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(2-FLUORO-BENZYL)-HYDRAZINE

CAS No.
51859-98-4
Chemical Name:
(2-FLUORO-BENZYL)-HYDRAZINE
Synonyms
(2-FLUORO-BENZYL)-HYDRAZINE;[(2-fluorophenyl)methyl]hydrazine;1-fluoro-1-(phenylmethyl)hydrazine;1-Fluoro-2-(hydrazinomethyl)benzene;Hydrazine, [(2-fluorophenyl)methyl]-;(2-Fluorobenzyl)hydrazine (HCl forM)
CBNumber:
CB5133923
Molecular Formula:
C7H9FN2
Molecular Weight:
140.16
MDL Number:
MFCD07785903
MOL File:
51859-98-4.mol
MSDS File:
SDS
Last updated:2025-07-24 18:13:46
Product description Number Pack Size Price
2-Fluorobenzylhydrazine F588635 1g $195
(2-Fluorobenzyl)hydrazine 95% PC49334 25g $275
(2-Fluorobenzyl)hydrazine W6669 1g $380
(2-Fluorobenzyl)hydrazine 90% AK-35444 1g $29
(2-Fluorobenzyl)hydrazine 3739-3-01 1g $48
More product size

(2-FLUORO-BENZYL)-HYDRAZINE Properties

Boiling point 265.8±23.0 °C(Predicted)
Density 1.144±0.06 g/cm3(Predicted)
storage temp. Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
pka 6.74±0.10(Predicted)
form liquid
color Clear, colourless
InChI InChI=1S/C7H9FN2/c8-7-4-2-1-3-6(7)5-10-9/h1-4,10H,5,9H2
InChIKey OOMBRKGIWITBLL-UHFFFAOYSA-N
SMILES N(CC1=CC=CC=C1F)N

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS06
Signal word  Danger
Hazard statements  H301+H311+H331
Precautionary statements  P280
HS Code  2928009090

(2-FLUORO-BENZYL)-HYDRAZINE price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC F588635 2-Fluorobenzylhydrazine 51859-98-4 1g $195 2021-12-16 Buy
Apolloscientific PC49334 (2-Fluorobenzyl)hydrazine 95% 51859-98-4 25g $275 2021-12-16 Buy
AK Scientific W6669 (2-Fluorobenzyl)hydrazine 51859-98-4 1g $380 2021-12-16 Buy
Ark Pharm AK-35444 (2-Fluorobenzyl)hydrazine 90% 51859-98-4 1g $29 2021-12-16 Buy
SynQuest Laboratories 3739-3-01 (2-Fluorobenzyl)hydrazine 51859-98-4 1g $48 2021-12-16 Buy
Product number Packaging Price Buy
F588635 1g $195 Buy
PC49334 25g $275 Buy
W6669 1g $380 Buy
AK-35444 1g $29 Buy
3739-3-01 1g $48 Buy

(2-FLUORO-BENZYL)-HYDRAZINE Chemical Properties,Uses,Production

Uses

2-Fluorobenzylhydrazine has been used as a reactant for the synthesis of acylamino substituted benzylbenzohydrazide derivatives.

Synthesis

2-Fluorobenzyl bromide

446-48-0

(2-FLUORO-BENZYL)-HYDRAZINE

51859-98-4

The general procedure for the synthesis of 2-fluorobenzyl hydrazine from 2-fluorobenzyl bromide was as follows: 190 g (1.0 mol) of 2-fluorobenzyl bromide was slowly added to a 2 L ethanol solution containing 250 g (5.0 mol) of hydrazine hydrate and 137 g (1.0 mol) of potassium carbonate under stirring conditions. The reaction mixture was stirred continuously at room temperature for 48 hours. After completion of the reaction, the reaction mixture was concentrated by distillation under reduced pressure. The residue was extracted with ether to separate the organic phase. The organic phase was dried over anhydrous sodium sulfate and concentrated again under reduced pressure to remove the solvent. The crude product was purified by silica gel column chromatography to give 109 g (76% yield) of 2-fluorobenzylhydrazine.

References

[1] Journal of Medicinal Chemistry, 1995, vol. 38, # 19, p. 3884 - 3888
[2] Patent: WO2005/97784, 2005, A1. Location in patent: Page/Page column 70-71
[3] Patent: US2012/196861, 2012, A1
[4] Patent: US2012/196862, 2012, A1
[5] Patent: US2014/357637, 2014, A1. Location in patent: Paragraph 1226

446-48-0
51859-98-4
Synthesis of (2-FLUORO-BENZYL)-HYDRAZINE from 2-Fluorobenzyl bromide
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View Lastest Price from (2-FLUORO-BENZYL)-HYDRAZINE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(2-FLUORO-BENZYL)-HYDRAZINE pictures 2025-03-20 (2-FLUORO-BENZYL)-HYDRAZINE
51859-98-4
US $0.00 / kg 1kg 93% As your request Changzhou waston chemical technology Co.,Ltd
(2-fluorobenzyl)hydrazine pictures 2022-01-15 (2-fluorobenzyl)hydrazine
51859-98-4
US $0.00 / KG 1KG 98.5% 100 tons Honest Joy Holdings Limited
(2-FLUORO-BENZYL)-HYDRAZINE pictures 2019-07-06 (2-FLUORO-BENZYL)-HYDRAZINE
51859-98-4
US $1.00 / kg 1kg 99% Customized Career Henan Chemical Co
(2-FLUORO-BENZYL)-HYDRAZINE 1-Fluoro-2-(hydrazinomethyl)benzene [(2-fluorophenyl)methyl]hydrazine (2-Fluorobenzyl)hydrazine (HCl forM) 1-fluoro-1-(phenylmethyl)hydrazine Hydrazine, [(2-fluorophenyl)methyl]- 51859-98-4 Riociguat