Hydridocarbonyltris(triphenylphosphine)iridium (I)

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Company Name: Yunnan Boquan Metal Materials Co., Ltd  Gold
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Hydridocarbonyltris(triphenylphosphine)iridium (I) manufacturers

Hydridocarbonyltris(triphenylphosphine)iridium (I) Basic information
Reaction
Product Name:Hydridocarbonyltris(triphenylphosphine)iridium (I)
Synonyms:Hydridocarbonyltris-(triphenylphosphino)-iridium;Carbonylhydridotris(triphenylphosphine)iridium(I), Ir 18.6% min;Carbonylhydridotris(triphenylphosphine)iridium(I) slowly decomposes in air;iridium(I)-tris(triphenylphosphine) carbonyl hydride;carbonylhydrotris(triphenylphosphine)-iridiu;HydridocarbonyltristriphenylphosphineiridiumIlightyellow;carbonylhydrotris(triphenylphosphine)iridium;Ir18.6%min
CAS:17250-25-8
MF:C55H45IrOP3
MW:1007.08
EINECS:241-282-7
Product Categories:Ir;metal carbonyl complexes
Mol File:17250-25-8.mol
Hydridocarbonyltris(triphenylphosphine)iridium (I) Structure
Hydridocarbonyltris(triphenylphosphine)iridium (I) Chemical Properties
Melting point 170°C (dec.)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility Soluble in chloroform and toluene
form Powder
color light yellow
Sensitive Moisture Sensitive
CAS DataBase Reference17250-25-8
EPA Substance Registry SystemIridium, carbonylhydrotris(triphenylphosphine)- (17250-25-8)
Safety Information
Hazard Codes Xn
Risk Statements 36/37/38
Safety Statements 26-36/37/39
RIDADR UN2813
TSCA TSCA listed
HS Code 2843.90.0000
HazardClass 4.3
PackingGroup III
MSDS Information
ProviderLanguage
ALFA English
Hydridocarbonyltris(triphenylphosphine)iridium (I) Usage And Synthesis
Reaction
  1. Catalyst for ring-opening isomerization of unsymmetrically substituted methylenecyclopropanes into 1,3-dienes
  2. Catalyst for asymmetric transfer hydrogenation of aromatic ketones under base-free conditions
  3. Catalyst for C-F bond activation for the C-S cross-coupling of aryl fluorides with diaryl disulfides to synthesize thioethers.
Reactions of 17250-25-8
Chemical Propertiespale yellow powder
UsesHydridocarbonyltris(triphenylphosphine)iridium (I) (CAS# 17250-25-8) is a useful reagent used for Si-C bond cleavage, and as a catalyst in the C-S cross-coupling of aryl fluorides with diaryl disulfides to synthesize thioethers.
Hydridocarbonyltris(triphenylphosphine)iridium (I) Preparation Products And Raw materials
Tag:Hydridocarbonyltris(triphenylphosphine)iridium (I)(17250-25-8) Related Product Information
Carbonylchlorobis(triphenylphosphine)iridium(I) Carbonyldihydrotris(triphenylphosphine)ruthenium Iridium Hydridocarbonyltris(triphenylphosphine)iridium (I) (Formylmethylene)triphenylphosphorane Carbonyltris(triphenylphosphine)rhodium(I) hydride