Silver(I) trifluoromethanethiolate
- CAS No.
- 811-68-7
- Chemical Name:
- Silver(I) trifluoromethanethiolate
- Synonyms
- AgSCF3;silver,trifluoromethanethiol;Silver trifluoromethanethiolate;ver(I) TrifL;uoromethanethioL;trifluoromethanethiolsilver;(Trifluoromethylthio) silver(I);Silver(I)trifluoromethanethiolate;[(Trifluoromethyl)thio] silver(I);Trifluoromethanethiol Silver(I) Salt
- CBNumber:
- CB32256985
- Molecular Formula:
- CHAgF3S
- Molecular Weight:
- 209.94
- MDL Number:
- MFCD25563234
- MOL File:
- 811-68-7.mol
- MSDS File:
- SDS
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
|---|---|
| Water Solubility | Insoluble in water |
| solubility | Methanol |
| form | powder to crystal |
| color | White to Light yellow to Light red |
| InChI | InChI=1S/CHF3S.Ag/c2-1(3,4)5;/h5H; |
| InChIKey | SVPQZGWGYCARGG-UHFFFAOYSA-N |
| SMILES | C(S)(F)(F)F.[Ag] |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P280-P304+P340-P305+P351+P338 | |||||||||
| HS Code | 2843290090 | |||||||||
| NFPA 704 |
|
Silver(I) trifluoromethanethiolate price More Price(25)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | S0977 | Silver(I) Trifluoromethanethiolate >95.0%(T) | 811-68-7 | 1g | $148 | 2026-04-30 | Buy |
| TCI Chemical | S0977 | Silver(I) Trifluoromethanethiolate >95.0%(T) | 811-68-7 | 5g | $533 | 2026-04-30 | Buy |
| Biosynth | FT79900 | (Trifluoromethylthio) Silver(I) | 811-68-7 | 2g | $900 | 2026-06-04 | Buy |
| Biosynth | FT79900 | (Trifluoromethylthio) Silver(I) | 811-68-7 | 1g | $900 | 2026-06-04 | Buy |
| Biosynth | FT79900 | (Trifluoromethylthio) Silver(I) | 811-68-7 | 0.5g | $900 | 2026-06-04 | Buy |
Silver(I) trifluoromethanethiolate Chemical Properties, Uses, Production
Uses
Silver(I) trifluoromethanethiolate is an important organic synthesis intermediate and pharmaceutical intermediate for the preparation of trifluoromethyl aryl sulfides and indanone derivatives[1-2].
Synthesis
14104-20-2
2926-29-6
811-68-7
Silver tetrafluoroborate (AgBF4, 19.77 g, 100 mmol) and sodium trifluoromethanesulfinate (CF3SO2Na, 18.73 g, 120 mmol) were dissolved in anhydrous acetonitrile (400 mL) under nitrogen protection. After cooling the reaction mixture to 0°C, triphenylphosphine (Ph3P, 62.95 g, 240 mmol) was slowly added. Subsequently, the reaction mixture was brought back to room temperature and heated to 50°C and maintained at this temperature for 12 hours. Upon completion of the reaction, the mixture was filtered through diatomaceous earth and the filtrate was cooled to -20°C to promote crystallization. After the crystals were sufficiently precipitated, the supernatant was decanted to remove most of the triphenylphosphine oxide. The supernatant was concentrated under reduced pressure to remove the solvent and the residue was washed well with ether and dried under vacuum. Finally, the resulting solid was recrystallized with tetrahydrofuran and benzene to afford silver trifluoromethane thiol (I) (18.60 g, 89% yield).
References
[1] DAVE J. ADAMS, James H C. ChemInform Abstract: Preparation of Trifluoromethyl Aryl Sulfides Using Silver(I) Trifluoromethanethiolate and an Inorganic Iodide.[J]. ChemInform, 2010, 31 23. DOI:10.1002/chin.200023091.
[2] YI-KANG SONG. Synthesis of 2-(trifluoromethylthio)-indenones by silver-mediated cascade trifluoromethylthiolation/cyclization of arylpropynones[J]. Tetrahedron, 2016, 72 47: Pages 7589-7593. DOI:10.1016/j.tet.2016.10.013.
Silver(I) trifluoromethanethiolate Preparation Products And Raw materials
Raw materials
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Preparation Products
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Silver(I) trifluoromethanethiolate Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Chenghe Medical Technology Co. Ltd. | 021-021-54382182 18601603956 | 18601603956@163.com | China | 1323 | 58 |
| Shandong Territorial sea Biological Technology Co., LTD | 15092083467 | tangfenjiushililiang@leadhigh.com.cn | China | 2986 | 58 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Accela ChemBio Co.,Ltd. | 021-50795510 4000665055 | marketing@accelachem.com | China | 10972 | 64 |
| Shandong Xiya Chemical Co., Ltd | 13355009207 13355009207 | 3007715519@qq.com | China | 18722 | 57 |
| TOKYO CHEMICAL INDUSTRY CO., LTD. | 03-36680489 | Sales-JP@TCIchemicals.com | Japan | 28364 | 80 |
| ShangHai D&B Biological Science and Technology Co.Ltd | 400-008-9730,021-54359730 400-008-9730 | info@chemxyz.com | China | 3642 | 60 |
| SHANG FLUORO | 021-65170832 15601903708 | qinba_1@163.com | China | 401 | 60 |
| Hangzhou J&H Chemical Co., Ltd. | 0571-87396432 | sales@jhechem.com | China | 14905 | 59 |
View Latest Price from Silver(I) trifluoromethanethiolate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2025-04-04 | (Trifluoromethylthio) silver(I)
811-68-7
|
1kg | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd.
|
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 |
2020-11-16 | Silver(I) Trifluoromethanethiolate
811-68-7
|
$35.00 | 25Kg/Bag | 99% | 20 Tons | Longyan Tianhua Biological Technology Co., Ltd |
-
- (Trifluoromethylthio) silver(I)
811-68-7
- 98%
- Henan Aochuang Chemical Co.,Ltd.
-
- Silver(I) Trifluoromethanethiolate
811-68-7
- $35.00
- 99%
- Longyan Tianhua Biological Technology Co., Ltd
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