ChemicalBook >> CAS DataBase List >>Zinc chloride

Zinc chloride

CAS No.
7646-85-7
Chemical Name:
Zinc chloride
Synonyms
ZnCl2;TRIS BASE;2-AMINO-2-(HYDROXYMETHYL)PROPANE-1,3-DIOL;ZnCl;TRIS BUFFER;TRIZMA BASE;TRIS AMINO;TRISAMINE;TRIS(HYDROXYMETHYL)METHYLAMINE;TROMETAMOLUM
CBNumber:
CB4854265
Molecular Formula:
Cl2Zn
Lewis structure
zncl2 lewis structure
Molecular Weight:
136.3
MDL Number:
MFCD00011295
MOL File:
7646-85-7.mol
MSDS File:
SDS
Last updated:2025-12-17 09:49:47
Product description Number Pack Size Price
Zinc chloride 0.1 M solution 39059 1mL $40.7
Zinc chloride 0.1 M solution 39059 100mL $107.1
Zinc chloride puriss., meets analytical specification of Ph. Eur., BP, USP, 98-100.5% 14422 500g $144
Zinc chloride puriss., meets analytical specification of Ph. Eur., BP, USP, 98-100.5% 14422 1kg $263
Zinc chloride EMPROVE? EXPERT, Ph. Eur., BP, USP 1.28221 1kg $222
More product size

Zinc chloride Properties

Melting point 293 °C (lit.)
Boiling point 732 °C (lit.)
Density 1.01 g/mL at 20 °C
bulk density 1400-1800kg/m3
vapor pressure 1 mm Hg ( 428 °C)
Flash point 732°C
storage temp. 2-8°C
solubility H2O: 4 M at 20 °C, clear, colorless
form crystalline
pka pKa 6.06 (Uncertain)
Specific Gravity 2.91
color white
PH 5 (100g/l, H2O, 20℃)
Odor wh. cubic cryst., odorless
Water Solubility 432 g/100 mL (25 ºC)
Sensitive Hygroscopic
Merck 14,10132
crystal system square
Space group I42d
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.540.541.0339090900.301
Exposure limits ACGIH: TWA 1 mg/m3; STEL 2 mg/m3
OSHA: TWA 1 mg/m3
NIOSH: IDLH 50 mg/m3; TWA 1 mg/m3; STEL 2 mg/m3
Stability hygroscopic
Cosmetics Ingredients Functions SOOTHING
ANTIMICROBIAL
ORAL CARE
ASTRINGENT
InChIKey JIAARYAFYJHUJI-UHFFFAOYSA-L
FDA 21 CFR 182.8985; 582.5985; 182.70; 310.545; 582.80
Substances Added to Food (formerly EAFUS) ZINC CHLORIDE
SCOGS (Select Committee on GRAS Substances) Zinc chloride
CAS DataBase Reference 7646-85-7(CAS DataBase Reference)
EWG's Food Scores 2-4
FDA UNII 86Q357L16B
ATC code B05XA12
NIST Chemistry Reference Zinc dichloride(7646-85-7)
EPA Substance Registry System Zinc chloride (7646-85-7)
Cosmetics Info Zinc Chloride
UNSPSC Code 51472303
NACRES NA.71

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS05,GHS07,GHS09
Signal word  Danger
Hazard statements  H302-H314-H410
Precautionary statements  P260-P273-P280-P301+P312-P303+P361+P353-P305+P351+P338
Hazard Codes  Xi,N,C,F+,F,Xn
Risk Statements  36/37/38-50/53-34-22-51/53-67-66-19-12-11-40
Safety Statements  26-36-61-60-45-36/37/39-16-36/37
RIDADR  UN 2924 3/PG 1
OEB C
OEL TWA: 1 mg/m3, STEL: 2 mg/m3
WGK Germany  2
RTECS  TY2900000
3
TSCA  TSCA listed
HazardClass  3
PackingGroup  I
HS Code  28273600
Hazardous Substances Data 7646-85-7(Hazardous Substances Data)
Toxicity Inhalation of zinc chloride fumes can injure lungs and respiratory tract. Dusts or fumes also cause dermatitis, boils, conjunctivitis, and gastrointestinal tract upset (Lewis(Sr), R.J. 1996. Sax’s Dangerous Properties of Industrial Materials, 9th ed. New York: Van Nostrand Reinhold).
LD50 oral (rat): 350mg/kg
LCLO (inhalation): 1.960 g/m3/10 min
IDLA 50 mg/m3
Limited Quantities 5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
NFPA 704
0
3 1

Zinc chloride price More Price(145)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 39059 Zinc chloride 0.1 M solution 7646-85-7 1mL $40.7 2025-07-31 Buy
Sigma-Aldrich 39059 Zinc chloride 0.1 M solution 7646-85-7 100mL $107.1 2025-07-31 Buy
Sigma-Aldrich 14422 Zinc chloride puriss., meets analytical specification of Ph. Eur., BP, USP, 98-100.5% 7646-85-7 500g $144 2025-07-31 Buy
Sigma-Aldrich 14422 Zinc chloride puriss., meets analytical specification of Ph. Eur., BP, USP, 98-100.5% 7646-85-7 1kg $263 2025-07-31 Buy
Sigma-Aldrich 1.28221 Zinc chloride EMPROVE? EXPERT, Ph. Eur., BP, USP 7646-85-7 1kg $222 2025-07-31 Buy
Product number Packaging Price Buy
39059 1mL $40.7 Buy
39059 100mL $107.1 Buy
14422 500g $144 Buy
14422 1kg $263 Buy
1.28221 1kg $222 Buy

Zinc chloride Chemical Properties,Uses,Production

Description

Zinc chloride is a white deliquescent salt. It forms acidic solutions in water and in polar organic solvents such as ethanol, acetone, and ether. Anhydrous zinc chloride hydrolyzes with moisture to form hydrochloric acid. It also forms complex ions with water, ammonia, and some organic solvents.
Zinc chloride
Zinc chloride reacts with sulphide to minimise release of H2S gas in waste treatment facilities. Zinc chloride 50% solution also serves as a high-quality mercerising agent for cotton. Zinc chloride is incompatible with strong oxidising agents, moisture, cyanides, sulphides, and potassium.

Chemical Properties

Zinc chloride typically appears as white, deliquescent, hexagonal crystals or as a colorless solution. Its fumes consist of white particulate matter dispersed in air. A 10% aqueous solution is acidic to litmus. It is soluble in water, alcohol, glycerol, and ether.

Physical properties

White crystalline powder or granules; hygroscopic; density 2.907 g/cm3; melts at 290°C; vaporizes at 732°C; vapor pressure 1 torr at 428°C and 20 torrat 536°C; highly soluble in water, 432 g/100mL at 25°C; aqueous solution acidic in litmus test; also soluble in ethanol, glycerol, and acetone.

Uses

Zinc chloride is used as a wood preservative and in fireproofing timber. Other uses are as a deodorant in disinfecting fluids; in dental cements; in electroplating; in etching metals and glass; as flux for soldering; as a mordant in printing and dyeing textiles; in making dry batteries; in denaturing alcohols; in vulcanizing rubber; in manufacturing parchment; in making artificial silk; in making activated carbon and cold-water glues; and in refining petroleum. Also, zinc chloride is used as a dehydrating and condensing agent in organic syntheses. In medicine it is used as an astringent and antiseptic.

Uses

Zinc chloride is used as an organic catalyst. It is deliquescent, which makes it an excellent dehydrating and drying agent. It is used in electroplating other metals, as an antiseptic, as a component of some deodorants, and as an astringent. It is also used for fireproofing materials and as a food preservative. Zinc chloride is also used in embalming and taxidermy fluids.

Definition

ChEBI: A compound of zinc and chloride ions in the ratio 1:2. It exists in four crystalline forms, in each of which the Zn2+ ions are trigonal planar coordinated to four chloride ions.

Preparation

Zinc chloride is prepared by the reaction of zinc oxide or zinc metal with dilute hydrochloric acid, followed by crystallization:
ZnO + 2HCl → ZnCl2 + H2O
Zn + 2HCl → ZnCl2 + H2

Definition

zinc chloride: A white crystalline compound, ZnCl2. The anhydrous salt, which is deliquescent, can be made by the action of hydrogen chloride gas on hot zinc; r.d. 2.9; m.p. 283°C; b.p. 732°C. It has a relatively low melting point and sublimes easily, indicating that it is a molecular compound rather than ionic. Various hydrates also exist. Zinc chloride is used as a catalyst, dehydrating agent, and Ûux for hard solder. It was once known as butter of zinc.

General Description

Zinc chloride is a colorless liquid. Zinc chloride is mildly corrosive to metals. Zinc chloride causes burns to eyes, skin and mucous membranes.

Air & Water Reactions

When dissolved in water, Zinc chloride is a strong acid. [Handling Chemicals Safely 1980. p. 964]

Reactivity Profile

Acidic salts, such as ZINC CHLORIDE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.

Hazard

Inhalation of zinc chloride fumes can injure lungs and respiratory tract. Dusts or fumes also cause dermatitis, boils, conjunctivitis, and gastrointestinal tract upset (Lewis(Sr), R.J. 1996. Sax’s Dangerous Properties of Industrial Materials, 9th ed. New York: Van Nostrand Reinhold). LD50 oral (rat): 350mg/kg LCLO (inhalation): 1.960 g/m3/10 min.

Health Hazard

Exposures to zinc chloride cause adverse health effects and poisoning. On contact with the skin, zinc chloride causes skin burns and ulcerations, redness, eyes develop pain and blurred vision, and any splashes from solutions may cause eye damage. It is extremely destructive to the tissues of the mucous membranes and upper respiratory tract. The symptoms of toxicity include, but are not limited to, burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting, and irritation or corrosion to the gastrointestinal tract with abdominal pain. After repeated exposures of zinc chloride through skin contact, occupational workers develop varying degrees of skin problems, such as dermatitis and skin ulcerations. Repeated inhalation of zinc chloride causes occupational asthma among workers

Health Hazard

Solid or water solution is astringent and can irritate the eyes. When ingested, can cause intoxication, severe irritation of stomach, nausea, vomiting, and diarrhea.

Fire Hazard

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.

reaction suitability

reagent type: catalyst
core: zinc

Safety Profile

Poison by ingestion, intravenous, and intraperitoneal routes. Human systemic effects by inhalation: pulm- onary changes. An experimental teratogen. Experimental reproductive effects. Questionable carcinogen with experimental tumorigenic data. Human mutation data reported. A corrosive irritant to skin, eyes, and mucous membranes, Exposure to ZnCl2 fumes or dusts can cause dermatitis, boils, conjunctivitis, gastrointestinal tract upsets. The fumes are highly toxic. Incompatible with potassium. Mixtures of the powdered chloride and powdered zinc are flammable. When heated to decomposition it emits toxic fumes of Cland ZnO. See also ZINC COMPOUNDS and CHLORIDES.

Potential Exposure

Zinc chloride is used in iron galvanizing; as a wood preservative; for dry battery cells; as a soldering flux; in textile finishing; in vulcanized fiber; reclaiming rubber; in oil and gas well operations; oil refining; manufacturing of parchment paper; in dyes; activated carbon; in chemical synthesis; in adhesives; dentists’ cement; deodorants, disinfecting and embalming solutions; and taxidermy. It is also produced by military screeningsmoke.

Shipping

UN2331 Zinc chloride, anhydrous, Hazard class: 8; Labels: 8-Corrosive material. UN1840 Zinc chloride, solution, Hazard class: 8; Labels: 8-Corrosive material.

Purification Methods

The anhydrous material can be sublimed under a stream of dry HCl, followed by heating to 400o in a stream of dry N2. It sublimes at high vacuum. Also purify it by refluxing (50g) in dioxane (400mL) with 5g zinc dust, filtering hot and cooling to precipitate ZnCl2. Crystallise it from dioxane and store it in a desiccator over P2O5. It has also been dried by refluxing in thionyl chloride. [Weberg et al. J Am Chem Soc 108 6242 1986.] Hygroscopic: minimal exposure to the atmosphere is necessary. [Wagenknecht & Juza Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1070 1965.]

Incompatibilities

Aqueous solutions are strongly acidic. Incompatible with bases and potassium. Incompatible with strong oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Corrosive to metals.

Waste Disposal

Dump in water; add soda ash and stir, then neutralize and flush to sewer with water. Alternatively, zinc chloride may be recovered from spent catalysts and used in acrylic fiber spinning solutions.

Precautions

Exposures to zinc chloride are dangerous, corrosive, and cause burns to any area of contact. Harmful if swallowed or inhaled. Affects the cardiovascular system.

Global( 669)Suppliers
Supplier Tel Email Country ProdList Advantage
Qingdao Trust Agri Chemical Co.,Ltd
+86-008615963231493 +86-008613573296305 trustagri@hotmail.com China 301 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34563 58
Aladdin Scientific
tp@aladdinsci.com United States 52923 58
Hengshui Haoye Co.,Ltd.
+86-2102300 +86-18632882519 hy@haoyecom.cn China 301 58
Hebei Chuanghai Biotechnology Co., Ltd
+8615350571055 Sibel@chuanghaibio.com China 8754 58
Hebei Chuanghai Biotechnology Co,.LTD
+86-13131129325 sales1@chuanghaibio.com China 5242 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21602 55
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679 +8618949832763 info@tnjchem.com China 2988 55
Shanxi Naipu Import and Export Co.,Ltd
+86-13734021967 +8613734021967 kaia@neputrading.com China 1001 58
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29838 58

Related articles

  • Is zinc chloride safe for humans?
  • Zinc chloride is corrosive by ingestion and highly irritant by inhalation. Topical zinc chloride causes ulceration and burns, ....
  • Apr 25,2024

View Lastest Price from Zinc chloride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Zinc chloride pictures 2026-01-05 Zinc chloride
7646-85-7
US $10.00 / kg 1kg 99% 100 Hebei Chuanghai Biotechnology Co., Ltd
Zinc chloride pictures 2025-12-02 Zinc chloride
7646-85-7
US $2.30 / KG 1KG 98% 2000ton per month Qingdao Trust Agri Chemical Co.,Ltd
Zinc chloride pictures 2025-09-26 Zinc chloride
7646-85-7
US $4.00 / kg 10kg 98% 96% 3000tons Hebei Dangtong Import and export Co LTD
  • Zinc chloride pictures
  • Zinc chloride
    7646-85-7
  • US $10.00 / kg
  • 99%
  • Hebei Chuanghai Biotechnology Co., Ltd
  • Zinc chloride pictures
  • Zinc chloride
    7646-85-7
  • US $2.30 / KG
  • 98%
  • Qingdao Trust Agri Chemical Co.,Ltd
  • Zinc chloride pictures
  • Zinc chloride
    7646-85-7
  • US $4.00 / kg
  • 98% 96%
  • Hebei Dangtong Import and export Co LTD

Zinc chloride Spectrum

Zinc Chloride, MB Grade (1.08811) Zincchlorideultradry ZINC CHLORIDE, 98+% ZINC CHLORIDE DRY, PURE ZINC CHLORIDE, ACS zinc atomic spectroscopy standard concentrate 1.00 g zn zinc chloride, 1m in diethyl ether zinc chloride, 1m in diethyl ether, packaged under argon in resealable chemseal zinc standard concentrate 10.00 g zn ZINCCHLORIDE,FUSEDSTICKS ZINCCHLORIDE,GRANULAR,REAGENT,ACS ZINCCHLORIDE,GRANULAR,TECHNICAL ZINCCHLORIDE,GRANULAR,USP,JP ZINC(II)CHLORIDE ZINC CHLORIDE, ULTRADRY: 99.99% Zinc chloride hydrate, Puratronic, 99.999% (metals basis) Zinc chloride hydrate Zinc chloride,98.5%,for analysis Zinc chloride,2M solution in 2-methyltetrahydrofuran Zinc chloride ZINC CHLORIDE P. A. BIOCHEMICA Zinc chloride, 1M in diethyl ether, packaged under Argon in resealable ChemSealTM bottles Zinc chloride, ultra dry, 99.99% (metals basis) Zinc chloride, anhydrous, 98+% Zinc Chloride (16% in Ethyl Ether, ca. 1.0mol/L) Zinc chloride, 2M solution in 2-methyltetrahydrofuran, AcroSeal§3 Zinc chloride, 0.7M solution in THF, AcroSeal Zinc chloride, extra pure, (trace metal basis), 99.99% Zinc chloride, 1.0M solution in diethyl ether, AcroSeal Zinc chloride, anhydrous, (trace metal basis), 99.99% Zinc chloride, 2M solution in 2-Methyltetrahydrofuran, AcroSeal Zinc Chloride (ca. 7% in Tetrahydrofuran, ca. 0.5Mol/L) Zinc chloride, 0.7M soln. in THF EMPROVE(R) Zinc Chloride, Extra Pure, USP, Ph Eur, BP, JP Zinc Chloride (ca. XX% in 2-Methyltetrahydrofuran, ca. 1.9Mol/L) Zinc chloride, 97+%, ACS reagent Zinc chloride, 99.99%, (trace Metal basis), anhydrous Zinc chloride, 99.99%, (trace Metal basis), extra pure Zinc chloride, 0.7M solution in THF, AcroSeal 800ML Zinc chloride, for analysis ACS, 97+% 500GR TRISAMINE TRIS AMINO TRIS BASE TRIS, ENDOTOXIN TESTED TRIS[HYDROXYMETHYL] AMINOETHANE TRIS (HYDROXYMETHYL) AMINOMETHANE, 7-9 TRIS(HYDROXYMETHYL)METHYLAMINE TRISMAT TRISMAT(R) TRISMAT(TM) TRIS PRE-SET CRYSTALS REAGENT TROMETHANOL TROMETAMOLUM TRIZMA BASE TRIZMA(R) BASE TRIZMA(R) PRE-SET TYPE 7.2-FT chloruredezinc chloruredezinc(french)