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Rhodium(III) chloride hydrate

CAS No.
20765-98-4
Chemical Name:
Rhodium(III) chloride hydrate
Synonyms
RHODIUM(III) CHLORIDE HYDRATE;Rhod;Rhodium Chloride Hydrate;RHODIUM TRICHLORIDE HYDRATE;oride trihydrate;Rhodium (III) chL;RhodiumchloridehydrateRh;trichlororhodium hydrate;hodium(III) chloride hydrate;Rhodium(III) chloride, puriss
CBNumber:
CB5473720
Molecular Formula:
Cl3H2ORh
Molecular Weight:
227.27
MDL Number:
MFCD01941625
MOL File:
20765-98-4.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 02:03:21

Rhodium(III) chloride hydrate Properties

Melting point 100 °C (dec.)(lit.)
Density 2.76
storage temp. Store below +30°C.
solubility Methanol (Slightly), Water (Slightly)
form crystalline
color White to off-white
Water Solubility soluble
Sensitive Hygroscopic
Merck 14,8188
Exposure limits ACGIH: TWA 0.01 mg/m3
NIOSH: IDLH 2 mg/m3; TWA 0.001 mg/m3
Stability hygroscopic
Major Application PEM fuel cells
homogeneous catalyst
material synthesis precursor
InChI InChI=1S/3ClH.H2O.Rh/h3*1H;1H2;/q;;;;+3/p-3
InChIKey HSSMNYDDDSNUKH-UHFFFAOYSA-K
SMILES [Rh](Cl)(Cl)Cl.O
CAS DataBase Reference 20765-98-4(CAS DataBase Reference)
UNSPSC Code 12352302
NACRES NA.23

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)Exclamation Mark (GHS07)Health Hazard (GHS08)Environment (GHS09)
GHS05,GHS07,GHS08,GHS09
Signal word  Danger
Hazard statements  H290-H302-H318-H341-H410
Precautionary statements  P202-P273-P280-P301+P312-P305+P351+P338-P308+P313
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xn,Xi
Risk Statements  22-41
Safety Statements  26-36/39
RIDADR  1759
WGK Germany  3
TSCA  Yes
HazardClass  8
HS Code  28439000
Storage Class 8A - Combustible corrosive hazardous materials
Hazard Classifications Acute Tox. 4 Oral
Aquatic Acute 1
Aquatic Chronic 1
Eye Dam. 1
Met. Corr. 1
Muta. 2
REACH Registrations Active
Limited Quantities 5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
NFPA 704
1
3 0

Rhodium(III) chloride hydrate price More Price(94)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 206261 Rhodium(III) chloride hydrate Rh 38-40 % 20765-98-4 1g $616 2026-04-30 Buy
Sigma-Aldrich 206261 Rhodium(III) chloride hydrate Rh 38-40 % 20765-98-4 5g $2450 2026-04-30 Buy
TCI Chemical R0244 Rhodium(III) Chloride Hydrate 20765-98-4 250MG $62 2023-01-07 Buy
TCI Chemical R0244 Rhodium(III) Chloride Hydrate 20765-98-4 1G $170 2021-12-16 Buy
Strem Chemicals 45-1880 Rhodium(III) chloride hydrate (38-41% Rh) 20765-98-4 250mg $157 2026-04-30 Buy
Product number Packaging Price Buy
206261 1g $616 Buy
206261 5g $2450 Buy
R0244 250MG $62 Buy
R0244 1G $170 Buy
45-1880 250mg $157 Buy

Rhodium(III) chloride hydrate Chemical Properties, Uses, Production

Chemical Properties

red-brown to dark brown crystalline powder, easily soluble in water, hydrochloric acid, alcohol and alkali solution, insoluble in ether and aqua regia, lose crystal water by strong heat and become insoluble, and then decompose into rhodium and chlorine.

Uses

Rhodium(III) chloride hydrate is used as a catalyst to prepare acetic acid. It is also used as a catalyst for the isomerization of alkenes, the reduction of aromatic rings, the oxidation ofalkenes, the hydration of acetylene. It is involved in the hydrosilylation of α,β-unsaturated esters to form dimethylketene trimethylsilyl acetals.

Application

Rhodium(III) chloride is often used in synthetic chemistry as a hydrogenation catalyst. Rhodium(III) chloride is also used to make transition metal complexes, some of which are used as reagents in the decarbonylation dehydration reactions of fatty acids to alkenes.

Reactions

Catalyst in conjunction with "pybox" for the asymmetric hydrosilylation of ketones.
C-C bond forming reactions.
Rhodium (III) chloride trihydrate Reaction

reaction suitability

core: rhodium
reagent type: catalyst

Rhodium(III) chloride hydrate Preparation Products And Raw materials

Global Suppliers ( 362)
Supplier Tel Email Country ProdList Advantage
Hangzhou Raisaijin Environmental Protection Technology Co., Ltd. 18458449126 2862984566@qq.com China 36 58
Chenzhou Gaoxin Platinum Industry Co., Ltd. 0735-2390599 13574551630;15073547586 1156989506@qq.com China 78 58
Baoji Funuokang Industrial Co., Ltd 0917-3236817 13220096790 1754423088@qq.com China 3000 58
Beijing HwrkChemical Technology Co., Ltd 89508211 18501085097 sales.bj@hwrkchemical.com China 9407 55
Guangzhou Ilike Technology Co., LTD 15800028809 18258355559 ws@gzfcs.cn China 157 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
INTATRADE GmbH +49 3493/605464 sales@intatrade.de Germany 3563 66
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
ShangHai DEMO Chemical Co.,Ltd 400-021-7337 2355568890 sales@demochem.com China 2569 57

View Latest Price from Rhodium(III) chloride hydrate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
RHODIUM TRICHLORIDE HYDRATE pictures 2026-08-25 RHODIUM TRICHLORIDE HYDRATE
20765-98-4
$2.00-5.00 1kg 99% 100kg ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
 rhodium (III) chloride trihydrate  pictures 2026-03-20 rhodium (III) chloride trihydrate
20765-98-4
$1.00 1PCS 99% 10mt Hebei Chuanghai Biotechnology Co., Ltd
Rhodium (III) chloride trihydrate pictures 2022-09-21 Rhodium (III) chloride trihydrate
20765-98-4
1kg 99% 1000kg henan kanbei chemical co.,ltd
RHODIUM(III) CHLORIDE HYDRATE RhodiumchloridehydrateRh RHODIUM(III) CHLORIDE HYDRATE: 99.9% (38% RH) Rhodium(III) Chloride n-Hydrate Rhodium(III) chloride hydrate ,99.9% RhodiuM(III) chloride hydrate, (trace Metal basis) RhodiuM(III) chloride hydrate, 38% Rh 1GR RHODIUM(III) CHLORIDE HYDRATE, 99.98% Rhodium(III) chloride hydrate, 38-40% Rh Rhodium(III) chloride hydrate, crystals, 99.9+% Rhodium Chloride Hydrate Rhodium(III) chloride hydrate, 38% Rh Rhodium(III)chloridehydrate(38-41%Rh) Rhodium chloride (RhCl3), hydrate rhodium(iii) chloride hydrate, premion Rhodium(III) chloride hydrate, Rh 38.5-45.5% Rhodium(III) chloride hydrate, Premion(R), 99.99% (metals basis) Rhodium(III) chloride hydrate, Premion, 99.99% (metals basis) RhodiuM(III) chloride hydrate, 99.95%, (trace Metal basis) oride trihydrate Rhodium (III) chL RhodiuM chloride(RhCl3), hydrate (9CI) RhodiuM(III) chloride hydrate Rh 38-40 % Rhodium(III) chloride hydrate 99.98% trace metals basis Rhodium(III) chloride hydrate crystalline, >=99.9% trace metals basis Rhodium(III) chloride hydrate, crystals Rhodium(III) chloride hydrate, 99.99% trace metals basis III) -Rh39.5%Rhodium trichloride hydrate trichlororhodium hydrate High-content rhodium (III) chloride trihydrate from Chin Rhodium(III) chloride xhydrate Rhodium(III) chloride, puriss, app. 40% Rh Rhodium(III) chloride, hydrate, crystalline, 99.9% Rhodium(III) chloride, hydrate, crystalline Rhodium(III) chloride, puriss Rhodium(III) chloride hydrate, Premion&trade Rhodium (III) Chloride Trihydrate pure, 98% Rhodium(IlI) chloride hydrate hodium(III) chloride hydrate Rhodium (II) chloride hydrate Rhodium(III) chloride hydrate [soluble butyl)phenyl-palladium(II)chloride dimer RHODIUM TRICHLORIDE HYDRATE Rhod 20765-98-4 Cl3ORh H6Cl3O3Rh RhCl33H2O Cl3H2ORh RhCl3稾H2O Cl3RhxH2O Catalysis and Inorganic Chemistry Metal and Ceramic Science Rhodium Salts Salts Catalysis and Inorganic Chemistry Chemical Synthesis RhodiumMetal and Ceramic Science