(1,5-Cyclooctadiene)bis(triphenylphosphine)rhodium(I) hexafluorophosphate dichloromethane complex (1:1)

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(1,5-Cyclooctadiene)bis(triphenylphosphine)rhodium(I) hexafluorophosphate dichloromethane complex (1:1) Basic information
Product Name:(1,5-Cyclooctadiene)bis(triphenylphosphine)rhodium(I) hexafluorophosphate dichloromethane complex (1:1)
Synonyms:(1,5-cyclooctadiene)bis(triphenylphosphine)rhodium(I) PF6/;(1,5-cyclooctadiene)bis(triphenylphos-phine)rhodi;(1,5-CYCLOOCTADIENE)BIS(TRIPHENYLPHOS-PH INE)RHODIUM(I) PF6 CH2CL2 (1:1);NSC 179445;(1,5-Cyclooctadiene)bis(triphenylphosphine)rhodium(I) hexafluorophosphate dichloromethane complex (1:1)
CAS:35238-97-2
MF:C45H44Cl2F6P3Rh4*
MW:965.55
EINECS:
Product Categories:Catalysis and Inorganic Chemistry;Chemical Synthesis;Rhodium
Mol File:35238-97-2.mol
(1,5-Cyclooctadiene)bis(triphenylphosphine)rhodium(I) hexafluorophosphate dichloromethane complex (1:1) Structure
(1,5-Cyclooctadiene)bis(triphenylphosphine)rhodium(I) hexafluorophosphate dichloromethane complex (1:1) Chemical Properties
Melting point 215 °C(lit.)
InChIKeyFCVRPQBVWYQXFH-ISVFTUMHSA-N
SMILES[Rh+].ClCCl.F[P-](F)(F)(F)(F)F.[CH]1[CH]CC[CH][CH]CC1.c2ccc(cc2)P(c3ccccc3)c4ccccc4.c5ccc(cc5)P(c6ccccc6)c7ccccc7
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
(1,5-Cyclooctadiene)bis(triphenylphosphine)rhodium(I) hexafluorophosphate dichloromethane complex (1:1) Usage And Synthesis
UsesCatalyst for:
  • Polycyclotrimerization reactions
  • Hydrosilylation and hydrogenation reactions
  • Hydroformylation reactions
  • Regioselective di- and trisilylation reactions
  • Mannich and nitro-Mannich reactions
  • Reductive alkylation reactions
reaction suitabilitycore: rhodium
reagent type: catalyst
(1,5-Cyclooctadiene)bis(triphenylphosphine)rhodium(I) hexafluorophosphate dichloromethane complex (1:1) Preparation Products And Raw materials
Tag:(1,5-Cyclooctadiene)bis(triphenylphosphine)rhodium(I) hexafluorophosphate dichloromethane complex (1:1)(35238-97-2) Related Product Information
Aluminum oxide Manganese dioxide NEON Palladium nitrate Germanium N/A (1,5-Cyclooctadiene)bis(triphenylphosphine)rhodium(I) hexafluorophosphate dichloromethane complex (1:1) Dichloromethane