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Thiophosgene

CAS No.
463-71-8
Chemical Name:
Thiophosgene
Synonyms
CSCl2;Thiocarbonyl dichloride;THIOCARBONYL CHLORIDE;Carbon chlorosulfide;Carbonothioyl dichloride;Thiophosg;Thiofosgen;THIOPHOSGENE;thio-phosgen;Phosgene, thio-
CBNumber:
CB7117651
Molecular Formula:
CCl2S
Lewis structure
cscl2 lewis structure
Molecular Weight:
114.98
MDL Number:
MFCD00004918
MOL File:
463-71-8.mol
MSDS File:
SDS
Last updated:2026-07-14 15:19:21

Thiophosgene Properties

Melting point <25 °C
Boiling point 73 °C
Density 1.508
vapor density 4 (vs air)
refractive index n20/D 1.548(lit.)
Flash point 62 °C
storage temp. 2-8°C
solubility Chloroform
form Liquid
color A reddish liquid
Water Solubility slow decomposition in cold, fast in hot water
BRN 1633495
Stability Stable. but reacts violently with water to produce toxic fumes. Incompatible with water, alcohols. Refrigerate at 2-8 C.
CAS DataBase Reference 463-71-8(CAS DataBase Reference)
EWG's Food Scores 1-2
FDA UNII 067FQP576P
NIST Chemistry Reference Carbonothioic dichloride(463-71-8)
EPA Substance Registry System Thiophosgene (463-71-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)  Skull and Crossbones (GHS06)
GHS06
Signal word  Danger
Hazard statements  H331-H302-H315-H319-H335
Precautionary statements  P501-P261-P270-P271-P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313-P301+P312+P330-P304+P340+P311-P403+P233-P405
Hazard Codes  T
Risk Statements  22-23-36/37/38
Safety Statements  7-9-36/37-45-7/9
RIDADR  UN 2474
WGK Germany  1
RTECS  XN2450000
F  19-21
TSCA  TSCA listed
HazardClass  6.1
PackingGroup  I
HS Code  28530090
Hazardous Substances Data 463-71-8(Hazardous Substances Data)
REACH Registrations Inactive
Excepted Quantities Forbidden

Thiophosgene price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 115150 Thiophosgene 463-71-8 5g $40.5 2026-04-30 Buy
Sigma-Aldrich 115150 Thiophosgene 463-71-8 25g $113 2026-04-30 Buy
TRC TRC-T368200-5G Thiophosgene 463-71-8 5g $65 2026-06-03 Buy
TRC TRC-T368200-10G Thiophosgene 463-71-8 10g $109 2026-06-03 Buy
TRC TRC-T368200-100G Thiophosgene 463-71-8 100g $491 2026-06-03 Buy
Product number Packaging Price Buy
115150 5g $40.5 Buy
115150 25g $113 Buy
TRC-T368200-5G 5g $65 Buy
TRC-T368200-10G 10g $109 Buy
TRC-T368200-100G 100g $491 Buy

Thiophosgene Chemical Properties, Uses, Production

Chemical Properties

Reddish liquid. Decomposes in water and alcohol; soluble in ether.

Chemical Properties

A clear dark red to reddish-yellow liquid. Sharp, choking odor.

Uses

Thiophosgene is a photo degradation product of the agricultural fungicide Folpet (F402000).

Definition

ChEBI: Thiophosgene is a thiocarbonyl compound and a one-carbon compound.

General Description

A reddish liquid. Boiling point 73.5°C. A severe eye irritant. May severely burn skin on contact. Very toxic by inhalation and by skin absorption.

Air & Water Reactions

Reacts with water to evolve hydrogen chloride, carbon disulfide, and carbon dioxide. Reaction is slow unless the water is hot.

Reactivity Profile

Thiophosgene is incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Liberates hydrogen sulfide upon reaction with acids.

Hazard

Toxic by ingestion and inhalation.

Health Hazard

Inhalation causes irritation of respiratory system and delayed pulmonary edema. Vapor irritates eyes. Liquid burns skin and eyes. Ingestion causes irritation of mouth and stomach.

Safety Profile

Poison by intravenous route. Moderately toxic by ingestion. A skin, mucous membrane, and severe eye irritant. When heated to decomposition it emits very toxic fumes of Cland SOx. See also PHOSGENE.

Potential Exposure

Primary irritant (w/o allergic reaction). There is not large-scale production of the chemical in the United States It is used to make other chemicals and in laboratory synthesis.

Shipping

UN2474 Thiophosgene, Hazard class: 6.1; Labels: 6.1-Poison Inhalation Hazard; Inhalation Hazard Zone B. PG 2. STN: 49 232 98.

Incompatibilities

Vapors may form explosive mixture with air. Incompatible with water and alcohols. Reacts with water releasing toxic hydrogen chloride, carbon disulfide, and carbon dioxide. Reaction is slow unless the water is hot. Decomposes above 200℃ to highly flammable carbon bisulfide and carbon tetrachloride. Corrodes metals, rubber and some plastics in the presence of moisture. Thiophosgene is incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Liberates hydrogen sulfide upon reaction with acids

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

Global Suppliers ( 195)
Supplier Tel Email Country ProdList Advantage
Shanghai Yudiao Chemistry Technology Co.,Ltd 021-37285211 18964703211 info@yudiaochem.com China 120 58
Yangzhou juhechang Technology Co., Ltd 0514-0514-83662002 13073488988 13073488988@163.com China 40 58
Liaocheng Jinxinda New Materials Co., Ltd 18063557833 18006358937 2102868595@qq.com China 64 58
Hubei Paijian Biotechnology Co., Ltd 18164202469 18163347313 1205135340@qq.com China 116 58
Shandong Yuxuan Chemical Products Co., Ltd 15315790065 15315790065 1748782088@qq.com China 105 58
Xingyuan(Inner Mongolia)Advanced Material Technology Co.,Ltd, 13770809750 zsj@xyxcl.cc China 104 58
Shanghai Hanyang Chemical Products Co., Ltd. 18063541133 18063541133 zhangzhen198705@sina.com China 496 58
Shandong Xinmuyuan Chemical Technology Co., Ltd 19105383610 83809669@qq.com China 402 58
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Beijing Donghualituo Techonlogy Development Co.,Ltd. 010-88425576 sales@dhltchem.com China 793 59

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Thiophosgene Spectrum

carbonchlorosulfide Carbonic dichloride, thio- carbonothioicdichloride Carbonyl chloride, thio- Dichlorothiocarbonyl Phosgene, thio- Thiocarbonic dichloride THIOPHOSGENE Thiophosgene, AcroSeal, 97% Carbon Dichloride Sulfide Carbonyl Sulfide Dichloride DichlorothioforMaldehyde Thiophosgene, 95%, AcroSeal Carbonothioyl dichloride Chlorothioformic acid chloride Dichloromethanethione Thiophosgene,97% Thiophosgene, 95%, J&KSeal Thiophosg thio-carbonicdichlorid thiocarbonicdichloride thio-carbonylchlorid thiocarbonyldichloride Thiofosgen thiofosgen(czech) Thiokarbonylchlorid thiokarbonylchlorid(czech) thio-phosgen Thiophosgene (Thiocarbonyl chloride) 463-71-8 Thiophosgene Thiophosgene, 85%, AcroSeal&trade Carbon chlorosulfide CSCl2 THIOCARBONYL CHLORIDE Thiocarbonyl dichloride Thiocarbonic acid Thiocarbonic acid (H2CS3) Thiophosgene / Carbonothioic dichloride 463-71-8 CCl2S Coupling Phosgene Derivatives Synthetic Reagents Organics