3-(Bromomethyl)phenyl acetate
- CAS No.
- 49617-80-3
- Chemical Name:
- 3-(Bromomethyl)phenyl acetate
- Synonyms
- 3-(Bromomethyl)phenyl acetate;m-(bromomethyl)phenyl acetate;Phenol, 3-(bromomethyl)-, 1-acetate
- CBNumber:
- CB8811240
- Molecular Formula:
- C9H9BrO2
- Molecular Weight:
- 229.07
- MDL Number:
- MFCD08543447
- MOL File:
- Mol file
- MSDS File:
- SDS
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302-H315-H319-H332-H335 |
| Precautionary statements | P280-P305+P351+P338-P310 |
| Hazard Codes | C |
| Hazard Note | Corrosive/Lachrymatory |
| HS Code | 2915390090 |
3-(Bromomethyl)phenyl acetate price More Price(29)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Apolloscientific | OR8905 | 3-(Bromomethyl)phenyl acetate ≥95% | 49617-80-3 | 1g | $177 | 2026-06-04 | Buy |
| Apolloscientific | OR8905 | 3-(Bromomethyl)phenyl acetate ≥95% | 49617-80-3 | 5g | $655 | 2026-06-04 | Buy |
| Apolloscientific | OR8905 | 3-(Bromomethyl)phenyl acetate ≥95% | 49617-80-3 | 25g | $2291 | 2026-06-04 | Buy |
| Activate Scientific | AS45688 | 3-(Bromomethyl)phenyl acetate 95% | 49617-80-3 | 1g | $232 | 2026-06-04 | Buy |
| Activate Scientific | AS45688 | 3-(Bromomethyl)phenyl acetate 95% | 49617-80-3 | 5g | $857 | 2026-06-04 | Buy |
3-(Bromomethyl)phenyl acetate Chemical Properties,Uses,Production
Synthesis
620-24-6
49617-80-3
General procedure for the synthesis of phenyl 3-(bromomethyl)acetate from 3-hydroxybenzyl alcohol: 3-hydroxybenzyl alcohol (37.2 g, 0.3 mol) was dissolved in 100 ml of pyridine, and acetic anhydride (81.7 g, 0.8 mol) was added slowly with stirring while the reaction temperature was raised to 70 °C. The reaction mixture was stirred at 70 °C for half an hour and then poured into a mixture of ice and hydrochloric acid. The organic phase was separated and the aqueous phase was extracted twice with dichloromethane. The organic phase and the dichloromethane extract were combined and washed sequentially with sodium bicarbonate solution, water, dilute acid and water. The organic phase was dried with anhydrous magnesium sulfate, filtered and the solvent was evaporated under reduced pressure to give 55.7 g of crude product (87% yield). The crude product was dissolved in 150 g of 30-32% hydrogen bromide in acetic acid solution and reacted for 10 min followed by addition of 25 ml of acetic anhydride. The mixture was allowed to stand overnight at room temperature. After completion of the reaction, it was evaporated under reduced pressure to an oil. The oily substance was dissolved in dichloromethane and washed sequentially with water, aqueous sodium bicarbonate solution and water. The organic phase was dried with anhydrous magnesium sulfate, filtered and the solvent evaporated under reduced pressure. The obtained oily substance was placed in a refrigerator for one week to allow slow crystallization.
References
[1] Tetrahedron, 2000, vol. 56, # 29, p. 5169 - 5175
[2] Patent: US4476207, 1984, A
3-(Bromomethyl)phenyl acetate Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
3-(Bromomethyl)phenyl acetate Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Brain Biotechnology Co., Ltd. | 13564638271 | shhjiang1977@163.com | China | 2985 | 55 |
| BePharm Ltd | 400-685-9117 | market@bepharm.com | China | 15081 | 60 |
| Aikon International Limited | 025-66113011 19370895928 | qzhang@aikonchem.com | China | 15390 | 58 |
| Fuxin Pharmaceutical | +86-021-021-50872116 | contact@fuxinpharm.com | China | 9976 | 58 |
| SHENZHEN PHYSTANDARD BIO-TECH CO.,LTD | 0755-83725350 13380397412 | 3001280422@qq.com | China | 10000 | 58 |
| Energy Chemical | 021-58432009 400-005-6266 | marketing@energy-chemical.com | China | 44871 | 58 |
| Jiangsu Nanchuang Chemical and Life Health Research Institute Co., Ltd. | 15720605021 | zhang_lei@jsnchem.com | China | 1881 | 58 |
| Bide Pharmatech Ltd. | 400-1647117 13681763483 | product02@bidepharm.com | China | 59929 | 58 |
| Bide Pharmatech Ltd. | 400-6005915 | sales@picasso-e.com | China | 39645 | 58 |
| Jiangsu Yaoheng Pharmaceutical Technology Co., Ltd. | 13524761129 | 2183470029@qq.com | China | 864 | 58 |
View Lastest Price from 3-(Bromomethyl)phenyl acetate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-08-25 | 3-(Bromomethyl)phenyl acetate
49617-80-3
|
$2.00-6.00 | 1kg | 99% | 100kg | ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD |
-
- 3-(Bromomethyl)phenyl acetate
49617-80-3
- $2.00-6.00
- 99%
- ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
