1-(Bromoacetyl)pyrene

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Company Name: Henan Dowon Chemical Technology Co., Ltd.  Gold
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1-(Bromoacetyl)pyrene manufacturers

1-(Bromoacetyl)pyrene Basic information
Product Name:1-(Bromoacetyl)pyrene
Synonyms:2-bromo-1-(1-pyrenyl)Ethanone;2-bromo-1-(pyren-3-yl)ethanone;2-broMo-1-(pyren-1-yl)ethanone;1-(Bromoacetyl)pyrene 97%;Ethanone, 2-bromo-1-(1-pyrenyl)-;2-bromo-1-(pyren-1-yl)ethan-1-one;1-(Bromoacetyl)pyrene
CAS:80480-15-5
MF:C18H11BrO
MW:323.18
EINECS:
Product Categories:C15 to C38;Carbonyl Compounds;Ketones
Mol File:80480-15-5.mol
1-(Bromoacetyl)pyrene Structure
1-(Bromoacetyl)pyrene Chemical Properties
Melting point 129-131 °C (lit.)
Boiling point 476.7±18.0 °C(Predicted)
density 1.563±0.06 g/cm3(Predicted)
storage temp. 2-8°C
form Solid
color Yellow to Dark Yellow
InChI1S/C18H11BrO/c19-10-16(20)14-8-6-13-5-4-11-2-1-3-12-7-9-15(14)18(13)17(11)12/h1-9H,10H2
InChIKeyKAEDEGFCOPIKKM-UHFFFAOYSA-N
SMILESBrCC(=O)c1ccc2ccc3cccc4ccc1c2c34
Safety Information
Hazard Codes C
Risk Statements 34
Safety Statements 22-26-36/37/39-45
RIDADR UN 1759 8/PG 2
WGK Germany 3
HazardClass 8
HS Code 29147000
Storage Class8A - Combustible corrosive hazardous materials
Hazard ClassificationsAquatic Chronic 4
Eye Dam. 1
Skin Corr. 1B
MSDS Information
ProviderLanguage
SigmaAldrich English
1-(Bromoacetyl)pyrene Usage And Synthesis
Chemical PropertiesYellow solid
Uses1-(Bromoacetyl)pyrene is suitable for use in the following studies:
  • As an initiator in the bulk polymerization of 2-ethyl-2-oxazoline to generate pyrene labelled poly(2-ethyl-2-oxazoline) (PETOX-py).
  • As a fluorophore in the generation of podand-type fluoroionophores with two pyrene moieties.
  • As a fluorescent labeling agent for the determination of okadaic acid toxin by HPLC with fluorescence detection.
It may also be used in the following studies:
  • As a photoremovable protecting group for carboxylic acids and amino acids.
  • As a photoinitiator in the photopolymerization of styrene with methylmethacrylate.
  • As a reactant in the synthesis of potentially tetradentate pyrene appended ligands.
  • As a derivatizing agent of dialkyl phosphates (DAP) in the HPTLC method of quantitative determination of DAP in fruit juices.
General Description1-(Bromoacetyl)pyrene (BAP) is a pyrene derivative. It has been synthesized by reacting cupric bromide with 1-acetylpyrene. Studies suggest that the introduction of a bromoacetyl chromophoric moiety to pyrene drastically increases the photoinitiating efficiency of pyrenes.
1-(Bromoacetyl)pyrene Preparation Products And Raw materials
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