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[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Structure
[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride structure
CAS No.
15629-92-2
Chemical Name:
[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
Synonyms
NiCl2(dppp);Ni(dppp)Cl2;(1,3-dppp)NiCl2;NiCl2(DPPP)NiCl2(DPPP);[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]DICHLORONICKEL(II);1.3-Bis(dipheny phosphine) propane nickel(II)chloride;Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II);1,3-BIS(DIPHENYLPHOSPHINO)PROPANE NICKEL (II) CHLORIDE;1,3-Bis(diphenyl phosphine)propane nickel(II)dichloride;1,3-B
CBNumber:
CB3416370
Molecular Formula:
C27H26Cl2NiP2
Molecular Weight:
542.04
MDL Number:
MFCD00015318
MOL File:
15629-92-2.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 06:29:46
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[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Properties

Melting point 213 °C (dec.)(lit.)
storage temp. Inert atmosphere,Room Temperature
form crystal
color red
Water Solubility insoluble
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
Exposure limits NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
InChI InChI=1S/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2
InChIKey ZBQUMMFUJLOTQC-UHFFFAOYSA-L
SMILES P(C1=CC=CC=C1)(CCCP(C1C=CC=CC=1)C1C=CC=CC=1)C1C=CC=CC=1.[Ni](Cl)Cl
CAS DataBase Reference 15629-92-2(CAS DataBase Reference)
REACH Annex XVII Substances List Nickel, dichloro[1,1'-(1,3-propanediyl)bis[1,1-diphenylphosphine-[?]P]]- (15629-92-2)
UNSPSC Code 12161600
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS07,GHS08
Signal word  Danger
Hazard statements  H315-H317-H319-H334-H335-H350
Precautionary statements  P201-P280-P302+P352-P305+P351+P338-P308+P313
target organs Respiratory system
PPE Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Codes  T,Xn
Risk Statements  49-36/37/38-42/43-40
Safety Statements  53-26-36/37/39-45-24-22
RIDADR  3282
WGK Germany  3
F  10-21
TSCA  No
HS Code  29319090
Storage Class 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications Carc. 1A
Eye Irrit. 2
Resp. Sens. 1
Skin Irrit. 2
Skin Sens. 1
STOT SE 3
NFPA 704
0
2 0

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride price More Price(93)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 335363 [1,3-Bis(diphenylphosphino)propane]dichloronickel(II) 15629-92-2 5g $90.1 2026-04-30 Buy
Sigma-Aldrich 335363 [1,3-Bis(diphenylphosphino)propane]dichloronickel(II) 15629-92-2 25g $167 2026-04-30 Buy
TCI Chemical B1313 [1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride >98.0%(T) 15629-92-2 5g $35 2026-04-30 Buy
TCI Chemical B1313 [1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride >98.0%(T) 15629-92-2 25g $118 2026-04-30 Buy
Strem Chemicals 28-0080 1,3-Bis(diphenylphosphino)propane nickel(II) chloride, 99% 99% 15629-92-2 5g $76 2026-04-30 Buy
Product number Packaging Price Buy
335363 5g $90.1 Buy
335363 25g $167 Buy
B1313 5g $35 Buy
B1313 25g $118 Buy
28-0080 5g $76 Buy

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Chemical Properties, Uses, Production

Reaction

  1. Nickel catalyst used in the N-heterocycle-directed cross-coupling of fluorinated arenes with organozinc reagents.
  2. Nickel catalyst used in the (E)-selective semihydrogenation of internal alkynes.
  3. Nickel catalyst used in the borylation of halides and pseudohalides.
Reactions of 15629-92-2

Chemical Properties

red to red-brown powder or crystals

Uses

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins. Further, it is used as a catalyst for preparation of block-copolythiophenes and solid state metathesis polycondensation.

Application

Catalyst for:
Synthesis of block-copolythiophenes
Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acids
Solid state metathesis polycondensation
Polymerization of poly(3-alkoxythiophene)s
Diastereoselective Nozaki-Hiyama-Kishi coupling reactions of C1-C19 fragment of macrolide antibiotic aplyronine A
Transfer condensation polymerization of conjugated polymers
[1,3-Bis(diphenylphosphino)propane]dichloronickel(II) can be used as a precursor to synthesize metal-fullerene coordination complexes by reduction method.

reaction suitability

core: nickel
reaction type: Cross Couplings
reagent type: catalyst

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Preparation Products And Raw materials

Raw materials

Nickel(II) chloride hexahydrate Diphenylphosphine Ethanol 1,3-Dichloropropane 1,3-Bis(diphenylphosphino)propane
1,3-Dibromopropane Tetrahydrofuran Ethyl acetate Hydrochloric acid Dichloromethane
Sodium hydroxide Triphenylphosphine Petroleum ether Lithium

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Preparation Products

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Suppliers

Global Suppliers ( 418)
Supplier Tel Email Country ProdList Advantage
Puyang Huicheng Electronic Material Co. Ltd. 0393-0393-8910800 15039333257 info@huichengchem.com China 588 64
Panjin Greenchem Technology Co., Ltd. 13121959385 chemrocking@bjgreenchem.com China 223 58
JIANGSU B-WIN CHEMICAL INDUSTRY CO.,LTD. 0510-85840252 400-005-1800 843925888@qq.com China 29 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Beijing Donghualituo Techonlogy Development Co.,Ltd. 010-88425576 sales@dhltchem.com China 793 59
INTATRADE GmbH +49 3493/605464 sales@intatrade.de Germany 3563 66
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TAIYUAN RHF CO.,LTD. +86 351 7031519 sales@RHFChem.com China 2334 56
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Supplier Advantage
Puyang Huicheng Electronic Material Co. Ltd. 64
Panjin Greenchem Technology Co., Ltd. 58
JIANGSU B-WIN CHEMICAL INDUSTRY CO.,LTD. 58
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
Beijing Donghualituo Techonlogy Development Co.,Ltd. 59
INTATRADE GmbH 66
Alfa Aesar 84
TAIYUAN RHF CO.,LTD. 56
TCI (Shanghai) Development Co., Ltd. 81

Related articles

Related Questions

Ask a question
Q:What is the use and synthesis of [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride?Zora - Oct 15,2025
A: [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride is a bright orange-red crystalline powder, it is used as a catalyst in organic synthesis. [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride is synthesized by combining equal molar portions of nickel(II) chloride hexahydrate with 1,3-bis(diphenylphosphino)propane in 2-propanol.

View Latest Price from [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride pictures 2022-11-11 [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
15629-92-2
 $28.00-30.00 1Kg 99.0% up 50 tons per month Xinxiang Hongqi District Houyuan Trading Co.,Ltd
[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride pictures 2022-09-24 [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
15629-92-2
 1kg 99% 1000kg henan kanbei chemical co.,ltd
[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride pictures 2021-07-13 [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
15629-92-2
 $10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd

15629-92-2 ([1,3-Bis(diphenylphosphino)propane]nickel(II) chloride) Related Search:

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DICHLORO[1,3-BIS-(DIPHENYLPHOSPHINO)PROPANE] NICKE NICL2(DPPP)/ 1,3-BIS(DIPHENY PHOSPHINE) PROPANE NICKEL(II)CHLORIDE 1,3-Bis(diphenyl phosphine)propane nickel(II)dichloride 1,3-Bis-(diphenylphosphino)-propane nickel chloride Dichlorobis(1,3-diphenylphosphino)propaneünickel(II), C 59.9% (1,3-dppp)NiCl2, 1,3-Bis(diphenylphosphino)propane nickel(II) chloride Dichloro1,3-Bis-(diphenylphosphino ) propane nickel (II)（DPPE.Nicl2） 98% 1,3-Bis(diphenylphosphino)propane nickel(II) chlor 1,3-B 3-Bis(diphenylphosphino)propane]nickel(II) chloride phosphino)propane]dichL [1,3-Bis(diphenylphosphino)propane]dichloronicke(II) B**[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride, 99% 1GR [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride, 99% 5GR DICHLORO[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]NICKEL(II) [1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]DICHLORONICKEL(II) 1,3-BIS(DIPHENYLPHOSPHINO)PROPANE NICKEL (II) CHLORIDE [1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]NICKEL(II) DICHLORIDE 1,3-BIS(DIPHENYLPHOSPHINE)PROPANE NICKEL(II) CHLORIDE 1,3-Bis(diphenylphosphiNA)propane nickel(II) chloride 1,3-Bis(diphenylphosphino)propane nickel(II) chloride,98% (DPPP)NiCl2 [1,3-Bis(diphenylphosphino)propane]dichloronickel(II) Dichloro[1,3-bis(diphenylphosphino)propane]nickel(II) (1,3-Bis[Diphenylphosphino]Propane)Dichloronickel 1,3-BIS-(DIPHENYLPHOSPHINO)-PROPAN- 1,3-Bis(dipenylphosphino)propanenickel(II) chloride Dichloro[1,3-Bis-(Diphenylphos 1,3-Bis(diphenylphosphino)propanenickel(II)chloride,99% 1,3-Bis(diphenylphosphino)propane nickel(Ⅱ) chloride [1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride > 1,3-Bis(diphenylphosphino)propane nickel(II) chloride, 99%, reagent grade [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride ISO 9001：2015 REACH 1, 3-bis (diphenylphosphine propane) nickel dichloride Dichloro[1,1'-(1,3-propanediyl)bis[1,1-diphenylphosphine-κP]]nickel (1,3-Bis(diphenylphosphino) propane)dichloridenickel(II) 1,3-Bis(diphenylphosphino Nickel, dichloro[1,1′-(1,3-propanediyl)bis[1,1-diphenylphosphine-κP]]- Dichloro[1,1'-bis(diphenylphosphino)ferrocene]nickel(II) di-cyclohexylphosphino)ferrocene] 3-diphenylphosphanylpropyl(diphenyl)phosphane dichloronickel 1,3-Bis(diphenylphosphinopropane)nickel dichloride (1,3-dppp)NiCl2 1.3-Bis(dipheny phosphine) propane nickel(II)chloride Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II) NiCl2(DPPP)NiCl2(DPPP) Ni(dppp)Cl2 NiCl2(dppp) 15629-92-2 C27H26CI2NIP2 C27H26Cl2P2Ni C6H52PCH23PC6H52NiCl2 C27H26P2NiCl2 C6H52PCH2CH2CH2PC6H52NiCl2 C27H26Cl2NiP2 Catalysts for Organic Synthesis Classes of Metal Compounds Homogeneous Catalysts Metal Complexes