ChemicalBook >> CAS DataBase List >>(R)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[7,6,1,2-cde]azepinium bromide

(R)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[7,6,1,2-cde]azepinium bromide

(R)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[7,6,1,2-cde]azepinium bromide structure

CAS No.: 887938-70-7

Chemical Name:: (R)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[7,6,1,2-cde]azepinium bromide

Synonyms: (R)-Dibutyl Maruoka Catalyst (R);(11BR)-(-)-4,4-DIBUTYL-4,5-DIHYDRO-2,6-&;(11bR)-(-)-4,4-Dibutyl-4,5-dihydro-2,6-bis(3,4,5-trifluorophenyl)-3H-dinaphth[2,1-c:1,2-e]azepiniu;(R)-4,4-DIBUTYL-2,6-BIS(3,4,5-TRIFLUOROPHENYL)-4,5-DIHYDRO-3H-DINAPHTHO'7,6,1,2-CDEAZEPINIUM BROMIDE;(R)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphthol[7,6,1,2-cde]azepiniumbromide;(R)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[7,6,1,2-cde]azepinium bromide;4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]azepin-4-ium bromide;(11bR)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]azepinium bromide;(11bR)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1'',2''-e]azepinium bromide;(11bR)-(-)-4,4-Dibutyl-4,5-dihydro-2,6-bis(3,4,5-trifluorophenyl)-3H-dinaphth[2,1-c:1μ,2μ-e]azepinium bromide

CBNumber:: CB7501667

Molecular Formula:: C42H36BrF6N

Molecular Weight:: 748.6363592

MDL Number:: MFCD09264271

MOL File:: 887938-70-7.mol

MSDS File:: SDS

Last updated:2026-09-12 18:54:59

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(R)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[7,6,1,2-cde]azepinium bromide Properties

Melting point	223-228 °C
form	Powder
color	brown
InChIKey	LOMUZNOWQYZTRP-UHFFFAOYSA-M
SMILES	CCCC[N+]1(CCCC)Cc2c(cc3ccccc3c2-c4c(C1)c(cc5ccccc45)-c6cc(F)c(F)c(F)c6)-c7cc(F)c(F)c(F)c7
UNSPSC Code	12352005
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H315-H319-H335
Precautionary statements	P302+P352-P305+P351+P338
target organs	Respiratory system
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26
WGK Germany	3
Storage Class	11 - Combustible Solids
Hazard Classifications	Eye Irrit. 2 Skin Irrit. 2 STOT SE 3

(R)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[7,6,1,2-cde]azepinium bromide price More Price(11)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	687596	(11bR)-(–)-4,4-Dibutyl-4,5-dihydro-2,6-bis(3,4,5-trifluorophenyl)-3H-dinaphth[2,1-c:1′,2′-e]azepinium bromide Nagase purity	887938-70-7	50mg	$306	2026-04-30	Buy
Strem Chemicals	07-0380	(11bR)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]azepinium bromide	887938-70-7	50mg	$213	2021-12-16	Buy
Strem Chemicals	07-0380	(11bR)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]azepinium bromide	887938-70-7	250mg	$935	2021-12-16	Buy
aablocks	AA00GVEH	(11bR)-(–)-4，4-Dibutyl-4，5-dihydro-2，6-bis(3，4，5-trifluorophenyl)-3H-dinaphth[2，1-c:1′，2′-e]azepinium bromide 98%	887938-70-7	25mg	$140	2026-05-28	Buy
aablocks	AA00GVEH	(11bR)-(–)-4，4-Dibutyl-4，5-dihydro-2，6-bis(3，4，5-trifluorophenyl)-3H-dinaphth[2，1-c:1′，2′-e]azepinium bromide 98%	887938-70-7	50mg	$253	2026-05-28	Buy

Product number	Packaging	Price	Buy
687596	50mg	$306	Buy
07-0380	50mg	$213	Buy
07-0380	250mg	$935	Buy
AA00GVEH	25mg	$140	Buy
AA00GVEH	50mg	$253	Buy

(R)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[7,6,1,2-cde]azepinium bromide Chemical Properties, Uses, Production

Reaction

2nd Generation Maruoka chiral phase transfer catalyst, for enantioselective alkylation of α-amino acid derivatives, that is easily recovered for recycle by extraction with fluorous solvent.
Catalyst for asymmetric conjugate addition of α-substituted-α-cyanoacetates to α,β-unsaturated acetylenic esters.
Phase transfer catalyzed enantioselective α-alkylation.
Asymmetric amination of β-keto esters.
Diastereo- and enantioselective conjugate addition of α-substituted nitroacetates to maleimides.
Cyclization of β-alkynyl hydrazines.

Uses

Potent phase transfer organocatalyst for asymmetric α-alkylation of glycine derivatives at extremely low loadings.

(R)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[7,6,1,2-cde]azepinium bromide Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[7,6,1,2-cde]azepinium bromide Suppliers

Global Suppliers ( 21)

Supplier	Tel	Email	Country	ProdList	Advantage
J & K SCIENTIFIC LTD.	18210857532 18210857532	jkinfo@jkchemical.com	China	96815	76
Tianjin Derchemist Science & Technology Co., Ltd.	22-58627059 13920586291	zdcomcon@126.com	China	4094	50
Sigma-Aldrich	021-61415566 800-8193336	orderCN@merckgroup.com	China	51389	80
Alfa Chemistry	1-516-6625404	support@alfa-chemistry.com	United States	9170	60
Shanghai Anyinuo Biomedical Technology Co., Ltd.	021-34625901	420970979@qq.com	China	5982	58
Jinan ponder chemical co. LTD	0531-0000	thinklifescience@163.com	China	19684	58
Block Chemical Technology (Shanghai) Co., Ltd.	021-20432219 13918097649	li_jinfei@acblock-lab.com	China	10000	58
Bide Pharmatech Ltd.	400-1647117 13681763483	product02@bidepharm.com	China	59929	58
Shanghai Maclean Biochemical Technology Co., LTD	021-50706066 15221275939	shenlinxing@macklin.cn	China	29676	58
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.	025-025-66113011 15955137747	cb5@aikonchem.com	China	10354	58

Supplier	Advantage
J & K SCIENTIFIC LTD.	76
Tianjin Derchemist Science & Technology Co., Ltd.	50
Sigma-Aldrich	80
Alfa Chemistry	60
Shanghai Anyinuo Biomedical Technology Co., Ltd.	58
Jinan ponder chemical co. LTD	58
Block Chemical Technology (Shanghai) Co., Ltd.	58
Bide Pharmatech Ltd.	58
Shanghai Maclean Biochemical Technology Co., LTD	58
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.	58

887938-70-7 ((R)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[7,6,1,2-cde]azepinium bromide) Related Search:

N-[3,5-bis(trifluoroMethyl)phenyl-N'-[(1R,2R)-2-(11bS)3,5-dihydro-4H-dinaphth[2,1-c:1',2'-e]azepin-4-yl]cyclohexyl]-thiourea (S)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[7,6,1,2-cde]azepinium bromide (11bR,11'bR)-4,4'-(1S,2S)-1,2-cyclohexanediylbis[4,5-dihydro-H-Dinaphth[2,1-c:1',2'-e]azepine (11bS,11'bS)-4,4'-(R,2R)-1,2-cyclohexanediylbis[4,5-dihydro-H-Dinaphth[2,1-c:1',2'-e]azepine (R,R)-3,4,5-Trifluorophenyl-nas bromide

(S,S)-3,4,5-Trifluorophenyl-nas bromide

1of2

(11BR)-(-)-4,4-DIBUTYL-4,5-DIHYDRO-2,6-& (R)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphthol[7,6,1,2-cde]azepiniumbromide (11bR)-(-)-4,4-Dibutyl-4,5-dihydro-2,6-bis(3,4,5-trifluorophenyl)-3H-dinaphth[2,1-c:1μ,2μ-e]azepinium bromide (11bR)-(-)-4,4-Dibutyl-4,5-dihydro-2,6-bis(3,4,5-trifluorophenyl)-3H-dinaphth[2,1-c:1',2'-e]azepinium bromide Nagase purity (R)-4,4-DIBUTYL-2,6-BIS(3,4,5-TRIFLUOROPHENYL)-4,5-DIHYDRO-3H-DINAPHTHO'7,6,1,2-CDEAZEPINIUM BROMIDE (11bR)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]azepinium bromide (11bR)-(-)-4,4-Dibutyl-4,5-dihydro-2,6-bis(3,4,5-trifluorophenyl)-3H-dinaphth[2,1-c:1,2-e]azepiniu 4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]azepin-4-ium bromide (11bR)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1'',2''-e]azepinium bromide (R)-Dibutyl Maruoka Catalyst (R) (11bR)-(–)-4,4-Dibutyl-4,5-dihydro-2,6-bis(3,4,5-trifluorophenyl)-3H-dinaphth[2,1-c:1′,2′-e]azepinium bromide (R)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[7,6,1,2-cde]azepinium bromide 887938-70-7 C42H36F6NBr Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents Phase Transfer Reaction