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ChemicalBook >> CAS DataBase List >> Benzyl chloroformate

Benzyl chloroformate

Benzyl chloroformate price.
  • $10 - $781.65
  • Product name: Benzyl chloroformate
  • CAS: 501-53-1
  • MF: C8H7ClO2
  • MW: 170.59
  • EINECS:207-925-0
  • MDL Number:MFCD00000640
  • Synonyms:Benzyl Chlorofomate;Phenylmethyl chloroformate;BENZYL CHLOROFORMATE SOLUTION, 50% IN TO LUENE;BENZYL CHLOROFORMATE, TECH. 95%;Z-Cl (Cbz-Cl);Benzyl chloroformate, pract., 95%;Cbz-Cl (Carboobenzoxy Chloride);CBZ-Cl (Z-Cl)
24 prices
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Brand
  • AK Scientific
  • Biosynth Carbosynth
  • Chem-Impex
  • ChemSupplyAustralia
  • Medical Isotopes, Inc.
  • Oakwood
  • Sigma-Aldrich
  • SynQuest Laboratories
  • TCI Chemical
  • Thermo Scientific Chemicals
  • TRC
Package
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  • 10g
  • 25g
  • 50g
  • 100g
  • 250ML
  • 250g
  • 500g
  • 500ML
  • 1000g
  • 100 mL
  • ManufacturerAK Scientific
  • Product numberC478
  • Product descriptionBenzyl Chloroformate
  • Packaging25g
  • Price$66
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB02352
  • Product descriptionBenzyl chloroformate
  • Packaging250g
  • Price$102.5
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB02352
  • Product descriptionBenzyl chloroformate
  • Packaging100g
  • Price$60
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB02352
  • Product descriptionBenzyl chloroformate
  • Packaging500g
  • Price$187.5
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number42370
  • Product descriptionBenzylchloroformate(30-35%inToluene)Hazmat
  • Packaging500ML
  • Price$126.96
  • Updated2021-12-16
  • Buy
  • ManufacturerChemSupplyAustralia
  • Product number300457
  • Product descriptionBenzyl chloroformate, 95%
  • Packaging500g
  • Price$123.2
  • Updated2021-12-16
  • Buy
  • ManufacturerChemSupplyAustralia
  • Product number300457
  • Product descriptionBenzyl chloroformate, 95%
  • Packaging100g
  • Price$60.5
  • Updated2021-12-16
  • Buy
  • ManufacturerChemSupplyAustralia
  • Product number300457
  • Product descriptionBenzyl chloroformate, 95%
  • Packaging25g
  • Price$26.4
  • Updated2021-12-16
  • Buy
  • ManufacturerMedical Isotopes, Inc.
  • Product number54277
  • Product descriptionBenzyl Chloroformate
  • Packaging5G
  • Price$610
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product numberM02865
  • Product descriptionCBZ-Cl
  • Packaging100g
  • Price$198
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product numberM02865
  • Product descriptionCBZ-Cl
  • Packaging25g
  • Price$66
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product numberM02865
  • Product descriptionCBZ-Cl
  • Packaging1g
  • Price$10
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product numberM02865
  • Product descriptionCBZ-Cl
  • Packaging5g
  • Price$13
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product numberM02865
  • Product descriptionCBZ-Cl
  • Packaging10g
  • Price$23
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number8.14688
  • Product descriptionBenzyl chloroformate (stabilised) for synthesis
  • Packaging250ML
  • Price$199
  • Updated2024-03-01
  • Buy
  • ManufacturerSynQuest Laboratories
  • Product number2716-5-X4
  • Product descriptionBenzyl chloroformate 95%
  • Packaging25g
  • Price$20
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific C478 Benzyl Chloroformate 25g $66 2021-12-16 Buy
Biosynth Carbosynth FB02352 Benzyl chloroformate 250g $102.5 2021-12-16 Buy
Biosynth Carbosynth FB02352 Benzyl chloroformate 100g $60 2021-12-16 Buy
Biosynth Carbosynth FB02352 Benzyl chloroformate 500g $187.5 2021-12-16 Buy
Chem-Impex 42370 Benzylchloroformate(30-35%inToluene)Hazmat 500ML $126.96 2021-12-16 Buy
ChemSupplyAustralia 300457 Benzyl chloroformate, 95% 500g $123.2 2021-12-16 Buy
ChemSupplyAustralia 300457 Benzyl chloroformate, 95% 100g $60.5 2021-12-16 Buy
ChemSupplyAustralia 300457 Benzyl chloroformate, 95% 25g $26.4 2021-12-16 Buy
Medical Isotopes, Inc. 54277 Benzyl Chloroformate 5G $610 2021-12-16 Buy
Oakwood M02865 CBZ-Cl 100g $198 2021-12-16 Buy
Oakwood M02865 CBZ-Cl 25g $66 2021-12-16 Buy
Oakwood M02865 CBZ-Cl 1g $10 2021-12-16 Buy
Oakwood M02865 CBZ-Cl 5g $13 2021-12-16 Buy
Oakwood M02865 CBZ-Cl 10g $23 2021-12-16 Buy
Sigma-Aldrich 8.14688 Benzyl chloroformate (stabilised) for synthesis 250ML $199 2024-03-01 Buy
SynQuest Laboratories 2716-5-X4 Benzyl chloroformate 95% 25g $20 2021-12-16 Buy

Properties

Melting point :-20 °C
Boiling point :103 °C20 mm Hg(lit.)
Density :1.212 g/mL at 20 °C
vapor density :1 (vs air)
vapor pressure :1.39 psi ( 20 °C)
refractive index :n20/D 1.519(lit.)
Flash point :197 °F
storage temp. :Store at +2°C to +8°C.
solubility :Miscible with ether, acetone and benzene.
form :Solution
color :slightly yellow to slightly pink
Odor :Irritating; sharp, penetrating.
Water Solubility :decomposes
Sensitive :Moisture Sensitive
Merck :14,1801
Exposure limits :ACGIH: TWA 1 ppm
OSHA: TWA 1 ppm(5 mg/m3)
NIOSH: IDLH 10 ppm; Ceiling 1 ppm(5 mg/m3) Stability :Stable. Incompatible with water, oxidizing agents. Combustible.
InChI :1S/C8H7ClO2/c9-8(10)11-6-7-4-2-1-3-5-7/h1-5H,6H2
InChIKey :HSDAJNMJOMSNEV-UHFFFAOYSA-N
SMILES :ClC(=O)OCc1ccccc1
CAS DataBase Reference :501-53-1(CAS DataBase Reference)
NIST Chemistry Reference :Benzyl chloroformate(501-53-1)
EPA Substance Registry System :Carbonochloridic acid, phenylmethyl ester (501-53-1)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H227 Combustible liquid Flammable liquids Category 4 Warning P210, P280, P370+P378, P403+P235,P501
H290 May be corrosive to metals Corrosive to Metals Category 1 Warning GHS hazard pictograms P234, P390, P404
H303 May be harmfulif swallowed Acute toxicity,oral Category 5 P312
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H330 Fatal if inhaled Acute toxicity,inhalation Category 1, 2 Danger GHS hazard pictograms P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning GHS hazard pictograms P273, P391, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P234 Keep only in original container.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P363 Wash contaminated clothing before reuse.
P370+P378 In case of fire: Use … for extinction.
P390 Absorb spillage to prevent material damage.
P391 Collect spillage. Hazardous to the aquatic environment
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P406 Store in corrosive resistant/… container with a resistant inner liner.
P501 Dispose of contents/container to..…

Description

Benzyl chloroformate is widely used as a reactive chemical intermediate in plastic, pharmaceutical, agricultural and organic chemicals. It is useful for the introduction of carboxybenzyl (cbz) protecting group for amines such as aniline in organic synthesis. It is also involved in the synthesis of 1,2,4-oxadiazoles.

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