TpPa-(NO2) COF

孔径	1.5nm
比表面	>300m2/g

荧光：无明显荧光；具有多种相互作用力，包括静电、极性、范德华力、氢键、疏水和C─Hσ-π相互作用在水溶液中，在沸水（100°C）中放置7天，PXRD峰位置和强度不变；在12MHCl、2MH₂SO₄等强酸中浸泡1周以及在0.1MNaOH碱性水溶液中可保持24h稳定；热稳定性方面，在300°C稳定，失重不超过10%，350°C后开始分解；气体吸附与分离：从C₂H₂/C₂H₄/CO₂混合物中选择性分离C₂H₄，从CO₂/N₂中捕获CO₂。[1] Chemically Stable Multilayered Covalent Organic Nanosheets from Covalent Organic Frameworks via Mechanical Delamination. https://doi.org/10.1021/ja408121p
[2] EDTA - Functionalized Covalent Organic Framework for Removal of Heavy Metal Ions. https://doi.org/10.1021/acsami.9b11850
[3] Nitro-Decorated Microporous Covalent Organic Framework (TpPa-NO2) for Selective Separation of C2H4 from a C2H2/C2H4/CO2 Mixture and CO2 Capture. https://doi.org/10.1021/acsami.2c08338
[4] Pore Wall Engineered Polar COFs as Size - Matched Nanotraps Enable Highly Efficient Capture of Long - Chain Alkylamines. https://doi.org/10.1002/adfm.202406834