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ChemicalBook >> CAS DataBase List >>6-Bromo-1-methyl-1H-benzo[d]imidazole

6-Bromo-1-methyl-1H-benzo[d]imidazole

6-Bromo-1-methyl-1H-benzo[d]imidazole Structure
6-Bromo-1-methyl-1H-benzo[d]imidazole structure
CAS No.
53484-16-5
Chemical Name:
6-Bromo-1-methyl-1H-benzo[d]imidazole
Synonyms
6-bromo-1-methylbenzimidazole;1-Methyl-6-bromobenzimidazole;6-Bromo-1-methyl-1H-benzimidazole;1H-Benzimidazole, 6-bromo-1-methyl-;6-bromo-1-methyl-1H-1,3-benzodiazole;6-Bromo-1-methyl-1H-benzo[d]imidazole;6-bromo-1-(methyl-d3)-1H-1,3-benzodiazole
CBNumber:
CB7839386
Molecular Formula:
C8H7BrN2
Molecular Weight:
211.06
MDL Number:
MFCD09027271
MOL File:
53484-16-5.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-09-12 18:55:07
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6-Bromo-1-methyl-1H-benzo[d]imidazole Properties

Boiling point 317.2±34.0 °C(Predicted)
Density 1.60
storage temp. Keep in dark place,Sealed in dry,Room Temperature
pka 4.47±0.10(Predicted)
form powder
color Red/brown

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H332-H335
Precautionary statements  P280-P305+P351+P338-P310
Hazard Codes  Xi,Xn
Risk Statements  22-37/38-41
Safety Statements  26-39
Hazard Note  Irritant
HS Code  2933998090

6-Bromo-1-methyl-1H-benzo[d]imidazole price More Price(48)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Usbiological 234526 6-Bromo-1-methyl-1H-benzo[d]imidazole ≥96% (HPLC) ≥96%(HPLC) 53484-16-5 100mg $200 2026-06-03 Buy
Usbiological 234526 6-Bromo-1-methyl-1H-benzo[d]imidazole ≥96% (HPLC) ≥96%(HPLC) 53484-16-5 250mg $245 2026-06-03 Buy
Usbiological 234526 6-Bromo-1-methyl-1H-benzo[d]imidazole ≥96% (HPLC) ≥96%(HPLC) 53484-16-5 1g $353 2026-06-03 Buy
Usbiological 234526 6-Bromo-1-methyl-1H-benzo[d]imidazole ≥96% (HPLC) ≥96%(HPLC) 53484-16-5 5g $1068 2026-06-03 Buy
Chem-Impex 26274 6-Bromo-1-methyl-1H-benzo[d]imidazole ≥96%(HPLC) 53484-16-5 100MG $60.39 2026-05-19 Buy
Product number Packaging Price Buy
234526 100mg $200 Buy
234526 250mg $245 Buy
234526 1g $353 Buy
234526 5g $1068 Buy
26274 100MG $60.39 Buy

6-Bromo-1-methyl-1H-benzo[d]imidazole Chemical Properties, Uses, Production

Synthesis

1,2-BENZENEDIAMINE, 4-BROMO-N2-METHYL-

337915-79-4

Trimethoxymethane

149-73-5

6-BROMO-1-METHYL-1H-BENZO[D]IMIDAZOLE

53484-16-5

General procedure for the synthesis of 6-bromo-1-methyl-1H-benzo[d]imidazole from 4-bromo-2-methylaminoaniline and trimethyl orthoformate: Stannous chloride dihydrate (9.8 g, 43 mmol) was added batchwise to a solution of intermediate 2 (5 g, 21.6 mmol) in ethanol (200 ml), and the mixture was heated and refluxed for 4 h, then concentrated under reduced pressure. The residue was treated with water (200 ml) and 1N sodium hydroxide solution (100 ml). After extraction with dichloromethane, the organic phase was dried with anhydrous sodium sulfate and concentrated under reduced pressure. The residue was dissolved in toluene (50 ml), trimethyl orthoformate (2.6 ml, 24 mmol) and p-toluenesulfonic acid (0.2 g) were added, and the mixture was heated to reflux for 2 h and then concentrated under reduced pressure. The residue was purified by silica gel column chromatography, eluting with dichloromethane/methanol (95/5). 6-Bromo-1-methyl-1H-benzo[d]imidazole was obtained as a cream-colored powder (2.5 g, 54.74%); melting point 126-128 °C.

References

[1] Patent: WO2004/111036, 2004, A1. Location in patent: Page 21
[2] Patent: WO2004/111046, 2004, A2. Location in patent: Page/Page column 18-19
[3] Patent: WO2014/100734, 2014, A1. Location in patent: Paragraph 00320
[4] Patent: WO2015/200677, 2015, A2. Location in patent: Paragraph 00459; 00460

6-Bromo-1-methyl-1H-benzo[d]imidazole synthesis

64-18-6
302800-13-1
53484-16-5
Synthesis of 6-Bromo-1-methyl-1H-benzo[d]imidazole from Formic acid and (5-Bromo-2-nitro-phenyl)-methyl-amine

6-Bromo-1-methyl-1H-benzo[d]imidazole Preparation Products And Raw materials

Raw materials

2-Fluoro-4-bromonitrobenzene (5-Bromo-2-nitro-phenyl)-methyl-amine Toluene 1,2-Benzenediamine, 4-bromo-N2-methyl- Trimethoxymethane
p-Toluenesulfonic acid monohydrate Formic acid

1of2

Preparation Products

5-Bromo-1-methyl-1H-benzo[d]imidazole

6-Bromo-1-methyl-1H-benzo[d]imidazole Suppliers

Global Suppliers ( 82)
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Wuhan Chemwish Technology Co., Ltd 86-027-67849912 sales@chemwish.com China 35884 56
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Chemsky（shanghai）International Co.,Ltd. 021-50135380 shchemsky@sina.com China 32273 50
Atop-Pharma (Shanghai) Technology Co., Ltd. +86 (21) 5196-9732 China 996 57
Chengdu HappySyn Pharmaceutical Technology Co., Ltd. 85114309 18982182443 yangli@happysyn.com China 2297 55
9ding chemical ( Shanghai) Limited 4009209199 sales@9dingchem.com China 18201 56
Shanghai Aladdin Bio-Chem Technology Co.,LTD 400-6206333 13167063860 anhua.mao@aladdin-e.com China 29977 65
SynAsst Chemical. 021-60343070 China 12731 55
Supplier Advantage
J & K SCIENTIFIC LTD. 76
Energy Chemical 61
Wuhan Chemwish Technology Co., Ltd 56
Shanghai Hanhong Scientific Co.,Ltd. 64
Chemsky（shanghai）International Co.,Ltd. 50
Atop-Pharma (Shanghai) Technology Co., Ltd. 57
Chengdu HappySyn Pharmaceutical Technology Co., Ltd. 55
9ding chemical ( Shanghai) Limited 56
Shanghai Aladdin Bio-Chem Technology Co.,LTD 65
SynAsst Chemical. 55

View Latest Price from 6-Bromo-1-methyl-1H-benzo[d]imidazole manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
6-BROMO-1-METHYL-1H-BENZO[D]IMIDAZOLE pictures 2019-12-20 6-BROMO-1-METHYL-1H-BENZO[D]IMIDAZOLE
53484-16-5
 $1.00 1KG 99% Career Henan Chemical Co

6-Bromo-1-methyl-1H-benzo[d]imidazole Spectrum

6-BROMO-1-METHYL-1H-BENZO[D]IMIDAZOLE(53484-16-5)1HNMR6-BROMO-1-METHYL-1H-BENZO[D]IMIDAZOLE(53484-16-5)FT-IR

53484-16-5 (6-Bromo-1-methyl-1H-benzo[d]imidazole) Related Search:

6-Bromo-1-methyl-1H-benzo[d]imidazole 6-Bromo-1,2-dimethyl-1H-benzoimidazol-4-ylamine AURORA KA-315 1H-BenziMidazole-1-carboxylicacid,6-broMo-,1,1-diMethylethylester 5-Bromo-1-methyl-1H-benzo[d]imidazole
4-broMo-1-Methyl-1H-benzo[d]iMidazole

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6-Bromo-1-methyl-1H-benzimidazole 6-bromo-1-methyl-1H-1,3-benzodiazole 1-Methyl-6-bromobenzimidazole 6-bromo-1-methylbenzimidazole 1H-Benzimidazole, 6-bromo-1-methyl- 6-bromo-1-(methyl-d3)-1H-1,3-benzodiazole 6-Bromo-1-methyl-1H-benzo[d]imidazole 53484-16-5 blocks Bromides Imidazoles