2,4,6-Trimethylpyrylium tetrafluoroborate
- CAS No.
- 773-01-3
- Chemical Name:
- 2,4,6-Trimethylpyrylium tetrafluoroborate
- Synonyms
- AKOS 90396;TRIMETHYLPYRYLIUM TETRAFLUOROBORATE;2,4,6-TRIMETHYLPYRILIUMTETRAFLUOROBORATE;2,4,6-Trimethylpyrylium tetrafluoroborate;2,4,6-Trimethylpyrylium tetrafluoroborate, 98+%
- CBNumber:
- CB5402005
- Molecular Formula:
- C8H11BF4O
- Molecular Weight:
- 209.98
- MDL Number:
- MFCD00032098
- MOL File:
- 773-01-3.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 224-226°C |
|---|---|
| solubility | Acetonitrile (Slightly), Methanol (Slightly, Heated) |
| form | powder to crystaline |
| color | White to Orange to Green |
| Water Solubility | Soluble in water and methanol. |
| BRN | 3639361 |
| InChI | InChI=1S/C8H11O.BF4/c1-6-4-7(2)9-8(3)5-6;2-1(3,4)5/h4-5H,1-3H3;/q+1;-1 |
| InChIKey | PYOPRIFMELCENN-UHFFFAOYSA-N |
| SMILES | [B-](F)(F)(F)F.C1(C)C=C([O+]=C(C)C=1)C |
| CAS DataBase Reference | 773-01-3(CAS DataBase Reference) |
| EPA Substance Registry System | Pyrylium, 2,4,6-trimethyl-, tetrafluoroborate(1-) (773-01-3) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36/37/39 | |||||||||
| RIDADR | UN 1759 8/PG III | |||||||||
| TSCA | TSCA listed | |||||||||
| HS Code | 2932.99.9090 | |||||||||
| HazardClass | IRRITANT | |||||||||
| PackingGroup | III | |||||||||
| NFPA 704 |
|
2,4,6-Trimethylpyrylium tetrafluoroborate price More Price(24)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | S920134 | 2,4,6-TRIMETHYLPYRYLIUM TETRAFLUOROBORATE AldrichCPR | 773-01-3 | 1 unit | $197 | 2026-04-30 | Buy |
| Sigma-Aldrich | S626848 | TRIMETHYLPYRYLIUM TETRAFLUOROBORATE AldrichCPR | 773-01-3 | 1 unit | $197 | 2026-04-30 | Buy |
| Sigma-Aldrich | S920134 | 2,4,6-TRIMETHYLPYRYLIUM TETRAFLUOROBORATE AldrichCPR | 773-01-3 | 50mg | $179 | 2024-03-01 | Buy |
| Sigma-Aldrich | S626848 | TRIMETHYLPYRYLIUM TETRAFLUOROBORATE AldrichCPR | 773-01-3 | 1g | $179 | 2024-03-01 | Buy |
| TCI Chemical | T2375 | 2,4,6-Trimethylpyrylium Tetrafluoroborate >98.0%(HPLC)(T) | 773-01-3 | 5g | $66 | 2026-04-30 | Buy |
2,4,6-Trimethylpyrylium tetrafluoroborate Chemical Properties, Uses, Production
Uses
It is used in the radical Arylation Reactions of 4, 6, 8-Trimethylazulene.
Synthesis
Method 1: Acetic anhydride (100 mL, 1.06 mol, 13.0 eq.) and tert-butanol (8.00 mL, 84.2 mmol, 1.00 eq.) were added to a round-bottom flask equipped with a condenser and a dropping funnel. Fluoroboric acid (14 mL, 78 mmol, 0.95 eq.) was added dropwise. During its addition, the temperature was raised to 80°C. After completion of the exothermic reaction, the mixture was cooled to 5C and cold Et 2 O was added, the precipitate was collected, washed with cold Et 2 O and dried. 2,4,6-Trimethylpyranium tetrafluoroborate was obtained as a colorless solid (11.6 g, 55.4 mmol, 71%). 1H NMR (300 MHz, CD3OD, 300 K) δ= 7.87 (s, 2H, CHarom), 2.88 (s, 6H, 2× CH3), 2.72 (s, 3H, CH3). 13 C NMR (75MHz, CDCl 3, 300K) δ= 179.5 (Cq), 134.1 (Cq), 124.3 (CH), 21.1 (CH 3), 20.7 (CH 3). 19F NMR (282MHz, CD3OD, 300K) δ= -154.7. HRMS (ESI) m/z = 123.0804 Calculated values. MS (ESI): C8H11O [M] +, measured value: 123.0762. Spectral data is consistent with previously reported data.
2,4,6-Trimethylpyrylium tetrafluoroborate Preparation Products And Raw materials
2,4,6-Trimethylpyrylium tetrafluoroborate Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Xingui Biotechnology Co., Ltd. | 15121041756 | xingui2022@126.com | China | 10000 | 58 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44566 | 61 |
| Adamas Reagent, Ltd. | 4006009262 13023226327 | hmj@titansci.com | China | 14098 | 59 |
| Sichuan Kulinan Technology Co., Ltd | 400-1166-196 18981987031 | cdhxsj@163.com | China | 11674 | 57 |
| Hunan Hui Bai Shi Biotechnology Co., Ltd. | 0731-85526065 13308475853 | ivy@hnhbsj.com | China | 5000 | 62 |
| Jiangsu Aikon Biopharmaceutical R&D co.,Ltd. | 025-66113011 13913916777 | cfzhang@aikonchem.com | China | 19902 | 55 |
View Latest Price from 2,4,6-Trimethylpyrylium tetrafluoroborate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2026-08-07 | 2,4,6-TRIMETHYLPYRYLIUM TETRAFLUOROBORATE
773-01-3
|
$1.00 | 1KG | 99% | 10000KG | Shaanxi Dideu Medichem Co. Ltd | |
![]() |
2020-02-26 | 2,4,6-Trimethylpyrylium Tetrafluoroborate
773-01-3
|
$1.00 | 1KG | 99%+ | 100 tons | Shaanxi Dideu Medichem Co. Ltd | |
![]() |
2020-02-26 | 2,4,6-Trimethylpyrylium Tetrafluoroborate
773-01-3
|
1KG | 99.0%+ | 100 tons | Shaanxi Dideu Medichem Co. Ltd |
-

- 2,4,6-TRIMETHYLPYRYLIUM TETRAFLUOROBORATE
773-01-3
- $1.00
- 99%
- Shaanxi Dideu Medichem Co. Ltd
-

- 2,4,6-Trimethylpyrylium Tetrafluoroborate
773-01-3
- $1.00
- 99%+
- Shaanxi Dideu Medichem Co. Ltd
-

- 2,4,6-Trimethylpyrylium Tetrafluoroborate
773-01-3
- 99.0%+
- Shaanxi Dideu Medichem Co. Ltd
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