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ChemicalBook >> CAS DataBase List >>1,4,7-Trimethyl-1,4,7-triazacyclononane

1,4,7-Trimethyl-1,4,7-triazacyclononane

1,4,7-Trimethyl-1,4,7-triazacyclononane Structure
1,4,7-Trimethyl-1,4,7-triazacyclononane structure
CAS No.
96556-05-7
Chemical Name:
1,4,7-Trimethyl-1,4,7-triazacyclononane
Synonyms
1,4,7-triMethyl-1,4,7-triazonane;CL232;TMTACN;ononane;147TM147TZ;1,4,7-TrimethyL;TRIMETHYL TRICLEN;-1,4,7-triazacycL;1,4,7-Trimethyl-1,4,7-triazacycl;1,4,7-Trimethyl-1,4,7-Triazacylononane
CBNumber:
CB5741845
Molecular Formula:
C9H21N3
Molecular Weight:
171.28
MDL Number:
MFCD00012359
MOL File:
96556-05-7.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-09-12 18:53:40
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1,4,7-Trimethyl-1,4,7-triazacyclononane Properties

Boiling point 208℃
Density 0.884 g/mL at 25 °C(lit.)
vapor pressure 1.23hPa at 25℃
refractive index n20/D 1.473(lit.)
Flash point 155 °F
storage temp. 2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
pka 8.69±0.20(Predicted)
form liquid
Specific Gravity 0.884
color pale yellow
Sensitive moisture sensitive
BRN 4174812
InChI 1S/C9H21N3/c1-10-4-6-11(2)8-9-12(3)7-5-10/h4-9H2,1-3H3
InChIKey WLDGDTPNAKWAIR-UHFFFAOYSA-N
SMILES CN1CCN(C)CCN(C)CC1
LogP 0.446-1.67 at 40℃ and pH7-10.5
Surface tension 59.8-67.5mN/m at 1g/L and 20℃
Dissociation constant 2.86-8.63 at 20℃
FDA UNII R7BZK76RTP
UNSPSC Code 12352005
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363-P405
PPE Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Codes  C,Xi
Risk Statements  34
Safety Statements  26-36/37/39-45
RIDADR  UN 3267 8/PG 2
WGK Germany  3
F  10-34
HazardClass  8
PackingGroup  III
HS Code  2933998090
Storage Class 8A - Combustible corrosive hazardous materials
Hazard Classifications Skin Corr. 1B
REACH Registrations Active
NFPA 704
2
3 0

1,4,7-Trimethyl-1,4,7-triazacyclononane price More Price(52)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 311294 1,4,7-Trimethyl-1,4,7-triazacyclononane 97% 96556-05-7 100mg $64.2 2026-04-30 Buy
Sigma-Aldrich 311294 1,4,7-Trimethyl-1,4,7-triazacyclononane 97% 96556-05-7 500mg $241 2026-04-30 Buy
TCI Chemical T1879 1,4,7-Trimethyl-1,4,7-triazacyclononane (stabilized with NaHCO3) >98.0%(GC)(T) 96556-05-7 1g $202 2026-04-30 Buy
TCI Chemical T1879 1,4,7-Trimethyl-1,4,7-triazacyclononane (stabilized with NaHCO3) >98.0%(GC)(T) 96556-05-7 5g $646 2026-04-30 Buy
Strem Chemicals 07-2750 1,4,7-Trimethyl-1,4,7-triazacyclononane, min. 97% min.97% 96556-05-7 250mg $135 2026-04-30 Buy
Product number Packaging Price Buy
311294 100mg $64.2 Buy
311294 500mg $241 Buy
T1879 1g $202 Buy
T1879 5g $646 Buy
07-2750 250mg $135 Buy

1,4,7-Trimethyl-1,4,7-triazacyclononane Chemical Properties, Uses, Production

Uses

Useful ligand for preparing transition metal complexes.

Synthesis

Formaldehyde

50-00-0

1,4,7-tris[(4-Methylphenyl)sulfonyl]-1,4,7-triazonane

52667-89-7

1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE

96556-05-7

The general procedure for the synthesis of 1,4,7-trimethyl-1,4,7-triazacyclononane from formaldehyde and 1,4,7-tri-tosyl-1,4,7-triazacyclononane is as follows: 10.37 g of 1,4,7-tri-toluenesulfonyl-1,4,7-triazacyclononane (Ts3TACN) was added to a 30 mL round-bottomed flask, followed by the addition of 10 mL of of concentrated sulfuric acid mixed with 2 mL of distilled water. The reaction vessel was placed in an oil bath, heated to 140 °C, and the solid was completely dissolved by stirring to form a black solution. The reaction was kept at 140°C with continued stirring for 6 hours. Upon completion of the reaction, the resulting solution was slowly poured into a 500 mL two-necked flask which was pre-filled with 32 g of 50% (w/w) aqueous sodium hydroxide solution and 13 g of distilled water while being cooled in an ice bath. Subsequently, 23 mL of 37% formaldehyde aqueous solution and 23 mL of 88% formic acid were added to the reaction system and the mixture was heated to 90 °C, at which time carbon dioxide gas was observed to be generated. After the release of gas ceased, the reaction mixture was cooled to 0 °C and 50 g of 50% (w/w) aqueous sodium hydroxide solution was added. Next, 200 mL of hexane was added and after stirring for 2 min, the organic phase was separated using a separatory funnel. The aqueous phase was further extracted with hexane and all hexane phases were combined and dried with anhydrous sodium sulfate. Finally, the organic phase was concentrated under reduced pressure to afford the target product 1,4,7-trimethyl-1,4,7-triazacyclononane (Me3TACN) in 25% yield.

References

[1] Patent: US7674866, 2010, B2. Location in patent: Page/Page column 17

1,4,7-Trimethyl-1,4,7-triazacyclononane Preparation Products And Raw materials

Raw materials

Formaldehyde 1,4,7-tris[(4-Methylphenyl)sulfonyl]-1,4,7-triazonane Sulfuric acid Formic acid Sodium hydroxide

Preparation Products

1,4,7-Trimethyl-1,4,7-triazacyclononane Suppliers

Global Suppliers ( 209)
Supplier Tel Email Country ProdList Advantage
YiZheng HaiFan Chemical CO., LTD. 0514-83468749 13852506708 zcw@yzhaifan.com China 49 58
Shanghai Qiao Chemical Science Co., Ltd 021-58892003 info@qiaochem.com China 6065 65
shanghaikeyiyuan Technology Co., Ltd 15316056835 545311776@qq.com China 76 58
Shanghai Taijilin Industrial Co., Ltd. 02150630626 17717886015 kate@tajilin.com China 1340 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Ark Pharm, Inc. 847-367-3680 sales@arkpharminc.com United States 1669 56
Beijing HwrkChemical Technology Co., Ltd 89508211 18501085097 sales.bj@hwrkchemical.com China 9407 55
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Supplier Advantage
YiZheng HaiFan Chemical CO., LTD. 58
Shanghai Qiao Chemical Science Co., Ltd 65
shanghaikeyiyuan Technology Co., Ltd 58
Shanghai Taijilin Industrial Co., Ltd. 58
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
TCI (Shanghai) Development Co., Ltd. 81
Ark Pharm, Inc. 56
Beijing HwrkChemical Technology Co., Ltd 55
Energy Chemical 61

View Latest Price from 1,4,7-Trimethyl-1,4,7-triazacyclononane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1,4,7-trimethyl-1,4,7-triazacyclononane pictures 2026-09-15 1,4,7-trimethyl-1,4,7-triazacyclononane
96556-05-7
 25kg/pp drum 98% 20 tons YiZheng HaiFan Chemical CO., LTD.
1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE pictures 2026-06-30 1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE
96556-05-7
 1KG 98 10000KGS Shaanxi Dideu New Materials Co. Ltd
1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE pictures 2025-04-04 1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE
96556-05-7
 1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.

1,4,7-Trimethyl-1,4,7-triazacyclononane Spectrum

1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE(96556-05-7)1HNMR1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE(96556-05-7)Raman1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE(96556-05-7)FT-IR

96556-05-7 (1,4,7-Trimethyl-1,4,7-triazacyclononane) Related Search:

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1,4,7-triMethyl-1,4,7-triazonane 1,4,7-Trimethyl-1,4,7-triazacyclononane 97% 1,4,7-Trimethyl-1,4,7-triazacyclononane, min. 97% 1,4,7-Trimethyl-1,4,7-triazacyclononane (stabilized with NaHCO3) 1,4,7-Trimethyloctahydro-1H-1,4,7-triazonine 1,4,7-Trimethyl-1,4,7-triazacyclononane purum 1,4,7-Trimethyl-1,4,7-triazacyclononane(stabilizedwithNaHCO3),98% 1,4,7-Trimethyl-1,4,7-triazacyclononane (stabilized with NaHCO3) TRIMETHYL TRICLEN CL232 Octahydro-1,4,7-trimethyl-1H-1,4,7-triazonine (stabilized with NaHCO3) -1,4,7-triazacycL 1,4,7-TrimethyL ononane OCTAHYDRO-1,4,7-TRIMETHYL-1H-1,4,7-TRIAZONINE 1,4,7-Trimethyl-1,4,7-triazacycl 1,4,7-trimethyl-1,4,7-triaazacyclononane 1,4,7-Trimethyl-1,4,7-triazacyclononane,min.97% 1H-1,4,7-Triazonine, octahydro-1,4,7-trimethyl- 1,4,7-Trimethyl-1,4,7-triazacyclononane (stabilized with NaHCO?) 1,4,7-Trimethyl-1,4,7-Triazacylononane 147TM147TZ N,N',N''-trimethyl-1,4,7-triazacyclononane TMTACN 1,4,7-Trimethyl-1,4,7-triazacyclononane 96556-05-7 6556-05-7 Macrocycles for Host-Guest Chemistry Crown Ethers Synthetic Reagents Chelation/Complexation Compounds Crown Ethers Functional Materials Macrocycles for Host-Guest Chemistry Achiral Nitrogen Cy-N organic amine Macrocyclics/Ligand Chelation/Complexation Compounds Crown Ethers Synthetic Reagents