(7Z,9E)-7,9-ドデカジエン-1-オールアセタート
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- CAS番号.
- 55774-32-8
- 化学名:
- (7Z,9E)-7,9-ドデカジエン-1-オールアセタート
- 别名:
- (7Z,9E)-7,9-ドデカジエン-1-オールアセタート;(7Z,9E)-ドデカ-7,9-ジエン-1-イル アセタート;酢酸(7Z,9E)-7,9-ドデカジエニル
- 英語名:
- (7Z,9E)-dodecadienyl acetate
- 英語别名:
- (E,Z)-7,9-Dodecadienyl acetate;EGVM;trans-7;Ai3-36730;7Z9E-12Ac;7E9Z-12OAc;(E,Z)-7,9-DDDA;Einecs 259-812-0;(7Z,9E)-Dodecadienyl acetate;EGVM (European Grapevine Moth)
- CBNumber:
- CB4498047
- 化学式:
- C14H24O2
- 分子量:
- 224.34
- MOL File:
- 55774-32-8.mol
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(7Z,9E)-7,9-ドデカジエン-1-オールアセタート 物理性質
- 沸点 :
- 309.6±21.0 °C(Predicted)
- 比重(密度) :
- 0.896±0.06 g/cm3(Predicted)
- 蒸気圧:
- 0.16 Pa (20 °C)
- 闪点 :
- 61 °C
- 貯蔵温度 :
- −20°C
- 溶解性:
- Chloroform (Slightly), Methanol (Slightly)
- 水溶解度 :
- 2.0 mg l-1 (推定 20 °C)
- 外見 :
- Oil
- 色:
- Colourless
- 安定性：:
- Light Sensitive
- InChI:
- InChI=1S/C14H24O2/c1-3-4-5-6-7-8-9-10-11-12-13-16-14(2)15/h4-7H,3,8-13H2,1-2H3/b5-4+,7-6-
- InChIKey:
- LLRZUAWETKPZJO-DEQVHDEQSA-N
- SMILES:
- C(OC(=O)C)CCCCC/C=C\C=C\CC
- EPAの化学物質情報:
- 7,9-Dodecadien-1-ol, acetate, (7Z,9E)- (55774-32-8)
(7Z,9E)-7,9-ドデカジエン-1-オールアセタート 価格
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(7Z,9E)-7,9-ドデカジエン-1-オールアセタート 化学特性,用途語,生産方法
使用
The pheromone is used for trapping and control of the European
grapevine moth (Lubesia butrana).
主な応用
(7Z,9E)-dodecadienyl acetate is a polyunsaturated fatty acid ester compound that can be used in the following areas:
(1) Pest management: By placing a small amount of this product in a lure, male moths are captured in traps, thereby disrupting mating; this is suitable for pest prevention and control in vineyards.
(2) Experimental research: Elucidating the metabolic pathways involved in the synthesis of this substance within pests through in vivo labelling; identifying key genes associated with the synthesis of this product via transcriptomic sequencing, facilitating its production in microorganisms or plants using genetic engineering techniques.
代謝経路
Facile hydrolysis to the alcohol (2) would be expected in alkaline solution.
No published information is available but generally compounds of this
class are rapidly degraded biologically and their behaviour is similar to
that of typical long chain alkenoic acids.
Degradation
The effect of heat, sunlight, radicals and oxidants on isomerisation of the
double bonds has been investigated. The compound is degraded by
heating at 50 °C (6 mg remained of 100 mg after 6 days) but the process
may be slowed by the addition of antioxidants. Isomerisation occurs readily
in sunlight in the presence of a photosensitiser. Within 100 minutes an
equilibrium mixture containing 76% E,E and 12-14% of each of the
E,Z- and Z,E-isomers was formed. In the absence of photosensitiser,
degradation was faster than photoequilibration. Photo-oxidation in the
presence of Rose Bengal as a singlet oxygen generator gave a furan
derivative (4) (see Scheme 1). This takes place after isomerisation of 1 to
the E,E-isomer (3) (Shani et al., 1981).
(7Z,9E)-7,9-ドデカジエン-1-オールアセタート 上流と下流の製品情報
原材料
準備製品
(7Z,9E)-7,9-ドデカジエン-1-オールアセタート 生産企業
Global( 45)Suppliers
55774-32-8((7Z,9E)-7,9-ドデカジエン-1-オールアセタート)キーワード:
- 55774-32-8
- 7Z9E-12Ac
- TRANS-7, CIS-9-DODECADIENYL ACETATE
- trans-7
- trans-7,cis-9-dodecadien-1-yl acetate
- (7E,9Z)-dodeca-7,9-dienyl acetate
- (E,Z)-7,9-DDDA
- (7Z,9E)-7,9-Dodecadien-1-ol acetate
- 7,9-Dodecadien-1-ol, acetate, (E,Z)-
- Ai3-36730
- Einecs 259-812-0
- EGVM (European Grapevine Moth)
- (7Z,9E)-7,9-Dodecadien-1-yl acetate
- (Z,E)-7,9-Dodecadienyl acetate
- EGVM
- (7Z,9E)-Dodecadienyl acetate
- 7,9-Dodecadien-1-ol, acetate, (7Z,9E)-
- (7E,9Z)-Dodeca-7,9-dien-l-y1 acetate
- 7E, 9Z-Dodecadienyl Acetate CAS 55774-32-8
- 7E9Z-12OAc
- (E,Z)-7,9-Dodecadienyl acetate
- (7Z,9E)-7,9-ドデカジエン-1-オールアセタート
- (7Z,9E)-ドデカ-7,9-ジエン-1-イル アセタート
- 酢酸(7Z,9E)-7,9-ドデカジエニル