uses

Isopropenylmagnesium bromide (iPrMgBr) solution (0.5 M in THF) has been used in the Grignard reaction, a key step the in preparation of zofenoprilat and (S)-()-phosphonotrixin. It can also be used for the regioselective ring opening of an optically active epoxy alcohol in the total synthesis of (+)-desepoxyasperdiol.

General Description

This product, 1.0 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention.

reaction suitability

reaction type: Grignard Reaction

Synthesis

The Preparative Method of 2-Propenylmagnesium Bromide-Copper(I) Iodide: prepared in situ under anhydrous conditions by reacting 2-propenylmagnesium bromide (1) with Copper(I) Iodide (2) in varying molar ratios.

ISOPROPENYLMAGNESIUM BROMIDE synthesis

Synthesis of ISOPROPENYLMAGNESIUM BROMIDE from 2-Bromopropene

ISOPROPENYLMAGNESIUM BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

Isopropenylboronic acid pinacol ester H-tBu-Gly-OtBu HCl prop-1-ene-2-sulfonyl chloride

ISOPROPENYLMAGNESIUM BROMIDE Suppliers

Global( 196)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shanghai Weiji Environmental Protection Technology Co., LTD	13817380975 13391095697	info@wjscientific.cn	China	18	58
Nanjing Freehoo Chemical Technology Co., Ltd.	025-57798086 13951998329	sjg9988@126.com	China	37	58
Meryer (Shanghai) Chemical Technology Co., Ltd.	4006356688 18621169109	market03@meryer.com	China	40202	62
Beijing HwrkChemical Technology Co., Ltd	89508211 18501085097	sales.bj@hwrkchemical.com	China	9407	55
Energy Chemical	400-0056266	sales8178@energy-chemical.com	China	44850	61
Beijing Ouhe Technology Co., Ltd	13552068683 13522913783	2355560935@qq.com	China	11777	60
JinYan Chemicals(ShangHai) Co.,Ltd.	13817811078	sales@jingyan-chemical.com	China	9963	60
Nanjing Chemlin Chemical Co., Ltd	025-83697070 13770331960	info@chemlin.com.cn	China	16305	64
Shanghai Hanhong Scientific Co.,Ltd.	021-54306202 13764082696	info@hanhongsci.com	China	42917	64
Shandong Xiya Chemical Co., Ltd	13355009207 13355009207	3007715519@qq.com	China	18722	57

Supplier	Advantage
Shanghai Weiji Environmental Protection Technology Co., LTD	58
Nanjing Freehoo Chemical Technology Co., Ltd.	58
Meryer (Shanghai) Chemical Technology Co., Ltd.	62
Beijing HwrkChemical Technology Co., Ltd	55
Energy Chemical	61
Beijing Ouhe Technology Co., Ltd	60
JinYan Chemicals(ShangHai) Co.,Ltd.	60
Nanjing Chemlin Chemical Co., Ltd	64
Shanghai Hanhong Scientific Co.,Ltd.	64
Shandong Xiya Chemical Co., Ltd	57

View Lastest Price from ISOPROPENYLMAGNESIUM BROMIDE manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2023-07-19	Bromo(isopropenyl)magnesium 13291-18-4	$30.00	1KG	99%	20 Tons	Wuhan wingroup Pharmaceutical Co., Ltd
	2019-07-06	isopropenylmagnesium bromide 13291-18-4	$1.00	1kg	99%		Career Henan Chemical Co

Bromo(isopropenyl)magnesium
13291-18-4
$30.00
99%
Wuhan wingroup Pharmaceutical Co., Ltd

isopropenylmagnesium bromide
13291-18-4
$1.00
99%
Career Henan Chemical Co

13291-18-4(ISOPROPENYLMAGNESIUM BROMIDE)Related Search:

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METHYLZINC CHLORIDE Benzylmagnesium chloride 3-FLUOROPHENYLMAGNESIUM BROMIDE Cyclopropylmagnesium bromide SEC-BUTYLMAGNESIUM BROMIDE

Di-n-butylmagnesium Cyclopentylmagnesium bromide 4-Fluorophenylmagnesium bromide

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Isopropenylmagnesium bromide, 0.5 M solution in THF, HySeal ISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURAN ISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURAN ISOPROPENYLMAGNESIUM BROMIDE 0.5 M THF Isopropenylmagnesium bromide( 1.0 M solution in THF) Isopropenylmagnesium bromide 1M solution in tetrahydrofuran ISOPROPENYLMAGNESIUM BROMIDE isopropenylmagnesium bromide solution ISOPROPENYLMAGNESIUM BROMIDE SOLUTION, ~ 0.5 M IN THF ISOPROPENYLMAGNESIUM BROMIDE, 0.5M SOLUT ION IN TETRAHYDROFURAN ISOPROPENYLMAGNESIUM BROMIDE in ETHYL ETHER ISOPROPENYLMAGNESIUM BROMIDE in TETRAHYDROFURAN (1-Methylethenyl)magnesium bromide 1-Methylethenylmagnesium bromide Bromoisopropenylmagnesium Isopropenylmagnesium bromide,0.5M solution inTHF Isopropenylmagnesium bromide, 0.5M solution in THF, AcroSeal§3 Isopropenylmagnesium bromide solution 0.5 in THF Isopropenylmagnesium bromide, 0.5M solution in THF, AcroSeal Iso Propenyl MagnesiuM BroMide0.5M In Thf IsopropenylMagnesiuM broMide soluti IsopropenylMagnesiuM broMide, 0.5 M solution in THF, SpcSeal Isopropenylmagnesium bromide, 0.5 M solution in THF, J&KSeal IsopropenylMagnesiuM broMide, 1.0 M solution in THF, SpcSeal Isopropenylmagnesium bromide(1M THF) Bromo(isopropenyl)magnesium Solution (0.5M in THF) Isopropenylmagnesium bromide (0.5M in THF) FandaSeal Magnesium, bromo(1-methylethenyl)- (9CI) bromo(1-methylethenyl)-Magnesium ISOPROPENYLMAGNESIUM BROMIDE 0.5M IN THF/1.0M IN 2Me THF Iso Propenyl Magnesium Bromide .5M in THF Iso Propenyl Magnesium Bromide 1.M in 2-Methyl THF ISOPROPENYL MAGNESIUM BROMIDE 0.5M THF/1.0M &2M THF Iso Propenyl Magnesium Bromide 1.5M in 2-Methyl THF bromo(prop-1-en-2-yl)magnesium Isopropenylmagnesium bromide, 1.5M in 2-MeTHF - [K5651] Isopropenylmagnesium bromide, 0.50 M in THF - [K73514] Isopropenylmagnesium bromide 1.0M in 2-methyl THF / 0.5M inTHF Isopropenylmagnesium bromide solution in 2-Methyltetrahydrofuran 1-Methylvinylmagnesium bromide IsopropenyL Magnesium isopropenyl Bromoide 13291-18-4 13219-18-4 CH2CCH3MgBr H2CCCH3MgCl Alkenyl Grignard Reagents Organometallic Reagents Grignard Reagent Alkenyl Grignard Reagents Organometallic Reagents