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4-(4-Bromobenzyl)morpholine

4-(4-Bromobenzyl)morpholine Structure
4-(4-Bromobenzyl)morpholine structure
CAS No.
132833-51-3
Chemical Name:
4-(4-Bromobenzyl)morpholine
Synonyms
Morpholine,4-[(4-broMophenyl)Methyl]-;4-(morpholin-4-ylmethyl)-1-bromobenzene
CBNumber:
CB8957102
Molecular Formula:
C11H14BrNO
Molecular Weight:
256.14
MDL Number:
MFCD00979535
MOL File:
132833-51-3.mol
MSDS File:
SDS
Last updated:2026-05-28 04:14:29
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4-(4-Bromobenzyl)morpholine Properties

storage temp. Keep in dark place,Inert atmosphere,Room temperature
form solid
color White
InChI InChI=1S/C11H14BrNO/c12-11-3-1-10(2-4-11)9-13-5-7-14-8-6-13/h1-4H,5-9H2
InChIKey KWJZFQQTDGVBOX-UHFFFAOYSA-N
SMILES N1(CC2=CC=C(Br)C=C2)CCOCC1
UNSPSC Code 12352200
NACRES NA.21

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302
Precautionary statements  P280-P305+P351+P338
Hazard Codes  Xi,Xn
Risk Statements  22
WGK Germany  3
Hazard Note  Irritant
HS Code  2934999090
Storage Class 11 - Combustible Solids
Hazard Classifications Acute Tox. 4 Oral

4-(4-Bromobenzyl)morpholine price More Price(46)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich BML00227 4-(4-Bromobenzyl)morpholine Aldrich 132833-51-3 1g $45.5 2026-04-30 Buy
Activate Scientific AS70169 4-(4-Bromobenzyl)morpholine 98% 132833-51-3 1g $26 2026-06-04 Buy
Activate Scientific AS70169 4-(4-Bromobenzyl)morpholine 98% 132833-51-3 5g $59 2026-06-04 Buy
Activate Scientific AS70169 4-(4-Bromobenzyl)morpholine 98% 132833-51-3 25g $178 2026-06-04 Buy
Matrix Scientific 064685 4-(4-Bromobenzyl)morpholine 132833-51-3 500.00mg $119 2026-05-18 Buy
Product number Packaging Price Buy
BML00227 1g $45.5 Buy
AS70169 1g $26 Buy
AS70169 5g $59 Buy
AS70169 25g $178 Buy
064685 500.00mg $119 Buy

4-(4-Bromobenzyl)morpholine Chemical Properties, Uses, Production

Synthesis

Morpholine

110-91-8

4-Bromobenzyl bromide

589-15-1

4-(4-Bromobenzyl)morpholine

132833-51-3

Morpholine (13, 1.4 mL, 1.39 g, 16 mmol) and 4-bromobenzyl bromide (12, 1.0 g, 4 mmol) were reacted in acetonitrile (50 mL). The reaction mixture was heated to reflux for 4 hours. After completion of the reaction, water was added and extracted with dichloromethane (3 x 50 mL). The organic layers were combined, dried with anhydrous sodium sulfate, filtered and concentrated under reduced pressure. The residue was purified by fast column chromatography (silica gel column, 6 cm diameter, 50 mL volume, eluent n-hexane/ethyl acetate=8/2, Rf=0.19) to afford the target product 14 as a colorless solid (1.0 g, 3.9 mmol, 98% yield). The melting point of the product was 85 °C. Structural confirmation and purity analysis of the product were carried out by various analytical methods including 1H NMR, 13C NMR, IR, MS (ESI), HRMS and HPLC, which showed that the product was pure and structurally correct.

References

[1] Carbohydrate Research, 2012, vol. 359, p. 59 - 64,6
[2] Carbohydrate Research, 2012, vol. 359, p. 59 - 64
[3] Patent: WO2013/153357, 2013, A1. Location in patent: Page/Page column 18; 39
[4] Patent: US2015/45354, 2015, A1. Location in patent: Paragraph 0233-0236
[5] Patent: WO2008/154642, 2008, A2. Location in patent: Page/Page column 188-189

4-(4-Bromobenzyl)morpholine Preparation Products And Raw materials

Raw materials

Morpholine 4-Bromobenzyl bromide 1-BroMo-4-(fluoroMethyl)-benzene

Preparation Products

4-(4-Bromobenzyl)morpholine Suppliers

Global Suppliers ( 95)
Supplier Tel Email Country ProdList Advantage
Zhengzhou kangnuochenrui Chemical Technology Co.,Ltd 18210788515; 18210788515 zhuzixin999@163.c0m China 4999 55
gekdbiotech 19150199476 2035843955@qq.com China 58 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Adamas Reagent, Ltd. 400-6009262 15618770481 yhx@titansci.com China 14098 59
Accela ChemBio Co.,Ltd. 021-50795510 4000665055 marketing@accelachem.com China 10972 64
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Shanghai Sphchem Co., Ltd. 021-56491756 13512199871 2819742715@qq.com China 3994 55
Tianjin Derchemist Science & Technology Co., Ltd. 22-58627059 13920586291 zdcomcon@126.com China 4094 50
Chiba Pharmaceutical Science and technology Co, Ltd. 0531-81313138 13066006660 chibapharm@foxmail.com China 3996 55
Shanghai Topbiochem Technology Co., Ltd 021-58170097 info@topbiochem.com China 9510 58
Supplier Advantage
Zhengzhou kangnuochenrui Chemical Technology Co.,Ltd 55
gekdbiotech 58
J & K SCIENTIFIC LTD. 76
Adamas Reagent, Ltd. 59
Accela ChemBio Co.,Ltd. 64
Shanghai Hanhong Scientific Co.,Ltd. 64
Shanghai Sphchem Co., Ltd. 55
Tianjin Derchemist Science & Technology Co., Ltd. 50
Chiba Pharmaceutical Science and technology Co, Ltd. 55
Shanghai Topbiochem Technology Co., Ltd 58

View Latest Price from 4-(4-Bromobenzyl)morpholine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-(4-Bromobenzyl)morpholine pictures 2019-07-06 4-(4-Bromobenzyl)morpholine
132833-51-3
 $1.00 1kg 98% 200KG Career Henan Chemical Co
4-(4-Bromobenzyl)morpholine pictures 2019-07-06 4-(4-Bromobenzyl)morpholine
132833-51-3
 $1.00 1kg 98% 200KG Career Henan Chemical Co
4-(4-Bromobenzyl)morpholine pictures 2019-07-06 4-(4-Bromobenzyl)morpholine
132833-51-3
 $1.00 1kg 98% 200KG Career Henan Chemical Co

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Morpholine,4-[(4-broMophenyl)Methyl]- 4-(morpholin-4-ylmethyl)-1-bromobenzene 132833-51-3 alkyl bromide Amino Aryl Organohalides