NICKEL(II) CHLORIDE
- CAS No.
- 69098-15-3
- Chemical Name:
- NICKEL(II) CHLORIDE
- Synonyms
- NICKEL(II) CHLORIDE HYDRATE;Puratronic99.995%(metalsbasis);NICKEL(II) CHLORIDE HYDRATE, 99.95%;nickel(ii) chloride hydrate, puratronic;Nickel(II) chloride hydrate 99.95% trace metals basis;Nickel(II) chloride hydrate, Puratronic, 99.995% (metals basis);Nickel(II) chloride hydrate, Puratronic(R), 99.995% (metals basis)
- CBNumber:
- CB5370083
- Molecular Formula:
- Cl2H2NiO
- Molecular Weight:
- 147.61
- MDL Number:
- MFCD00149808
- MOL File:
- 69098-15-3.mol
- TDS File:
- TDS
| Melting point | 1001 °C |
|---|---|
| vapor pressure | 1 mm Hg ( 671 °C) |
| form | Crystalline Aggregates |
| color | Green |
| Water Solubility | Freely soluble in water. Soluble in ethylene glycol, ethanol, and ammonium hydroxide. |
| Sensitive | Hygroscopic |
| Merck | 14,6505 |
| Exposure limits | NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3 |
| Major Application |
battery precursors catalysts material synthesis precursor |
| InChI | 1S/2ClH.Ni.H2O/h2*1H;;1H2/q;;+2;/p-2 |
| InChIKey | HGGYAQHDNDUIIQ-UHFFFAOYSA-L |
| SMILES | O.Cl[Ni]Cl |
| UNSPSC Code | 12352302 |
| NACRES | NA.23 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS06,GHS08,GHS09 |
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|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H301+H331-H315-H317-H334-H350i-H360D-H372-H410 | |||||||||
| Precautionary statements | P202-P273-P280-P301+P310-P302+P352-P304+P340+P311 | |||||||||
| PPE | Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges | |||||||||
| Hazard Codes | T,N | |||||||||
| Risk Statements | 45-23/24/25-36/37/38-42/43-68-50/53-48/23-38-23/25-61-49 | |||||||||
| Safety Statements | 53-26-27-28-36/37/39-45-61-60 | |||||||||
| RIDADR | UN 3288 6.1/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | QR6480000 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | III | |||||||||
| Storage Class | 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects |
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| Hazard Classifications | Acute Tox. 3 Inhalation Acute Tox. 3 Oral Aquatic Acute 1 Aquatic Chronic 1 Carc. 1B Inhalation Repr. 1B Resp. Sens. 1 Skin Irrit. 2 Skin Sens. 1 STOT RE 1 |
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| NFPA 704 |
|
NICKEL(II) CHLORIDE price More Price(11)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 364304 | Nickel(II) chloride hydrate 99.95% trace metals basis | 69098-15-3 | 100g | $82.9 | 2026-04-30 | Buy |
| Sigma-Aldrich | 364304 | Nickel(II) chloride hydrate 99.95% trace metals basis | 69098-15-3 | 500g | $242 | 2026-04-30 | Buy |
| Chem-Impex | 35700 | Nickel(II) chloride hydrate ≥99.95%(Tracemetalsbasis) | 69098-15-3 | 25G | $36.65 | 2026-05-19 | Buy |
| Chem-Impex | 35700 | Nickel(II) chloride hydrate ≥99.95%(Tracemetalsbasis) | 69098-15-3 | 100G | $77.62 | 2026-05-19 | Buy |
| Chem-Impex | 35700 | Nickel(II) chloride hydrate ≥99.95%(Tracemetalsbasis) | 69098-15-3 | 250G | $144.12 | 2026-05-19 | Buy |
NICKEL(II) CHLORIDE Chemical Properties, Uses, Production
Uses
It is used in electroplating and as a catalyst for organic conversions, for example in chemo-selective thioacetalization of aldehydes. In combination with lithium aluminum hydride, it serves as a reducing agent for alkenes, alkynes, and organic halides; it can cleave N-O bond and open epoxides. It is a precursor to several nickel-phosphine complexes, such as bis(triphenylphosphine)nickel(II) chloride, which are used in alkyne trimerizations, carbonylations, and as catalysts in organic reactions such as Suzuki-Miyaura cross coupling reactions as an alternative to palladium(0) catalysts. It is the precursor to acetylacetonate complex of Ni, used for producing 1,5-cyclooctadiene complex, an important reagent in organonickel chemistry. It can be used to prepare the sandwich compound nickelocene through dimethoxyethane complex of nickel chloride.
reaction suitability
reagent type: catalyst
core: nickel
Purification Methods
It crystallises from dilute HCl to form the green hexahydrate. At 70o this dehydrates to the tetrahydrate, and at higher temperatures it forms the anhydrous salt. It sublimes in yellow hexagonal scales in a stream of HCl. Store it in a desiccator as it is deliquescent. [Hart & Partington J Chem Soc 104 1943.]
NICKEL(II) CHLORIDE Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Adamas Reagent, Ltd. | 400-6009262 15618770481 | yhx@titansci.com | China | 14098 | 59 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| Shanghai Macklin Biochemical Co.,Ltd. | 15221275939 15221275939 | shenlinxing@macklin.cn | China | 15775 | 55 |
| Sigma-Aldrich | 021-61415566 800-8193336 | orderCN@merckgroup.com | China | 51389 | 80 |
| Shanghai YuanYe Biotechnology Co., Ltd. | 15026964105 | 2881489226@qq.com | China | 89667 | 60 |
| Guangzhou Jhd Chemical Reagent Co., Ltd. | 020-84383047 | sales@jhd.com.cn | China | 9177 | 65 |
| Shanghai Shuai Sun Industrial Co., Ltd. | 021-37590756 57450129 | China | 4282 | 58 | |
| Shanghai Jizhi Biochemical Technology Co. Ltd. | 021-4009004166/18616739031 18616739031 | 3007523370@qq.com | China | 40000 | 58 |
