Tetraphenylarsonium chloride
- CAS No.
- 507-28-8
- Chemical Name:
- Tetraphenylarsonium chloride
- Synonyms
- Nsc 18857;Ccris 9327;Einecs 208-070-6;Phenylarsonium chloride;tetraphenyl-arsoniuchloride;tetraphenylarseniumchloride;Tetraphenylarsenic chloride;Tetraphenylarsonium chloride;phenylarsoniumchloride(ph4ascl);Tetraphenylarsonium(V) chloride
- CBNumber:
- CB7228610
- Molecular Formula:
- C24H20As.Cl
- Molecular Weight:
- 418.79
- MDL Number:
- MFCD00011908
- MOL File:
- 507-28-8.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 258-260 °C(lit.) |
|---|---|
| form | Powder |
| color | white |
| Water Solubility | Freely soluble in water. Soluble in alcohol. Sparingly soluble in acetone |
| Merck | 14,9236 |
| BRN | 3580063 |
| Stability | Stable. Incompatible with strong oxidizing agents. |
| InChI | 1S/C24H20As.ClH.H2O/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;;/h1-20H;1H;1H2/q+1;;/p-1 |
| InChIKey | NGDWSDTZKCSLRK-UHFFFAOYSA-M |
| SMILES | O.[Cl-].c1ccc(cc1)[As+](c2ccccc2)(c3ccccc3)c4ccccc4 |
| REACH Annex XVII Substances List | Tetraphenylarsonium chloride (507-28-8) |
| CAS DataBase Reference | 507-28-8(CAS DataBase Reference) |
| EWG's Food Scores | 1 |
| FDA UNII | AG51MKF20J |
| EPA Substance Registry System | Arsonium, tetraphenyl-, chloride (507-28-8) |
| UNSPSC Code | 12161600 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS06,GHS09 |
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|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H301+H331-H410 | |||||||||
| Precautionary statements | P273-P301+P310+P330-P304+P340+P311 | |||||||||
| Hazard Codes | T,N | |||||||||
| Risk Statements | 23/25-50/53 | |||||||||
| Safety Statements | 20/21-28-45-60-61 | |||||||||
| RIDADR | UN 3465 6.1/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | CI0600000 | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | III | |||||||||
| Storage Class | 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects |
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| Hazard Classifications | Acute Tox. 3 Inhalation Acute Tox. 3 Oral Aquatic Acute 1 Aquatic Chronic 1 |
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| Limited Quantities | 5.0 kg (11 lbs) (solid) | |||||||||
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L) | |||||||||
| NFPA 704 |
|
Tetraphenylarsonium chloride price More Price(11)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | T25305 | Tetraphenylarsonium(V) chloride hydrate 97% | 507-28-8 | 2.5g | $171 | 2024-03-01 | Buy |
| Sigma-Aldrich | T25305 | Tetraphenylarsonium(V) chloride hydrate 97% | 507-28-8 | 10g | $648 | 2024-03-01 | Buy |
| Strem Chemicals | 33-3050 | Tetraphenylarsonium chloride monohydrate, 99% | 507-28-8 | 1g | $73 | 2021-12-16 | Buy |
| Strem Chemicals | 33-3050 | Tetraphenylarsonium chloride monohydrate, 99% | 507-28-8 | 5g | $290 | 2021-12-16 | Buy |
| Strem Chemicals | 33-3050 | Tetraphenylarsonium chloride monohydrate, 99% | 507-28-8 | 25g | $1162 | 2021-12-16 | Buy |
Tetraphenylarsonium chloride Chemical Properties, Uses, Production
Chemical Properties
crystalline solid
Uses
Cation exchange reagent. Used to prepare arsonium amide, oxime, and carbohydrate derivatives.
reaction suitability
core: arsenic
reagent type: catalyst
Safety Profile
Poison by intravenous route. When heated to decomposition it emits toxic fumes of As and Cl-.
Purification Methods
A neutralised aqueous solution is evaporated to dryness. The residue is extracted into absolute EtOH, evaporated to a small volume and precipitated by addition of absolute Et2O. It is again dissolved in a small volume of absolute EtOH or ethyl acetate and re-precipitated with Et2O. Alternatively, it is purified by adding conc HCl to precipitate the chloride dihydrate. Redissolve in water, neutralise with Na2CO3 and evaporate to dryness. The residue is extracted with CHCl3 and finally crystallised from CH2Cl2 or EtOH by adding Et2O. If the aqueous layer is somewhat turbid treat. it with Celite and filter through filter paper. It can be dehydrated before use in a vacuum. The tetrafluoroborate salt has m 293-295o (needles from MeCN), and the picrate salt has m 203-204o (from EtOH). [Blicke et al. J Am Chem Soc 57 702 1935, Duke & Brown J Am Chem Soc 76 1443 1954, Popov & Humphrey J Am Chem Soc 81 2043 1959, Singhal & Raj Synth Inorg Met-org Chem 23 1011 1993, Beilstein 16 III 1006, 16 IV 1170.] POISONOUS.
Tetraphenylarsonium chloride Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| Syntechem Co.,Ltd | info@syntechem.com | China | 12973 | 57 | |
| Tianjin heowns Biochemical Technology Co., Ltd. | 400 638 7771 | sales@heowns.com | China | 14412 | 57 |
| Sinopharm Chemical Reagent Co,Ltd. | 86-21-63210123 | sj_scrc@sinopharm.com | China | 9791 | 79 |
| Spectrum Chemical Manufacturing Corp. | 021-021-021-67601398-809-809-809 15221380277 | marketing_china@spectrumchemical.com | China | 9643 | 60 |
| Chengdu Ai Keda Chemical Technology Co., Ltd. | 4008-755-333 18080918076 | 800078821@qq.com | China | 9706 | 55 |
| 9ding chemical ( Shanghai) Limited | 4009209199 | sales@9dingchem.com | China | 22497 | 55 |
View Latest Price from Tetraphenylarsonium chloride manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2021-07-02 | TETRAPHENYLARSONIUM CHLORIDE
507-28-8
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd | ||
 |
2019-07-06 | TETRAPHENYLARSONIUM CHLORIDE
507-28-8
|
$1.00 | 1KG | 98% | 1 | Career Henan Chemical Co |
-
- TETRAPHENYLARSONIUM CHLORIDE
507-28-8
- $10.00-15.00
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
-
- TETRAPHENYLARSONIUM CHLORIDE
507-28-8
- $1.00
- 98%
- Career Henan Chemical Co
