Dihydridotetrakis(triphenylphosphine)ruthenium(II)
- CAS No.
- 19529-00-1
- Chemical Name:
- Dihydridotetrakis(triphenylphosphine)ruthenium(II)
- Synonyms
- Dihydrotetrakis(triphenylphosphine)ruthenium;Dihydridotetrakis(triphenyL;ruthenium,triphenylphosphane;Tetrakis(triphenylphosphine)ruthenium dihydride;Dihydridotetrakis(triphenylphosphine)ruthenium(Ⅱ);TETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) HYDRIDE;dihydridotetrakis(triphenylphosphine)-ruthenium(I;Dihydridotetrakis(triphenylphosphine)ruthenium(Il);Dihydridotetrakis(triphenylphosphine)ruthenium(II);DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENATE (II)
- CBNumber:
- CB5288861
- Molecular Formula:
- C72H62P4Ru
- Molecular Weight:
- 1152.23
- MDL Number:
- MFCD04126429
- MOL File:
- 19529-00-1.mol
- MSDS File:
- SDS
| Melting point | 181-183 °C(lit.) |
|---|---|
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| solubility | Slightly soluble in benzene, toluene, and THF. |
| form | Lustrous Powder |
| color | Ochre |
| Sensitive | air sensitive |
| InChI | 1S/4C18H15P.Ru.2H/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h4*1-15H;;; |
| InChIKey | RXFATFKBDIQXLS-UHFFFAOYSA-N |
| SMILES | [RuH2].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9.c%10ccc(cc%10)P(c%11ccccc%11)c%12ccccc%12 |
| UNSPSC Code | 12161600 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 |
| target organs | Respiratory system |
| PPE | dust mask type N95 (US), Eyeshields, Gloves |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-37/39 |
| WGK Germany | 3 |
| TSCA | No |
| HS Code | 28439000 |
| Storage Class | 11 - Combustible Solids |
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
Dihydridotetrakis(triphenylphosphine)ruthenium(II) price More Price(28)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 335037 | Dihydridotetrakis(triphenylphosphine)ruthenium(II) | 19529-00-1 | 500mg | $157 | 2026-04-30 | Buy |
| Strem Chemicals | 44-0460 | Dihydrotetrakis(triphenylphosphine)ruthenium(II), 95% | 19529-00-1 | 250mg | $77 | 2026-04-30 | Buy |
| Strem Chemicals | 44-0460 | Dihydrotetrakis(triphenylphosphine)ruthenium(II), 95% | 19529-00-1 | 1g | $228 | 2026-04-30 | Buy |
| TRC | TRC-D195290-500MG | Dihydrotetrakis(triphenylphosphine)ruthenium | 19529-00-1 | 500mg | $567 | 2026-06-03 | Buy |
| TRC | TRC-D195290-250MG | Dihydrotetrakis(triphenylphosphine)ruthenium | 19529-00-1 | 250mg | $314 | 2026-06-03 | Buy |
Dihydridotetrakis(triphenylphosphine)ruthenium(II) Chemical Properties, Uses, Production
Chemical Properties
ochre lustrous powder
Uses
Catalyst for hydration of nitriles, isomerization of alkynes,Knoevenagel reactions and conjugate additions, and transferhydrogenation
reaction suitability
core: ruthenium
reagent type: catalyst
Synthesis
The Preparative Method of Dihydridotetrakis(triphenylphosphine)ruthenium(II): prepared from Ruthenium(III) Chloride or ruthenium(III) acetylacetonate by reduction with Triethylaluminum in the presence of Triphenylphosphine in THF or benzene under nitrogen at room temperature. The complex can also be prepared by reacting Dichlorotris(triphenylphosphine)ruthenium(II) with Sodium Borohydride and triphenylphosphine.
Purification Methods
Dihydridotetrakis(triphenylphosphine)ruthenium(II) could be recrystallized from benzene, toluene, or THF.
Precautions
Dihydridotetrakis(triphenylphosphine)ruthenium(II) is air and light-sensitive and should be stored under argon in the dark.
Dihydridotetrakis(triphenylphosphine)ruthenium(II) Preparation Products And Raw materials
Raw materials
Preparation Products
Dihydridotetrakis(triphenylphosphine)ruthenium(II) Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Beijing HwrkChemical Technology Co., Ltd | 89508211 18501085097 | sales.bj@hwrkchemical.com | China | 9407 | 55 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Shandong Xiya Chemical Co., Ltd | 13355009207 13355009207 | 3007715519@qq.com | China | 18722 | 57 |
| Thermo Fisher Scientific | 800-810-5118 | cnchemical@thermofisher.com | China | 17752 | 75 |
| Shanghai Macklin Biochemical Co.,Ltd. | 15221275939 15221275939 | shenlinxing@macklin.cn | China | 15775 | 55 |
| Sigma-Aldrich | 021-61415566 800-8193336 | orderCN@merckgroup.com | China | 51389 | 80 |
| Shanghai YuanYe Biotechnology Co., Ltd. | 15026964105 | 2881489226@qq.com | China | 89667 | 60 |
| Tianjin Kailiqi Biotechnology Co., Ltd. | 15076683720 | klq@cw-bio.com | China | 9780 | 55 |
View Latest Price from Dihydridotetrakis(triphenylphosphine)ruthenium(II) manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2020-01-15 | DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
19529-00-1
|
$1.00 | 1KG | 98% | 1KG, 5KG, 50KG | Career Henan Chemical Co |
-
- DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
19529-00-1
- $1.00
- 98%
- Career Henan Chemical Co
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