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Tris(2,2'-bipyridyl)ruthenium(II) chloride hexahydrate

Tris(2,2'-bipyridyl)ruthenium(II) chloride hexahydrate Structure
Tris(2,2'-bipyridyl)ruthenium(II) chloride hexahydrate structure
CAS No.
50525-27-4
Chemical Name:
Tris(2,2'-bipyridyl)ruthenium(II) chloride hexahydrate
Synonyms
Ru(bpy)3Cl2;Ru(BPY)3;Ru(bpy)3(Cl)2·6H2O;Tris(2,2;Tris(2,2'-bipyridyL;Ru(bpy)3Cl2 Hexahydrate;ororuthenium(II) hexahydrate;tris(2,2’-bipyridyl)ruthenium;Dichlorotris(2,2'-bipyridyl)ruthenium(II);Ruthenium-tris(2,2′-bipyridyl) dichloride
CBNumber:
CB7101742
Molecular Formula:
C30H26ClN6ORu+
Molecular Weight:
623.1
MDL Number:
MFCD00149670
MOL File:
50525-27-4.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-09-12 18:54:26
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Tris(2,2'-bipyridyl)ruthenium(II) chloride hexahydrate Properties

Melting point >300 °C(lit.)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility DMSO (Slightly), Methanol (Slightly)
form powder
color Red-orange to red
Water Solubility Soluble in water.
Stability Stable, but may discolour upon exposure to light. Incompatible with strong oxidizing agents.
InChI InChI=1S/3C10H8N2.ClH.H2O.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;;;/h3*1-8H;1H;1H2;/q;;;;;+2/p-1
InChIKey VCIOOYXESNFDKX-UHFFFAOYSA-M
SMILES [Ru+2]123(N4=CC=CC=C4C4=CC=CC=N14)(N1=CC=CC=C1C1=CC=CC=N21)N1=CC=CC=C1C1=CC=CC=N31.[Cl-].O
CAS DataBase Reference 50525-27-4(CAS DataBase Reference)
UNSPSC Code 12352103
NACRES NA.23

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280a-P305+P351+P338-P321-P332+P313-P337+P313
PPE Eyeshields, Gloves, type N95 (US)
Risk Statements  36/38
Safety Statements  22-24/25
WGK Germany  3
RTECS  VM2730000
F  8-10
TSCA  Yes
HS Code  28439000
Storage Class 11 - Combustible Solids
NFPA 704
0
1 0

Tris(2,2'-bipyridyl)ruthenium(II) chloride hexahydrate price More Price(61)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 224758 Tris(2,2′-bipyridyl)dichlororuthenium(II) hexahydrate powder 50525-27-4 1g $158 2026-04-30 Buy
Sigma-Aldrich 224758 Tris(2,2′-bipyridyl)dichlororuthenium(II) hexahydrate powder 50525-27-4 5g $493 2026-04-30 Buy
TCI Chemical T1655 Tris(2,2'-bipyridyl)ruthenium(II) Chloride Hexahydrate >98.0%(T) 50525-27-4 1g $91 2026-04-30 Buy
TCI Chemical T1655 Tris(2,2'-bipyridyl)ruthenium(II) Chloride Hexahydrate >98.0%(T) 50525-27-4 5g $302 2026-04-30 Buy
Strem Chemicals 44-7900 Tris(2,2'-bipyridyl)ruthenium(II) chloride hexahydrate, min. 98% min.98% 50525-27-4 250mg $66 2026-04-30 Buy
Product number Packaging Price Buy
224758 1g $158 Buy
224758 5g $493 Buy
T1655 1g $91 Buy
T1655 5g $302 Buy
44-7900 250mg $66 Buy

Tris(2,2'-bipyridyl)ruthenium(II) chloride hexahydrate Chemical Properties, Uses, Production

Uses

Tris (2,2’-bipyridyl) dichlororuthenium hexahydrate (RTDP, Ru (BPY) 3) is an oxygen-sensitive fluorescent stain. It can be used to measure the oxygen concentration of microfluidic chips. 
Tris(2,2'-bipyridine)dichlororuthenium(II) hexahydrate is a catalyst used in light-induced redox reactions, and is an important catalyst in studies towards photochemical water splitting. This product is widely applied in fields of photoelectrical chemical components, photovoltaic cells, smart biosensors.

Chemical Properties

red to orange powder or crystals

Uses

suzuki reaction

Uses

Tris(2,2'-bipyridine)dichlororuthenium(II) hexahydrate is a catalyst used in light-induced redox reactions. It is an important catalyst in studies towards photochemical water splitting. This product can be used as a catalyst in pharmaceutical research. It is widely applied in fields of photoelectrical chemical components, photovoltaic cells, smart biosensors.

General Description

Tris(2,2′-bipyridyl)dichlororuthenium(II) hexahydrate is a metal complex and is used as an luminescent dye. The metal complex in its ground state can be excited by visible light which leads to the formation of a spin-allowed excited state. This excited state undergoes radiationless deactivation very quickly to form spin-forbidden, long-lived luminescent excited state. It is used widely in electroluminescent devices.

reaction suitability

core: ruthenium
reaction type: Photocatalysis
reagent type: catalyst

Synthesis

Dried RuCl3 (200 mg, 0.964 mmol) and 2,2-bipyridine (452 mg, 2.89 mmol) were dissolved in H2O (20 mL). Saturated naapo2h2 (2 ml) was added to the mixture. The resulting mixture was heated to reflux for 30 min. The reaction mixture was filtered. Potassium chloride (6.3 g, 84.5 mmol) was added to the filtrate. The mixture was heated to boiling. The reaction mixture was allowed to cool to room temperature. The crystals obtained were collected by filtration. The mixture was washed with cold acetone and recrystallized from water to give tris(bipyridyl)ruthenium(II) chloride.

Purification Methods

Recrystallise it from water, then from MeOH [Ikezawa et al. J Am Chem Soc 108 1589 1986].

Tris(2,2'-bipyridyl)ruthenium(II) chloride hexahydrate Preparation Products And Raw materials

Raw materials

N,N-Dimethylformamide Tetrabutyl ammonium chloride 2,2'-Bipyridine Hypophosphorous acid Ruthenium(III) chloride hydrate

Preparation Products

Tris(2,2'-bipyridyl)ruthenium(II) chloride hexahydrate Suppliers

Global Suppliers ( 289)
Supplier Tel Email Country ProdList Advantage
Shaanxi Rock New Materials Co., Ltd. 0917-8888777 18691786767 liuwei@bjrock.com China 309 62
Beijing Beibaoled Technology Co., Ltd. 010-60271698; 18001249871 bjbdoyd@163.com China 180 58
Panjin Greenchem Technology Co., Ltd. 13121959385 chemrocking@bjgreenchem.com China 223 58
Yunnan Precious Metals Laboratory Co., Ltd 13529192135 changqiaowen@126.com China 225 58
Shaanxi Ruihe Ming Biotechnology Co., Ltd 029-62584593 15029880552 77980819@qq.com China 19 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
ShangHai DEMO Chemical Co.,Ltd 400-021-7337 2355568890 sales@demochem.com China 2569 57
Supplier Advantage
Shaanxi Rock New Materials Co., Ltd. 62
Beijing Beibaoled Technology Co., Ltd. 58
Panjin Greenchem Technology Co., Ltd. 58
Yunnan Precious Metals Laboratory Co., Ltd 58
Shaanxi Ruihe Ming Biotechnology Co., Ltd 58
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
Alfa Aesar 84
TCI (Shanghai) Development Co., Ltd. 81
ShangHai DEMO Chemical Co.,Ltd 57

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[Ru (bpy)3] Cl2·6H2O pictures 2026-05-19 [Ru (bpy)3] Cl2·6H2O
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Tris(2,2'-bipyridyl)ruthenium(II) chloride hexahydrate Spectrum

TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE(50525-27-4)1HNMRTRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE(50525-27-4)FT-IRTRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE(50525-27-4)IRTRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE(50525-27-4)Raman

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tris(2,2’-bipyridine-n,n’)-,dichloride,hexahydrate,(oc-6-11)-ruthenium(2+ tris(2,2’-bipyridyl)ruthenium Tris(2,2'-bipyridine)ruthenium(II) chloride hexahydrate Tris(2,2'-bipyridyl)ruthenium(II)chloridehexahydrate,min.98% TRIS(2,2'-BIPYRIDYL)DICHLORORUTHENIUM(II)HEXAHYDRATE, POWDER TRIS(2,2'-BIPYRIDYL)DICHLORORUTHENIUM(II) HEXAHYDRATE, 99.95% TRIS(2,2-BIPYRIDYL)RUTHENIUM (II) CHLORIDE HEXAHYDRATE 98+% TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE 6-HYDRATE ruthenium(II)-tris(2,2'-bipyridyl) chloride.6H2O Ruthenium-tris(2,2μ-bipyridyl) dichloride, Tris(2,2μ-bipyridyl)ruthenium(II) chloride hexahydrate Tris(2,2'-bipyridyl)ruthenium(II) chloride hexahydrate, min. 98% Dichlorotris(2,2'-bipyridyl)ruthenium(II) Tris(2,2'-bipyridyl)ruthenium(II) Chloride Tris(2,2′-bipyridyl)dichlororuthenium(II) hexahydrate,Ruthenium-tris(2,2′-bipyridyl) dichloride, Tris(2,2′-bipyridyl)ruthenium(II) chloride hexahydrate Tris(2,2'-bipyridyl)ruthenium(II) dichloride Dichlorotris(2,2'-bipyridyl)ruthenium(II) Tris(2,2'-bipyridyl)dichlororuthenium(II) Tris(2,2'-bipyridine)dichlororutheniuM(II) hexahydrate, 98+% tris(2,2’-bipyridyl)rutheniumchloridehexahydrate tris(bipyridine)ruthenium(ii)chloridehexahydrate 2,2'-BIPYRIDINE RUTHENOUS DICHLORIDE HEXAHYDRATE RUTHENIUM-TRIS(2,2'-BIPYRIDYL) DICHLORIDE HEXAHYDRATE TRIS(2,2'-BIPYRIDYL)DICHLORORUTHENIUM(II) DICHLORIDE HEXAHYDRATE TRIS(2,2'-BIPYRIDYL)RUTHENIUM(2) CHLORIDE HEXAHYDRATE TRIS(2,2'-BIPYRIDINE)RUTHENIUM(II) CHLORIDE DICHLOROTRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) HEXAHYDRATE Tris(2,2'-bipyridyl)ruthenium(Ⅱ) chloride hexahydrate Tris(2,2'-bipyridyl)dichlororutheniuM(II) hexahydrate 99.95% trace Metals basis Ruthenium-tris(2,2′-bipyridyl) dichloride Tris(2,2′-bipyridine)dichlororuthenium(II) hexahydrate Tris(2,2 Tris(2,2'-bipyridine)ruthenium(II) chloride hexahydrate,98+% Tris(2,2'-bipyridyl)ruthenium(II)dichloride hexahydrate tris(2,2'-bipyridine-n,n')-,dichloride,hexahydrate(II) CHLORIDE HEXAHYDRATE Tris(2,2'-bipyridyl)ruthenium(Ⅱ) chloride ororuthenium(II) hexahydrate Tris(2,2'-bipyridyL tris-(2,2'-BIPYRIDINE) RUTHENIUM (II) CHLORIDE, HYDRATEtris-(2,2'-BIPYRIDINE) RUTHENIUM (II) CHLORIDE, HYDRATEtris-(2,2'-BIPYRIDINE) RUTHENIUM (II) CHLORIDE, HYDRATEtris-(2,2'-BIPYRIDINE) RUTHENIUM (II) CHLORIDE, HYDRATE Tris(2,2’-bipyridyl)dichlororuthenium(II) Hexahydrate (Ru(BPY)3) Methanesulfonato[(di(1-adamantyl)-n-butylphos-phine)-2-(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II),cataCXium Pd G4 TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE ISO 9001：2015 REACH Tripyridine ruthenium chloride hexahydrate Tris(2,2'-bipyridyl)dichlororuthenium(II) hexahydrate Tris(2,2'-bipyridine)ruthenium(II)chloridehexahydrate Tris(2,2’-bipyridine)dichlororuthenium(II) hexahydrate Ruthenium(II)tris(2,2'-bipyridine)chloridehexahydrate Tris(2,2'-bipyridyl)dichlororuthenium(II) hexahydrate Ru(bpy)3Cl2 Hexahydrate Tris(2,2'-bipyridyl)ruthenium(Ⅱ) chloride Ru(BPY)3 Ru(bpy)3Cl2 Ru(bpy)3(Cl)2·6H2O Ruthenium(2+) chloride - 2,2''-bipyridine hydrate (1:2:3:6) Tris(2,2'-bipyridyl)ruthenium(II) chloride hexahydrate 50525-27-4 C30H36Cl2N6O6Ru RuC10H8N23Cl2H2O C30H24N6Ru2Cl6H2O C30H24Cl2N6Ru6H2O