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Tetrafluorophthalic anhydride

CAS No.
652-12-0
Chemical Name:
Tetrafluorophthalic anhydride
Synonyms
4,5,6,7-tetrafluoroisobenzofuran-1,3-dione;Beilstein;PTFE anhydride;PTFE phthalic anhydride;4,5,6,7-Tetrafluoro-1,3-d;Tetrafluorophathlic Anhydride;TETRAFLUOROPHTHALIC ANHYDRIDE;Tetrafluorophthalic anhydride,97%;Tetrafluorophthalic anhydrid, 97%;Tetrafluoroisobenzofuran-1,3-dione
CBNumber:
CB7145393
Molecular Formula:
C8F4O3
Molecular Weight:
220.08
MDL Number:
MFCD00039697
MOL File:
652-12-0.mol
MSDS File:
SDS
Last updated:2026-08-28 09:47:23
Product description Number Pack Size Price
Tetrafluorophthalic anhydride 97% 339016 5g $169
Tetrafluorophthalic anhydride 97% 339016 1g $67.8
Tetrafluorophthalic Anhydride >95.0%(T) T2381 1g $35
Tetrafluorophthalic Anhydride >95.0%(T) T2381 5g $99
Tetrafluorophthalic anhydride FT70908 10g $276.5
More product size

Tetrafluorophthalic anhydride Properties

Melting point 94-96 °C(lit.)
Boiling point 332.6±42.0 °C(Predicted)
Density 1.843±0.06 g/cm3(Predicted)
storage temp. 2-8°C, sealed storage, away from moisture
solubility Soluble in most organic solvents and acetic acid.
form Powder
color Light grayish to beige
Sensitive Moisture Sensitive
InChI InChI=1S/C8F4O3/c9-3-1-2(8(14)15-7(1)13)4(10)6(12)5(3)11
InChIKey BJDDKZDZTHIIJB-UHFFFAOYSA-N
SMILES C1(=O)C2=C(C(F)=C(F)C(F)=C2F)C(=O)O1
CAS DataBase Reference 652-12-0(CAS DataBase Reference)
UNSPSC Code 12162002
NACRES NA.23

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
PPE Eyeshields, Gloves, type N95 (US)
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  37/39-26-36
WGK Germany  3
Hazard Note  Irritant
HazardClass  IRRITANT, MOISTURE SENSITIVE
HS Code  29173990
Storage Class 11 - Combustible Solids
NFPA 704
0
2 0

Tetrafluorophthalic anhydride price More Price(46)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 339016 Tetrafluorophthalic anhydride 97% 652-12-0 5g $169 2026-04-30 Buy
Sigma-Aldrich 339016 Tetrafluorophthalic anhydride 97% 652-12-0 1g $67.8 2021-12-16 Buy
TCI Chemical T2381 Tetrafluorophthalic Anhydride >95.0%(T) 652-12-0 1g $35 2026-04-30 Buy
TCI Chemical T2381 Tetrafluorophthalic Anhydride >95.0%(T) 652-12-0 5g $99 2026-04-30 Buy
Biosynth FT70908 Tetrafluorophthalic anhydride 652-12-0 10g $276.5 2026-06-04 Buy
Product number Packaging Price Buy
339016 5g $169 Buy
339016 1g $67.8 Buy
T2381 1g $35 Buy
T2381 5g $99 Buy
FT70908 10g $276.5 Buy

Tetrafluorophthalic anhydride Chemical Properties,Uses,Production

Chemical Properties

Light greyish to beige powder

Uses

Tetrafluorophthalic anhydride is used as polyimide monomer.

Synthesis

1,2-Benzenedicarbonyl difluoride, 3,4,5,6-tetrafluoro-

5292-39-7

Tetrafluorophthalic anhydride

652-12-0

In a 500 mL three-necked round-bottomed flask equipped with a reflux condenser and a mechanical stirrer, 100 g (0.413 mol) of 3,4,5,6-tetrafluorophthaloyl difluoride (derived from the distillation isolate of Example 2), 43.8 g (0.413 mol) of anhydrous sodium carbonate and 200 g of xylene were added. The reaction mixture was heated to 130°C and kept for 1.5 hours under vigorous stirring. Upon completion of the reaction, the insoluble inorganic salt was removed by thermal filtration. Subsequently, the filtrate was distilled under reduced pressure to remove the solvent, resulting in 84.9 g of the white solid product 3,4,5,6-tetrafluorophthalic anhydride in 93.4% yield.

References

[1] Patent: US5523476, 1996, A

Tetrafluorophthalic anhydride Preparation Products And Raw materials

Global( 208)Suppliers
Supplier Tel Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
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View Lastest Price from Tetrafluorophthalic anhydride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Tetrafluorophthalic anhydride pictures 2022-02-19 Tetrafluorophthalic anhydride
652-12-0
1KG 97.6% 100 tons Honest Joy Holdings Limited
Tetrafluorophthalic anhydride pictures 2019-07-14 Tetrafluorophthalic anhydride
652-12-0
$1.00 1KG 99% 1ton Career Henan Chemical Co
Tetrafluorophathlic Anhydride 3,4,5,6-TETRAFLUOROPHTHALIC ANHYDRIDE TETRAFLUOROPHTHALIC ANHYDRIDE 3,4,5,6-Tetrafluorophthalic anhydride 98% 3,4,5,6-Tetrafluorophthalicanhydride98% 4,5,6,7-Tetrafluoro-2-benzofuran-1,3-dione 3-[[4-chloro-6-[3-(triethylammonio)propylamino]-1,3,5-triazin-2-yl]amino]propyl-triethylammonium diiodide 4,5,6,7-Tetrafluoro-1,3-dihydroisobenzofuran-1,3-dione 4,5,6,7-Tetrafluoro-1,3-isobenzofurandione Tetrafluoroisobenzofuran-1,3-dione Tetrafluorophthalic anhydride,97% Tetrafluorophthalic anhydrid ,98.5% PTFE anhydride PTFE phthalic anhydride 4,5,6,7-Tetrafluoro-2-benzofuran-1,3-dione, 4,5,6,7-Tetrafluoroisobenzofuran-1,3-dione 1,3-Isobenzofurandione,4,5,6,7-tetrafluoro- Tetrafluorophthalic anhydrid, 97% 4,5,6,7-Tetrafluoro-1,3-d Beilstein 3,4,5,6-Tetrafluorophtlic anhydride Tetrafluorophthalic Acid Anhydride 4,5,6,7-TetrafluoroPhthalic Anhydride 4,5,6,7-tetrafluoroisobenzofuran-1,3-dione 652-12-0 65212-12-0 651-12-0 651-12-0 C8F4O3 Monomers Polymer Science Anhydride Monomers Fluorobenzene Highly Purified Reagents Other Categories Refined Products by Sublimation Phthalic Acids, Esters and Derivatives