rac-2β*-(2-メチルベンジルオキシ)-4α*-イソプロピル-1α*-メチル-7-オキサビシクロ[2.2.1]ヘプタン
rac-2β*-(2-メチルベンジルオキシ)-4α*-イソプロピル-1α*-メチル-7-オキサビシクロ[2.2.1]ヘプタン 物理性質
- 融点 :
- 25°C
- 沸点 :
- 313°C
- 比重(密度) :
- d20 1015 kg/m3
- 屈折率 :
- 1.4800 (estimate)
- 闪点 :
- 147 °C
- 貯蔵温度 :
- 0-6°C
- Henry's Law Constant:
- 1.3×101 mol/(m3Pa) at 25℃, Ebert et al. (2023)
- 主な用途:
- 農業
環境
- InChI:
- 1S/C18H26O2/c1-13(2)18-10-9-17(4,20-18)16(11-18)19-12-15-8-6-5-7-14(15)3/h5-8,13,16H,9-12H2,1-4H3/t16-,17+,18-/m1/s1
- InChIKey:
- QMTNOLKHSWIQBE-FGTMMUONSA-N
- SMILES:
- CC(C)[C@]12CC[C@](C)(O1)[C@@H](C2)OCc3ccccc3C
- CAS データベース:
- 87818-31-3(CAS DataBase Reference)
- EPAの化学物質情報:
- Cinmethylin (87818-31-3)
rac-2β*-(2-メチルベンジルオキシ)-4α*-イソプロピル-1α*-メチル-7-オキサビシクロ[2.2.1]ヘプタン 価格
もっと(7)
| メーカー |
製品番号 |
製品説明 |
CAS番号 |
包装 |
価格 |
更新時間 |
購入 |
|
富士フイルム和光純薬株式会社(wako)
|
W01TRCC475400 |
シンメチリン
Cinmethylin |
87818-31-3 |
500mg |
￥582900 |
2024-03-01 |
購入 |
|
富士フイルム和光純薬株式会社(wako)
|
W01TRCC475400 |
シンメチリン
Cinmethylin |
87818-31-3 |
50mg |
￥56900 |
2023-06-01 |
購入 |
|
関東化学株式会社(KANTO)
|
49833-79 |
シンメチリン標準品
Cinmethylin standard |
87818-31-3 |
50mg |
￥69000 |
2024-07-01 |
購入 |
|
関東化学株式会社(KANTO)
|
49832-04 |
シンメチリン標準液
Cinmethylin standard solution |
87818-31-3 |
10mL |
￥30000 |
2024-07-01 |
購入 |
|
Sigma-Aldrich Japan
|
34237 |
シンメチリン PESTANAL?, analytical standard
Cinmethylin PESTANAL?, analytical standard |
87818-31-3 |
50mg |
￥22400 |
2024-03-01 |
購入 |
rac-2β*-(2-メチルベンジルオキシ)-4α*-イソプロピル-1α*-メチル-7-オキサビシクロ[2.2.1]ヘプタン 化学特性,用途語,生産方法
外観
ごくうすい黄色〜黄色, 液体
溶解性
アセトンに溶け、水にほとんど溶けない。
農薬用途
除草剤
説明
Cinmethylinwas developed by Shell Chemical
Company in the early 1980s as a weed control agent for
monocotyledonous species. This herbicide controls important
grasses such as green foxtail (Setaria viridis) and
barnyardgrass (Echinochloa crus-galli) and suppresses
the growth of several broadleaf weeds such as prickly
sida (Sida spinosa) and velvetleaf (Abutilon theophrasti).
使用
Cinmethylin is used as pre-emergence grass herbicide. Cinmethylin is member of the cineole eucalyptol family.
薬理学
Cinmethylin is active on several important grasses in
rice (Echinochloa spp., Cyperus spp., and Monochoria
vaginalis) at rates from 25 to 100 g ai/ha (5). Its chemical
and toxicological features (low persistence in environment
and low mammalian toxicity) generated a significant level
of interest in its use as a rice herbicide.
代謝経路
When rats are administered 14C-cinmethylin orally, the
major route of its elimination is via urinary excretion. A
complex degradation pattern of cinmethylin is
observed and the metabolic pathways involve
hydroxylation, oxidation at the benzyl and cineol
portions, conjugation with glucuronic acid and glycine,
and cleavage of the ether linkage. When rats are
administered 14C-cinmethylin by stomach incubation,
two minor metabolites are identified as o-
(acetoxymethyl)benzoic acid and 9-(acetoxymethyl)-a-
carboxycinmethylin.
rac-2β*-(2-メチルベンジルオキシ)-4α*-イソプロピル-1α*-メチル-7-オキサビシクロ[2.2.1]ヘプタン 上流と下流の製品情報
原材料
準備製品
rac-2β*-(2-メチルベンジルオキシ)-4α*-イソプロピル-1α*-メチル-7-オキサビシクロ[2.2.1]ヘプタン 生産企業
Global( 99)Suppliers
87818-31-3(rac-2β*-(2-メチルベンジルオキシ)-4α*-イソプロピル-1α*-メチル-7-オキサビシクロ[2.2.1]ヘプタン)キーワード:
- 87818-31-3
- 1-Methyl-4-(1-methylethyl)-2-((2-methylphenyl)methoxy)-7-oxabicyclo[2.2.1]heptane
- (+-)-exo-1-methyl-4-(1-methylethyl)-2-((2-methylphenyl)methoxy)-7-oxabicyclo
- (2.2.1)heptane
- 1-methyl-4-(1-methylethyl)-2-[(2-methylphenyl)methoxy]-exo-(±)-7-Oxabicyclo[2.2.1]heptane
- 7-oxabicyclo(2.2.1)heptane,1-methyl-4-(1-methylethyl)-2-((2-methylphenyl)metho
- exo-(±)-1-methyl-4-(1-methyl ethyl)-2-((2-methyl phenyl)methoxy)-7-oxabicyclo(2,2,1)heptane
- CINMETHYLIN
- Cinmethylin mixture of isomers PESTANAL
- cinmethylin (bsi, draft e-iso, ansi, wssa)
- Caswell No. 731G
- argold
- cinch
- cinch(cinmethylin)
- (1RS,2RS,4RS)-1,4-Epoxy-p-menth-2-yl-2-methyl benzyl ether
- exo-(+/-)-1-methyl-2-(2-methylbenzyloxy)-4-isopropyl-7-oxabicyclo(2.2.1)heptane
- （1RS， 2SR， 4SR）-1-，4-epoxy-p-menth-2-yl-2-methyl benzyl ehter
- SKH 301
- WL 95481
- (1RS,2SR,4SR)-1,4-EPOXY-P-MENTHA-2-YL2-METHYLBENZYLETHER
- 7-Oxabicyclo(2.2.1)heptane, 1-methyl-4-(1-methylethyl)-2-((2-methylphenyl)methoxy)-, (1R,2S,4S)-rel-
- 7-Oxabicyclo(2.2.1)heptane, 1-methyl-4-(1-methylethyl)-2-((2-methylphenyl)methoxy)-, exo-(+-)-
- 7-Oxabicyclo(2.2.1)heptene exo-(+-)-1-methyl-4-(1-methylethyl)-2-((2-methylphenyl)methoxy)-
- Cinmethylin [iso]
- (1R,2S,4S)-rel-1-Methyl-4-(1-Methylethyl)-2-[(2-Methylphenyl)Methoxy]-7-oxabicyclo[2.2.1]heptane
- exo-(+-)-7-oxabicyclo(2.2.1)heptan
- exo-(+-)-xy)
- sd95481
- (1RS,2RS,4RS)-1,4-epoxy-p-menth-2-yl-2-metnyl-benzyl ether
- (1R,2R,4S)-1-methyl-2-[(2-methylphenyl)methoxy]-4-propan-2-yl-7-oxabicyclo[2.2.1]heptane
- Cinmethylin solution
- シンメチリン
- rac-2β*-(2-メチルベンジルオキシ)-4α*-イソプロピル-1α*-メチル-7-オキサビシクロ[2.2.1]ヘプタン
- （１ＲＳ，２ＳＲ，４ＳＲ）－１，４－エポキシ－ｐ－メンタ－２－イル２－メチルベンジルエーテル
- シンメチリン標準品
- シンメチリン標準液
- アゴールド
- アーゴールド
- 除草剤
- 環境
- 農薬類，殺虫剤および除草剤など
- 生活関係標準物質
- 食料品
- 有機標準物質