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(R)-(-)-Citramalic acid

CAS No.
6236-10-8
Chemical Name:
(R)-(-)-Citramalic acid
Synonyms
(-)-CITRAMALIC ACID;D-(-)-CITRAMALIC ACID;2-METHYLMALIC ACID;D-(-)-CitramalicAci;D-2-METHYLMALIC ACID;(-)-2-METHYLMALIC ACID;(R)-2-Methylmalic acid;D(-)-2-METHYLMALIC ACID;(R)-(-)-Citramalic acid;(-)-2-Methyl-D-malic acid
CBNumber:
CB9162004
Molecular Formula:
C5H8O5
Molecular Weight:
148.11
MDL Number:
MFCD00066438
MOL File:
6236-10-8.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-09-12 18:56:09

(R)-(-)-Citramalic acid Properties

Melting point 108-110 °C(lit.)
Boiling point 188.68°C (rough estimate)
Density 1.2336 (rough estimate)
refractive index 1.3920 (estimate)
storage temp. 2-8°C
solubility PBS (pH 7.2): 10 mg/ml
pka 3.65±0.28(Predicted)
form powder or crystals
optical activity [α]/D -19.0±1.0°, c = 0.5 in 1 M HCl
Merck 2323
BRN 1723818
InChI 1S/C5H8O5/c1-5(10,4(8)9)2-3(6)7/h10H,2H2,1H3,(H,6,7)(H,8,9)/t5-/m1/s1
InChIKey XFTRTWQBIOMVPK-RXMQYKEDSA-N
SMILES C[C@@](O)(CC(O)=O)C(O)=O || C[C@@](O)(CC(O)=O)C(O)=O
CAS DataBase Reference 6236-10-8(CAS DataBase Reference)
FDA UNII 788CNO6T4D
UNSPSC Code 12352204
NACRES NA.32

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
3-10
Storage Class 11 - Combustible Solids

(R)-(-)-Citramalic acid price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 06711 D-(?)-Citramalic acid lithium salt ≥95.0% (GC) 6236-10-8 10mg $117 2026-04-30 Buy
Sigma-Aldrich 06711 D-(?)-Citramalic acid lithium salt ≥95.0% (GC) 6236-10-8 50mg $333 2026-04-30 Buy
Cayman Chemical 19260 D-(-)-Citramalic Acid (lithium salt) ≥95% 5mg $49 2026-04-30 Buy
Cayman Chemical 19260 D-(-)-Citramalic Acid (lithium salt) ≥95% 10mg $81 2026-04-30 Buy
Cayman Chemical 19260 D-(-)-Citramalic Acid (lithium salt) ≥95% 25mg $190 2026-04-30 Buy
Product number Packaging Price Buy
06711 10mg $117 Buy
06711 50mg $333 Buy
19260 5mg $49 Buy
19260 10mg $81 Buy
19260 25mg $190 Buy

(R)-(-)-Citramalic acid Chemical Properties, Uses, Production

Chemical Properties

white fine crystalline powder

Definition

ChEBI: D-citramalic acid is the D-enantiomer of citramalic acid. It is a conjugate acid of a D-citramalate(2-).

Biological Activity

Citramalate is a biochemical intermediate known to be involved in several aspects of bacterial metabolism, including, among others, the anaerobic metabolism of glutamate via the methylaspartate pathway of Clostridium tetanomorphum.

References

[1] D M HOWELL  R H W  H Xu. (R)-citramalate synthase in methanogenic archaea.[J]. Journal of Bacteriology, 1999, 181 1: 331-333. DOI: 10.1128/jb.181.1.331-333.1999
[2] W BUCKEL  H A B. Two pathways of glutamate fermentation by anaerobic bacteria.[J]. Journal of Bacteriology, 1974, 117 3: 1248-1260. DOI: 10.1128/jb.117.3.1248-1260.1974
[3] SILKE FRIEDMANN  Georg F  Birgit E Alber. Properties of succinyl-coenzyme A:D-citramalate coenzyme A transferase and its role in the autotrophic 3-hydroxypropionate cycle of Chloroflexus aurantiacus.[J]. Journal of Bacteriology, 2006, 188 18: 6460-6468. DOI: 10.1128/jb.00659-06

(R)-(-)-Citramalic acid Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-(-)-Citramalic acid Suppliers

Global Suppliers ( 61)
Supplier Tel Email Country ProdList Advantage
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Beijing HuaMeiHuLiBiological Chemical 010-56205725 waley188@sohu.com China 12323 58
Shanghai Macklin Biochemical Co.,Ltd. 15221275939 15221275939 shenlinxing@macklin.cn China 15775 55
Changsha Jing Kang New Material Technology Co., Ltd. 0731-85118349 18874718518 877634463@qq.com China 1998 50
Shanghai YuanYe Biotechnology Co., Ltd. 15026964105 2881489226@qq.com China 89667 60
Guangzhou Jhd Chemical Reagent Co., Ltd. 020-84383047 sales@jhd.com.cn China 9177 65
Shanghai Hongye Biotechnology Co. Ltd 400-9205774 400-920-5774 sales@glpbio.cn China 6705 58
Alfa Chemistry +1-5166625404; Info@alfa-chemistry.com United States 20000 58

View Latest Price from (R)-(-)-Citramalic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
D-(-)-Citramalic Acid lithium salt pictures 2026-04-20 D-(-)-Citramalic Acid lithium salt
$159.00-265.00 10g TargetMol Chemicals Inc.
(R)-(-)-CITRAMALIC ACID pictures 2025-06-27 (R)-(-)-CITRAMALIC ACID
6236-10-8
1KG 99% 500000kg Hebei Chuanghai Biotechnology Co., Ltd
(R)-(-)-CITRAMALIC ACID pictures 2025-06-20 (R)-(-)-CITRAMALIC ACID
6236-10-8
$10.00-40.00 1kg 0.99 20 tons Hebei Yanxi Chemical Co., Ltd.
(-)-2-METHYLMALIC ACID 2-METHYLMALIC ACID (-)-2-HYDROXY-2-METHYLBUTANEDIOIC ACID 2-HYDROXY-2-METHYLBUTANEDIOIC ACID (R)-(-)-2-HYDROXY-2-METHYLBUTANEDIOIC ACID (R)-2-HYDROXY-2-METHYLSUCCINIC ACID (R)-(-)-Citramalic acid, 98+% Butanedioic acid, 2-hydroxy-2-methyl-, (2R)- α-hydroxy-α-methyl-succinic acid (R)-2-Hydroxy-2-methylbutanedioic acid, (R)-2-Hydroxy-2-methylsuccinic acid, 2-Methylmalic acid, D-(-)-2-Methylmalic acid (R)-2-Hydroxy-2-methylsuccinic acid, D-(-)-2-Methylmalic acid (-)-2-Methyl-D-malic acid (2R)-2-Hydroxy-2-methylsuccinic acid (2R)-2-Methyl-2-hydroxybutanedioic acid (R)-2-Methylmalic acid D-(?)-Citramalic acid lithium salt D(-)-2-METHYLMALIC ACID D-2-METHYLMALIC ACID (2R)-2-hydroxy-2-methylbutanedioic acid D-(-)-CitramalicAci (R)-(-)-Citramalic Acid DISCONTINUED PLEASE SEE C525525 D-(?)-Citramalic acid lithium salt (R)-(-)-Citramalic Acid lithium salt (-)-CITRAMALIC ACID D-(-)-CITRAMALIC ACID (R)-(-)-Citramalic acid 6236-10-8 6236-10-08 6236-19-8 HOOCCCH3OHCH2COOH HOOCCH3COHCH2COOH CH3COHCOOHCH2COOH C5H8O5 Organic Building Blocks Carboxylic Acids Asymmetric Synthesis Carboxylic Acids (Chiral) Chiral Building Blocks Carboxylic Acids (Chiral) Chiral Building Blocks Synthetic Organic Chemistry