Zinc trifluoromethanesulfonate
- CAS No.
- 54010-75-2
- Chemical Name:
- Zinc trifluoromethanesulfonate
- Synonyms
- Zn(OTf)2;ZINC TRIFLATE;zinc(ii) triflate;trifluoromethanesulphonate;Zinc trifluoromethylsulfonate;Bis(trifluoromethanesulfonato)zinc;Trifluoromethane sulfonic acid zinc;zinc(2+) ditrifluoromethanesulfonate;Zinc trifL;Zinc Ditriflate
- CBNumber:
- CB8137568
- Molecular Formula:
- C2F6O6S2Zn
- Molecular Weight:
- 363.53
- MDL Number:
- MFCD00013229
- MOL File:
- 54010-75-2.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | ≥300 °C(lit.) |
|---|---|
| storage temp. | Inert atmosphere,Room Temperature |
| form | Powder |
| color | White to light-gray |
| Water Solubility | Soluble in water and acetonitrile. Slightly soluble in methanol. Insoluble in dichloromethane. |
| Sensitive | Hygroscopic |
| BRN | 4028195 |
| Stability | hygroscopic |
| InChI | InChI=1S/2CHF3O3S.Zn/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2 |
| InChIKey | CITILBVTAYEWKR-UHFFFAOYSA-L |
| SMILES | C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S([O-])(=O)=O.[Zn+2] |
| CAS DataBase Reference | 54010-75-2(CAS DataBase Reference) |
| EPA Substance Registry System | Methanesulfonic acid, trifluoro-, zinc salt (54010-75-2) |
| UNSPSC Code | 12161600 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H314-H318 | |||||||||
| Precautionary statements | P280-P305+P351+P338-P310-P260h-P301+P330+P331-P303+P361+P353-P501a-P260-P264-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P405-P501 | |||||||||
| PPE | Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 34 | |||||||||
| Safety Statements | 26-36/37/39-45 | |||||||||
| RIDADR | UN 3261 8/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 3-10 | |||||||||
| Hazard Note | Irritant/Hygroscopic | |||||||||
| TSCA | TSCA listed | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29049090 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Limited Quantities | 1 Kg (2.2 lbs) (solid) | |||||||||
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml) | |||||||||
| NFPA 704 |
|
Zinc trifluoromethanesulfonate price More Price(65)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 290068 | Zinc trifluoromethanesulfonate 98% | 54010-75-2 | 10g | $65.8 | 2026-04-30 | Buy |
| Sigma-Aldrich | 290068 | Zinc trifluoromethanesulfonate 98% | 54010-75-2 | 50g | $250 | 2026-04-30 | Buy |
| Sigma-Aldrich | 290068 | Zinc trifluoromethanesulfonate 98% | 54010-75-2 | 200G | $836 | 2026-04-30 | Buy |
| TCI Chemical | Z0057 | Zinc(II) Trifluoromethanesulfonate [for Electrolyte] | 54010-75-2 | 5G | $61 | 2026-04-30 | Buy |
| TCI Chemical | Z0057 | Zinc(II) Trifluoromethanesulfonate [for Electrolyte] | 54010-75-2 | 25G | $181 | 2026-04-30 | Buy |
Zinc trifluoromethanesulfonate Chemical Properties, Uses, Production
Reaction
- Catalyst for the addition of acetylenes to carbonyls and nitrones.
- Claisen rearrangement.
- Catalyst for the enantioselective Henry and Aza-Henry reactions.
- Pd-catalyzed hydroalkylation of styrenes with zinc reagents.
Chemical Properties
white to light-grey powder
Uses
Zinc trifluoromethanesulfonate acts as a catalyst for the preparation of dithioketals. It is used as a Lewis acid catalyst in silylation reactions. It is also used as a catalyst for greener amine synthesis by reductive amination with hydrogen gas.
reaction suitability
core: zinc
reagent type: catalyst
Synthesis
Triflic acid (0.056mol) was added dropwise to a suspension of zinc carbonate (0.02 mol)in dry methanol (20 ml) at room temperature. During the addition, CO2 was evolved. The mixture was stirred at 25°C for 20 minutes and refluxed for 2 h. The clear solution was cooled to 25°C and concentrated under reduced pressure. The resulting white powder was dried at 125°C for 2 h to afford Zinc trifluoromethanesulfonate (Zn(OTf)2 )(98% yield).
Purification Methods
It should be dried at 125o for 2hours at 3mm before use. It is soluble in CH2Cl2 but insoluble in pet ether. [Corey & Shimoji Tetrahedron Lett 24 169 1983.]
References
[1] Tetrahedron Letters, 2016, vol. 57, # 51, p. 5753 - 5756
Zinc trifluoromethanesulfonate Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Jiahua Herong Biotechnology Co., Ltd | 18916155073 | market@trustwe.com | China | 203 | 58 |
| JIANGXI TIME PHARMACEUTICAL CO.,LTD | 0794-7183888 13155888520 | sales@groupchem.com | China | 50 | 60 |
| Shanghai Mixiu Chemical Co., Ltd. | 18101936766 | eileen@shmychem.com | China | 349 | 55 |
| Shanghai Qiao Chemical Science Co., Ltd | 021-58892003 | info@qiaochem.com | China | 6065 | 65 |
| Shanghai qiyan medicine technology co., ltd | 15021941186 | 3572772243@qq.com | China | 163 | 58 |
| Jinan Qicheng Chemical Co. , Ltd. | 0531-15628998092 15628998092 | 418597063@QQ.com | China | 245 | 58 |
| smart special gas Shanghai co.,Ltd | 18557025385 15757158480 | 1044710094@qq.com | China | 663 | 58 |
| Creasyn Finechem(Tianjin) Co., Ltd. | 022-83946278 13820372920 | sales@creasyn.com | China | 968 | 68 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
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View Latest Price from Zinc trifluoromethanesulfonate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
![]() |
2026-08-25 | Zinc trifluoromethanesulfonate
54010-75-2
|
$2.00-5.00 | 99% | ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | |||
![]() |
2026-03-20 | ZINC TRIFLUOROMETHANESULFONATE
54010-75-2
|
$10.00 | 1KG | 99% | 10 mt | Hebei Chuanghai Biotechnology Co., Ltd | |
![]() |
2023-03-10 | ZINC TRIFLUOROMETHANESULFONATE
54010-75-2
|
1KG | 99.0% | 1000KG | LY Global chemicals co.,ltd . |
-

- Zinc trifluoromethanesulfonate
54010-75-2
- $2.00-5.00
- 99%
- ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
-

- ZINC TRIFLUOROMETHANESULFONATE
54010-75-2
- $10.00
- 99%
- Hebei Chuanghai Biotechnology Co., Ltd
-

- ZINC TRIFLUOROMETHANESULFONATE
54010-75-2
- $0.00
- 99.0%
- LY Global chemicals co.,ltd .
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