1-(3-BROMO-4-METHOXYPHENYL)ETHANONE
- CAS No.
- 35310-75-9
- Chemical Name:
- 1-(3-BROMO-4-METHOXYPHENYL)ETHANONE
- Synonyms
- 4-Acetyl-2-bromoanisole;3'-BROMO-4'-METHOXYACETOPHENONE;1-(3-BROMO-4-METHOXYPHENYL)ETHANONE;Ethanone, 1-(3-bromo-4-methoxyphenyl)-
- CBNumber:
- CB6230281
- Molecular Formula:
- C9H9BrO2
- Molecular Weight:
- 229.07
- MDL Number:
- MFCD01812494
- MOL File:
- 35310-75-9.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 3'-Bromo-4'-methoxyacetophenone 98% | OR14758 | 5g | $21 |
| 3'-Bromo-4'-methoxyacetophenone 98% | OR14758 | 25g | $81 |
| 3'-Bromo-4'-methoxyacetophenone 97% | AS25924 | 5g | $32 |
| 3'-Bromo-4'-methoxyacetophenone 98% | OR14758 | 100g | $311 |
| 3'-Bromo-4'-methoxyacetophenone 97% | AS25924 | 25g | $106 |
| More product size | |||
| Melting point | 84-86°C |
|---|---|
| Density | 1.421 |
| storage temp. | Sealed in dry,Room Temperature |
| form | solid |
| color | Beige |
| CAS DataBase Reference | 35310-75-9(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302-H315-H319-H332-H335 |
| Precautionary statements | P261-P280-P305+P351+P338 |
| Hazard Codes | Xi,Xn |
| Risk Statements | 22 |
| HS Code | 2914790090 |
1-(3-BROMO-4-METHOXYPHENYL)ETHANONE price More Price(37)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Apolloscientific | OR14758 | 3'-Bromo-4'-methoxyacetophenone 98% | 35310-75-9 | 5g | $21 | 2026-06-04 | Buy |
| Apolloscientific | OR14758 | 3'-Bromo-4'-methoxyacetophenone 98% | 35310-75-9 | 25g | $81 | 2026-06-04 | Buy |
| Activate Scientific | AS25924 | 3'-Bromo-4'-methoxyacetophenone 97% | 35310-75-9 | 5g | $32 | 2026-06-04 | Buy |
| Apolloscientific | OR14758 | 3'-Bromo-4'-methoxyacetophenone 98% | 35310-75-9 | 100g | $311 | 2026-06-04 | Buy |
| Activate Scientific | AS25924 | 3'-Bromo-4'-methoxyacetophenone 97% | 35310-75-9 | 25g | $106 | 2026-06-04 | Buy |
1-(3-BROMO-4-METHOXYPHENYL)ETHANONE Chemical Properties,Uses,Production
Preparation
Obtained by reaction of acetic anhydride with o-bromoanisole in the presence of lithium perchlorate at 100° for 5 h (99%).
Synthesis
100-06-1
35310-75-9
General procedure for the synthesis of 1-(3-bromo-4-methoxyphenyl)ethanone from p-methoxyacetophenone: ketone 7a (5.0 g, 33.3 mmol) and N-bromosuccinimide (NBS, 5.9 g, 33.3 mmol) were dissolved in 100 mL of water and heated to 60 °C. Subsequently, 40% H2SO4 (66.7 mmol, 8.9 mL) was added slowly and dropwise. The reaction mixture was stirred continuously for 5 hours. After completion of the reaction, the mixture was cooled to room temperature and separated by extraction with ethyl acetate (60 mL x 3). The organic phases were combined, washed with saturated NaHCO3 solution, dried over anhydrous MgSO4 and concentrated under reduced pressure to give the crude product 7b (7.5 g, 98% yield) as a white solid. Thin layer chromatography (TLC) Rf value was 0.85 (petroleum ether/ethyl acetate, 3:1).1H NMR (400 MHz, DMSO-d6) δ: 3.09 (3H, s), 3.93 (3H, s), 3.95 (6H, s), 7.92 (1H, d, J = 8.9 Hz), 7.97 (1H, dd, J = 2.1 Hz, 8.9 Hz), 8.10 (2H, d, J = 2.1 Hz); LC-MS m/z: 230.9 [M + H]+.
References
[1] Bioorganic and Medicinal Chemistry Letters, 2016, vol. 26, # 17, p. 4372 - 4376
[2] Tetrahedron, 2017, vol. 73, # 50, p. 7105 - 7114
[3] Synthetic Communications, 2014, vol. 44, # 2, p. 181 - 187
[4] Bioorganic and Medicinal Chemistry, 2015, vol. 23, # 13, p. 3618 - 3628
[5] Organic Letters, 2013, vol. 15, # 9, p. 2108 - 2111
1-(3-BROMO-4-METHOXYPHENYL)ETHANONE Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shaanxi Dideu Medichem Co. Ltd | +86-029-81138252 +86-173 9270 1263 | 1057@dideu.com | China | 3958 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29640 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| Wuhan Chemwish Technology Co., Ltd | 027-67849912 | sales@chemwish.com | CHINA | 10821 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29792 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
| Win-Win chemical CO., Limited | +86-0086-577-64498589 +86-15355981851 | sales@win-winchemical.com | China | 14304 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52704 | 58 |
| Changzhou Anxuan Chemical Co., Ltd | +86-0519-89882563 +86-18961279162 | andy@anxuanchem.com | China | 4327 | 58 |
View Lastest Price from 1-(3-BROMO-4-METHOXYPHENYL)ETHANONE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-08-17 | 1-(3-BROMO-4-METHOXYPHENYL)ETHANONE
35310-75-9
|
$1.00 | 1KG | 99% | 20T | Shaanxi Dideu Medichem Co. Ltd | |
 |
2020-01-10 | 1-(3-BROMO-4-METHOXYPHENYL)ETHANONE
35310-75-9
|
$1.00 | 1g | 98% | 200kgs | Career Henan Chemical Co |
-
- 1-(3-BROMO-4-METHOXYPHENYL)ETHANONE
35310-75-9
- $1.00
- 99%
- Shaanxi Dideu Medichem Co. Ltd
-
- 1-(3-BROMO-4-METHOXYPHENYL)ETHANONE
35310-75-9
- $1.00
- 98%
- Career Henan Chemical Co
35310-75-9(1-(3-BROMO-4-METHOXYPHENYL)ETHANONE)Related Search:
1of4
