トリフルオロボラン/ジメチルエーテル,(1:1) 化学特性,用途語,生産方法
外観
わずかにうすい色～褐色、液体
用途
有機合成原料。
化学的特性
clear brownish liquid, fuming in moist air
使用
Reactant or reagent involved in:
- Deconvoluting the chemical reaction kinetics of platinum-silver ligand exchange
- Synthesis of neurogenic ganglioside LLG-3 from starfish via glycosylation reactions
- Synthesis of peloruside via lactonization and relay ring-closing metathesis cyclization
- FRET for monitoring Pd-catalyzed nucleophilic allylic substitution reactions
- Single molecuel imaging of fluorophore-tagged palldium(II) complexes
- β-elimination and rearrangement reactions for synthesis of exocyclic vinyl ethers
一般的な説明
A fuming liquid. Corrosive to skin, eyes and mucous membranes. May be toxic by inhalation. Used as a catalyst in chemical reactions.
空気と水の反応
Highly flammable. In moist air forms dense white pungent fumes, corrosive to skin, avoid inhalation [Merck 11th ed. 1989]. Upon exposure to water may emit flammable and corrosive vapors.
反応プロフィール
Boron trifluoride dimethyl etherate is a flammable, corrosive, and toxic liquid, moisture-sensitive. Emits toxic fluoride fumes when heated to decomposition [Lewis, 3rd ed., 1993, p. 189].
健康ハザード
Boron trifluoride dimethyl etherate is highly toxic by inhalation.
火災危険
Fire may produce irritating or poisonous gases. Flammable/combustible material which may be ignited by heat spark or flame. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion hazard indoors, outdoors, or in sewer. Runoff to sewer may create fire or explosion hazard. When heated to decomposition, Boron trifluoride dimethyl etherate emits toxic fumes of fluorides.
職業ばく露
Used as a catalyst.
輸送方法
Diethyl: UN2604 Boron trifluoride diethyl
etherate, Hazard class: 8; Labels: 8—Corrosive material,
3—Flammable liquid. Dimethyl: UN2965 Boron trifluoride
dimethyl etherate, Hazard class: 4.3; Labels: 4.3—
Dangerous when wet, 8—Corrosive material, 3—
Flammable liquid.
不和合性
Reacts with air forming corrosive hydrogen
fluoride vapors. Incompatible with oxidizers (may
cause fire and explosion), water, steam or heat, forming
corrosive and flammable vapors. Peroxide containing etherate
reacts explosively with aluminum lithium hydride,
magnesium tetrahydroaluminate. Mixtures with phenol
react explosively with 1,3-butadiene. Presumed to form
explosive peroxides.
トリフルオロボラン/ジメチルエーテル,(1:1) 上流と下流の製品情報
原材料
準備製品