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8-Bromo-1-octanol

8-Bromo-1-octanol structure

CAS No.: 50816-19-8

Chemical Name:: 8-Bromo-1-octanol

Synonyms: 8-bromooctan-1-ol;S,1000;8-BROMOOCTANOL;8-bromo-1-octano;8-Bromo-1-actanol;8-BROMO-1-OCTANOL;8-BroMo-1-oCLanol;8-Bromooctane-1-ol;1-bromo-octan-8-ol;1-Octanol, 8-bromo-

CBNumber:: CB6271684

Molecular Formula:: C8H17BrO

Molecular Weight:: 209.12

MDL Number:: MFCD00010388

MOL File:: 50816-19-8.mol

MSDS File:: SDS

Last updated:2026-05-28 05:41:18

Product description	Number	Pack Size	Price
8-Bromo-1-octanol 95%	294144	1g	$60.6
8-Bromo-1-octanol 95%	294144	5g	$201
8-Bromo-1-octanol >90.0%(GC)	B1729	5g	$126
8-Bromo-1-octanol >90.0%(GC)	B1729	25g	$402
8-Bromooctan-1-ol	TRC-B997403-500MG	500mg	$78
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8-Bromo-1-octanol Properties

Boiling point	79-80 °C/0.07 mmHg (lit.)
Density	1.22 g/mL at 25 °C (lit.)
refractive index	n20/D 1.480(lit.)
Flash point	>230 °F
storage temp.	2-8°C
solubility	Chloroform (Sparingly), Ethyl Acetate (Slightly)
form	Oil
pka	15.19±0.10(Predicted)
color	Colourless
Specific Gravity	1.22
BRN	1900837
InChI	InChI=1S/C8H17BrO/c9-7-5-3-1-2-4-6-8-10/h10H,1-8H2
InChIKey	GMXIEASXPUEOTG-UHFFFAOYSA-N
SMILES	C(O)CCCCCCCBr
CAS DataBase Reference	50816-19-8(CAS DataBase Reference)
NIST Chemistry Reference	8-Bromo-1-octanol(50816-19-8)
EPA Substance Registry System	1-Octanol, 8-bromo- (50816-19-8)
UNSPSC Code	12352200
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319

Precautionary statements

P264-P280a-P305+P351+P338-P321-P332+P313-P337+P313

PPE

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

Risk Statements

36-38

Safety Statements

23-24/25-37-26

WGK Germany

TSCA

TSCA listed

HS Code

29055900

Storage Class

10 - Combustible liquids

NFPA 704

	1
2		0

8-Bromo-1-octanol price More Price(65)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	294144	8-Bromo-1-octanol 95%	50816-19-8	1g	$60.6	2026-04-30	Buy
Sigma-Aldrich	294144	8-Bromo-1-octanol 95%	50816-19-8	5g	$201	2026-04-30	Buy
TCI Chemical	B1729	8-Bromo-1-octanol >90.0%(GC)	50816-19-8	5g	$126	2026-04-30	Buy
TCI Chemical	B1729	8-Bromo-1-octanol >90.0%(GC)	50816-19-8	25g	$402	2026-04-30	Buy
TRC	TRC-B997403-500MG	8-Bromooctan-1-ol	50816-19-8	500mg	$78	2026-06-03	Buy

Product number	Packaging	Price	Buy
294144	1g	$60.6	Buy
294144	5g	$201	Buy
B1729	5g	$126	Buy
B1729	25g	$402	Buy
TRC-B997403-500MG	500mg	$78	Buy

8-Bromo-1-octanol Chemical Properties,Uses,Production

Chemical Properties

Clear colorless to yellow liquid

Uses

It is used to produce 8-phenylselanyl-octan-1-ol by reaction with diphenyl-diselane. The reaction occurs with reagent sodium borohydride and solvent ethanol at ambient temperature. The yield is about 96%. 8-Bromo-1-octanol was used in the synthesis of (E)-10-hydroxy-2-decenoic acid (royal jelly acid)1. It was also used in the synthesis of (Z)-14-methyl-9-pentadecenoic acid.

reaction suitability

reagent type: cross-linking reagent

Synthesis

629-41-4

50816-19-8

The general procedure for the synthesis of 8-bromo-1-octanol from 1,8-octanediol was as follows: 16 g (110 mmol) of 1,8-octanediol was dissolved in 250 ml of toluene. To the solution was added 15.5 ml of hydrobromic acid (137 mmol, 1.25 eq., 48% aqueous solution), after which the reaction mixture was connected to a Dean-Stark manifold and refluxed to remove the water produced by the reaction. After 8 hours of reaction, the mixture was cooled to room temperature and washed sequentially twice with distilled water and once with brine. After drying over anhydrous sodium sulfate, the mixture was filtered and the solvent evaporated to give 8-bromo-1-octanol in quantitative yield. Nuclear magnetic resonance hydrogen spectroscopy (NMR) showed trace residues of toluene which did not affect the subsequent reaction. Densitometry (D2O calibration): 1.23 g/ml (literature value: 1.22 g/ml).13C NMR (CDCl3, ppm) data were as follows: 62.95 (CH2OH), 34.04 (BrCH2CH2), 32.78/32.71 (BrCH2 and CH2CH2OH), 29.23/28.73/ 28.09/25.65 (CH2).

References

[1] Patent: WO2018/108948, 2018, A1. Location in patent: Page/Page column 55
[2] Tetrahedron, 2008, vol. 64, # 30-31, p. 7369 - 7377
[3] Journal of the American Chemical Society, 1992, vol. 114, # 13, p. 5281 - 5294
[4] Phytochemistry, 1996, vol. 42, # 6, p. 1617 - 1620
[5] Tetrahedron Letters, 2002, vol. 43, # 15, p. 2745 - 2747

8-Bromo-1-octanol synthesis

Synthesis of 8-Bromo-1-octanol from 1,8-Octanediol

8-Bromo-1-octanol Preparation Products And Raw materials

Raw materials

1,8-Octanediol Hydrogen bromide Toluene

Preparation Products

Z,E-9,11-TETRADECADIENYL ACETATE Stearolic acid [(Z)-7-Decenyl]acetic acid 4-(8-HYDROXYOCTYLOXY)BENZOIC ACID Anacardic acid C15:3

8-Azido-1-octanol

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8-Bromo-1-octanol Suppliers

Global( 250)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Unipharm pharmaceutical industry Co., Ltd	536-8266195 +8613953676784	lee@unipharm-sd.com	China	1200	58
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32998	60
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29766	58
Zhejiang ZETian Fine Chemicals Co. LTD	18957127338	stella@zetchem.com	China	2993	58
Accela ChemBio Inc.	+1-858-6993322 +86-18019713315	info@accelachem.com	United States	21189	58
CONIER CHEM AND PHARMA LIMITED		sales@conier.com	China	49906	58
Hubei Ipure Biology Co., Ltd	+8618062405514	ada@ipurechemical.com	China	10224	58
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418671 +86-189 4982 3763	sales@tnjchem.com	China	34526	58
Shaanxi Dideu Medichem Co. Ltd	+86-29-81139210 +86-17392587031	1059@dideu.com	China	9984	58
Dayang Chem (Hangzhou) Co.,Ltd.	+86-0571-88938639 17705817739	info@dycnchem.com	China	52693	58

Supplier	Advantage
Unipharm pharmaceutical industry Co., Ltd	58
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
Zhejiang ZETian Fine Chemicals Co. LTD	58
Accela ChemBio Inc.	58
CONIER CHEM AND PHARMA LIMITED	58
Hubei Ipure Biology Co., Ltd	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
Shaanxi Dideu Medichem Co. Ltd	58
Dayang Chem (Hangzhou) Co.,Ltd.	58

View Lastest Price from 8-Bromo-1-octanol manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2025-04-04	8-Bromo-1-octanol 50816-19-8		1KG	98%	1ton	Henan Aochuang Chemical Co.,Ltd.
	2019-07-06	8-Bromo-1-octanol 50816-19-8	$1.00	1kg	96%+		Career Henan Chemical Co

8-Bromo-1-octanol
50816-19-8
98%
Henan Aochuang Chemical Co.,Ltd.

8-Bromo-1-octanol
50816-19-8
$1.00
96%+
Career Henan Chemical Co

8-Bromo-1-octanol Spectrum

8-Bromo-1-octanol(50816-19-8)MS 8-Bromo-1-octanol(50816-19-8)¹HNMR 8-Bromo-1-octanol(50816-19-8)IR

50816-19-8(8-Bromo-1-octanol)Related Search:

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1-Octanol, 8-bromo- 8-bromo-1-octano 1-bromo-octan-8-ol 8-BROMOOCTANOL 8-BROMO-1-OCTANOL 8-Bromo-1-actanol S,1000 OCTAMETHYLENE BROMOHYDRIN 8-Bromooctane-1-ol 8-Hydroxyoctyl bromide 8-BROMO-1-OCTANOL 90+% 8-BroMo-1-oCLanol 8-Bromo-1-octanol > Fulvestrant Impurity 71 8-bromooctan-1-ol 50816-19-8 BrCH28OH C8H17BrO Oxygen Compounds Organic Building Blocks C7 to C8 Alcohols Building Blocks 蠅-Functional Alkanols, Carboxylic Acids, Amines & Halides 蠅-Bromoalkanols Alcohols Bifunctional Crosslinkers Building Blocks C7 to C8 Chemical Biology Chemical Synthesis Linkers Organic Building Blocks Oxygen Compounds Peptide Chemistry OLED materials,pharm chemical,electronic omega-Bromoalkanols omega-Functional Alkanols, Carboxylic Acids, Amines & Halides Linear hydrocarbon series