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ChemicalBook >> CAS DataBase List >> Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)

Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)

Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor) price.
  • $105 - $1165
  • Product name: Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
  • CAS: 863971-62-4
  • MF: C20H37ClN2OPRu
  • MW: 489.02
  • EINECS:
  • MDL Number:MFCD16038117
  • Synonyms:Carbonylchlorohydrido[6-(di-t-butylphosphinoMethyl)-2-(N,N-diethylaMinoMethyl)pyridine]rutheniuM(II),98% (Milstein Catalyst Precursor);[2-(Di-tert-butylphosphinoMethyl)-6-(diethylaMinoMethyl)pyridine]carbonylchlorohydridorutheniuM(II);Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor);Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)
    pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor);Carbonylchlorohydrido[6-(di-tert-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II);[2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]ruthenium(II) chlorocarbonyl hydride;Milstein Catalyst Precursor;Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98%
Price9 Properties Safety Information Description
9 prices
Selected condition：
Brand
  • Alichem
  • American Custom Chemicals Corporation
  • Arctom
  • Chemenu
  • Crysdot
  • Sigma-Aldrich
  • Strem Chemicals
Package
  • 5MG
  • 100mg
  • 500mg
  • 1g
  • ManufacturerAlichem
  • Product number863971624
  • Product descriptionCarbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II)
  • Packaging1g
  • Price$431.64
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0013316
  • Product descriptionCARBONYLCHLOROHYDRIDO-[6-(DI-T-BUTYLPHOSPHINOMETHYL)-2-(N,N-DIETHYLAMINOMETHYL)PYRIDINE]RUTHENIUM(II) 95.00%
  • Packaging5MG
  • Price$503.67
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS670959
  • Product descriptionCarbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II) 98%
  • Packaging1g
  • Price$1165
  • Updated2021-12-16
  • Buy
  • ManufacturerChemenu
  • Product numberCM102953
  • Product descriptionCarbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II) 95%
  • Packaging1g
  • Price$458
  • Updated2021-12-16
  • Buy
  • ManufacturerCrysdot
  • Product numberCD52000122
  • Product descriptionCarbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II) 95+%
  • Packaging1g
  • Price$485
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number735809
  • Product description[2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]carbonylchlorohydridoruthenium(II)
  • Packaging100mg
  • Price$133
  • Updated2023-06-20
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number735809
  • Product description[2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]carbonylchlorohydridoruthenium(II)
  • Packaging500mg
  • Price$513
  • Updated2022-05-15
  • Buy
  • ManufacturerStrem Chemicals
  • Product number44-0081
  • Product descriptionCarbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
  • Packaging100mg
  • Price$105
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number44-0081
  • Product descriptionCarbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
  • Packaging500mg
  • Price$417
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alichem 863971624 Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II) 1g $431.64 2021-12-16 Buy
American Custom Chemicals Corporation ING0013316 CARBONYLCHLOROHYDRIDO-[6-(DI-T-BUTYLPHOSPHINOMETHYL)-2-(N,N-DIETHYLAMINOMETHYL)PYRIDINE]RUTHENIUM(II) 95.00% 5MG $503.67 2021-12-16 Buy
Arctom AS670959 Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II) 98% 1g $1165 2021-12-16 Buy
Chemenu CM102953 Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II) 95% 1g $458 2021-12-16 Buy
Crysdot CD52000122 Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II) 95+% 1g $485 2021-12-16 Buy
Sigma-Aldrich 735809 [2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]carbonylchlorohydridoruthenium(II) 100mg $133 2023-06-20 Buy
Sigma-Aldrich 735809 [2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]carbonylchlorohydridoruthenium(II) 500mg $513 2022-05-15 Buy
Strem Chemicals 44-0081 Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor) 100mg $105 2024-03-01 Buy
Strem Chemicals 44-0081 Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor) 500mg $417 2024-03-01 Buy

Properties

storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
form :solid
color :pale yellow
Sensitive :air sensitive
InChI :InChI=1S/C19H35N2P.CO.ClH.Ru.H/c1-9-21(10-2)14-16-12-11-13-17(20-16)15-22(18(3,4)5)19(6,7)8;1-2;;;/h11-13H,9-10,14-15H2,1-8H3;;1H;;
InChIKey :PZGQZQZSJOXPGP-UHFFFAOYSA-N
SMILES :C([Ru+2]12(N(CC3C=CC=C(CP1(C(C)(C)C)C(C)(C)C)N2=3)(CC)CC)([H-])[Cl-])#O

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
Precautionary statements:
P281 Use personal protective equipment as required.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Precursor to active ruthenium catalyst for greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Direct Synthesis of Amides from Alcohols and Amines with Liberation of H2

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