(3-BroMo-4-Methylphenoxy)(tert-butyl)diMethylsilane
- CAS No.
- 164513-48-8
- Chemical Name:
- (3-BroMo-4-Methylphenoxy)(tert-butyl)diMethylsilane
- Synonyms
- (3-BroMo-4-Methylphenoxy)(tert-butyl)diMethylsilane;Benzene, 2-bromo-4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-methyl-
- CBNumber:
- CB72662010
- Molecular Formula:
- C13H21BrOSi
- Molecular Weight:
- 301.29
- MDL Number:
- MFCD24847837
- MOL File:
- 164513-48-8.mol
- MSDS File:
- SDS
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H315-H319 |
| Precautionary statements | P305+P351+P338 |
(3-BroMo-4-Methylphenoxy)(tert-butyl)diMethylsilane price More Price(32)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Matrix Scientific | 126809 | (3-Bromo-4-methylphenoxy)-(tert-butyl)dimethylsilane | 164513-48-8 | 1.00g | $90 | 2026-05-18 | Buy |
| Matrix Scientific | 126809 | (3-Bromo-4-methylphenoxy)-(tert-butyl)dimethylsilane | 164513-48-8 | 5.00g | $270 | 2026-05-18 | Buy |
| Matrix Scientific | 126809 | (3-Bromo-4-methylphenoxy)-(tert-butyl)dimethylsilane | 164513-48-8 | 10.00g | $450 | 2026-05-18 | Buy |
| Synthonix | B57237 | (3-Bromo-4-methylphenoxy)(tert-butyl)dimethylsilane 97% | 164513-48-8 | 1g | $20 | 2026-05-06 | Buy |
| Synthonix | B57237 | (3-Bromo-4-methylphenoxy)(tert-butyl)dimethylsilane 97% | 164513-48-8 | 5g | $30 | 2026-05-06 | Buy |
(3-BroMo-4-Methylphenoxy)(tert-butyl)diMethylsilane Chemical Properties, Uses, Production
Synthesis
60710-39-6
18162-48-6
164513-48-8
Step 1: To a solution of 3-bromo-4-methylphenol (0.20 g) in dichloromethane (3 mL) cooled in an ice bath, tert-butyldimethylsilyl chloride (0.18 g) and triethylamine (0.23 mL) were added. Subsequently, 4-dimethylaminopyridine (13 mg) was added and the reaction mixture was stirred overnight at room temperature. Upon completion of the reaction, it was diluted with the addition of dichloromethane and the organic layer was washed sequentially with 1 M hydrochloric acid, aqueous NaHCO3 and brine and then dried with anhydrous MgSO4. The solvent was evaporated under reduced pressure and the residue was purified by silica gel column chromatography (eluent: cyclohexane/ethyl acetate) to give (3-bromo-4-methylphenoxy)(tert-butyl)dimethylsilane. Yield: 0.25 g (78% theoretical yield); LC (Method 1): tR = 1.59 min.
References
[1] Patent: WO2012/72691, 2012, A1. Location in patent: Page/Page column 107-108
[2] Patent: US2012/302566, 2012, A1. Location in patent: Page/Page column 48
[3] Organic Letters, 2012, vol. 14, # 9, p. 2350 - 2353
(3-BroMo-4-Methylphenoxy)(tert-butyl)diMethylsilane Preparation Products And Raw materials
Raw materials
Preparation Products
(3-BroMo-4-Methylphenoxy)(tert-butyl)diMethylsilane Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| Shanghai YuYuan Pharmaceutical Co., Ltd. | 13052276172 | product@yuyuanpharm.com | China | 402 | 55 |
| Shanghai HuanChuan Industry Co.,Ltd. | 021-61478794 | sales@hcshhai.com | China | 9781 | 50 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131885 | 58 |
| Hangzhou Molcore Biopharmatech Co.,Ltd | 400-711-5280 86-571-81025280 | sales@molcore.com | China | 9957 | 58 |
| Aikon International Limited | 025-66061636 19370895928 | qqyang@aikonchem.com | China | 15810 | 58 |
| Shanghai Jizhi Biochemical Technology Co. Ltd. | 021-4009004166/18616739031 18616739031 | 3007523370@qq.com | China | 40000 | 58 |
| Career Henan Chemica Co | +86-0371-86658258 +86-13203830695 | laboratory@coreychem.com | China | 30203 | 58 |
| Shanghai Lanle Bird Industrial Co., Ltd. | 15021845385 | 765325601@qq.com | China | 3607 | 58 |
| Energy Chemical | 021-58432009 400-005-6266 | marketing@energy-chemical.com | China | 44871 | 58 |
