ChemicalBook >> CAS DataBase List >>(1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)
(1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)
- CAS No.
- 259259-80-8
- Chemical Name:
- (1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)
- Synonyms
- (S)-AMAC;(S,S)-AMAC;CID 135483535;(1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II);(1S,2S)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II), CAS 259259-80-8;(1S,2S)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II);Cobalt,[[3,3'-[[(1S,2S)-1,2-bis(2,4,6-triMethylphenyl)-1,2-ethanediyl]bis[(nitrilo-kN)Methylidyne]]bis[2,4-pentanedionato-kO2]](2-)]-, (SP-4-2)-
- CBNumber:
- CB8189532
- Molecular Formula:
- C32H38CoN2O4
- Molecular Weight:
- 573.59
- MDL Number:
- MFCD06797062
- MOL File:
- 259259-80-8.mol
- MSDS File:
- SDS
- TDS File:
- TDS
Last updated:2026-09-12 18:55:25
(1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II) Properties
| Melting point | 242-246°C |
|---|---|
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| form | powder to crystal |
| color | Orange to Brown |
| optical activity | [α]/D 309°, c = 0.1 in chloroform |
| InChIKey | PHCQQLMRNZRDJA-OZXAGROVSA-L |
| SMILES | CC(=O)C1=C(C)O[Co]OC(C)=C(\C=N\[C@H]([C@@H](\N=C\1)c2c(C)cc(C)cc2C)c3c(C)cc(C)cc3C)C(C)=O |
| UNSPSC Code | 12352000 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS08 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302+H312+H332-H315-H319-H351 |
| Precautionary statements | P201-P202-P261-P264-P270-P271-P280-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P312-P305+P351+P338+P337+P313-P308+P313-P405-P501 |
| PPE | Eyeshields, Gloves, type N95 (US) |
| WGK Germany | 3 |
| HS Code | 2942.00.3500 |
| Storage Class | 11 - Combustible Solids |
(1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II) price More Price(21)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 708844 | (1S,2S)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II) | 259259-80-8 | 100mg | $93.6 | 2026-04-30 | Buy |
| Sigma-Aldrich | 708844 | (1S,2S)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II) | 259259-80-8 | 500mg | $389 | 2023-06-20 | Buy |
| TCI Chemical | B2315 | (1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II) | 259259-80-8 | 100mg | $303 | 2026-04-30 | Buy |
| Usbiological | 266979 | (1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II) Asreported | 259259-80-8 | 10mg | $307 | 2026-06-03 | Buy |
| Usbiological | 266979 | (1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II) Asreported | 259259-80-8 | 25mg | $438 | 2026-06-03 | Buy |
(1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II) Chemical Properties, Uses, Production
Uses
Catalyst for:
- Stereoselective preparation of benzylic alcohols via oxidative kinetic resolution of secondary benzylic alcohols with oxygen in presence of alkene
- Enantioselective borohydride reduction
- Preparation of -nitro alcohols from aldehydes and nitroalkanes by stereoselective Henry reaction in presence of amine bases
- Preparation of optically pure diarylpropanediols via reduction of the corresponding diketones
(1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II) Preparation Products And Raw materials
Raw materials
Preparation Products
(1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II) Suppliers
Global Suppliers ( 38)
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Shanghai Longsheng chemical Co.,Ltd. | 58099637 13585536065 | sales@shlschem.com | China | 9880 | 59 |
| Maya High Purity Chemicals | +86 (573) 82222445 (0)18006601000 452520369 | sales@maya-r.com | China | 11693 | 57 |
| TOKYO CHEMICAL INDUSTRY CO., LTD. | 03-36680489 | Sales-JP@TCIchemicals.com | Japan | 28364 | 80 |
| TCI Europe | 320-37350700 | sales@tcieurope.eu | Europe | 23654 | 75 |
| TCI AMERICA | 800-4238616 | sales@tciamerica.com | Americas | 23636 | 75 |
| 9ding chemical ( Shanghai) Limited | 4009209199 | sales@9dingchem.com | China | 22497 | 55 |
259259-80-8 ((1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)) Related Search:
(S)-AMAC
Cobalt,[[3,3'-[[(1S,2S)-1,2-bis(2,4,6-triMethylphenyl)-1,2-ethanediyl]bis[(nitrilo-kN)Methylidyne]]bis[2,4-pentanedionato-kO2]](2-)]-, (SP-4-2)-
(S,S)-AMAC
(1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)
CID 135483535
(1S,2S)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)
(1S,2S)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II), CAS 259259-80-8
259259-80-8
C32H38CoN2O4
Co (Cobalt) Compounds
Homogeneous Catalysts
Transition Metal Compounds
Catalysts for Organic Synthesis
Classes of Metal Compounds
Asymmetric Synthesis
Metal Complexes
Asymmetric Synthesis
Catalysts for Organic Synthesis
Classes of Metal Compounds
Co (Cobalt) Compounds
Homogeneous Catalysts
Metal Complexes
Synthetic Organic Chemistry
Transition Metal Compounds
